Organochlorine Contaminants in Ambient Waters of Lake Ontario

During October 1983, 36-L water samples were collected at 14 stations in Lake Ontario and analyzed for a range (23) of organochlorine contaminants: chlorobenzenes, pesticides and their by-products, and polychlorinated biphenyls (PCBs). Fifteen of the 23 compounds analyzed were ubiquitous in distribution and, of the remaining eight compounds, toxaphene, mirex, photomirex and dichloro· benzenes were undetected. A station located east of Hamilton Harbour was ranked highest in total PCBs (3.1 ng· L -1 ), oxychlordane (0.263 ng · L -1 ) and heptachlor epoxide (0.375 ng· L -1), and ranged second highest in total DDT (tDDT). The highest concentrations for a-BHC (8.08 ng· L -1 ), a-chlordane and r·chlordane (0.046 and 0.062 ng· L -1, respectively) were recorded at a station situated just west of Toronto Harbour. Most of the chlorobenzenes were highest offshore of Eighteen Mile Creek; sampling, however, was insufficient to demonstrate that the observed levels were the result of the Niagara River plume. While pesticide levels did not exceed current criteria established by the Great Lakes Water Quality Agreement and the United States Environmental Protection Agency, concentrations of lindane, dieldrin, endrin, and tDDT were within one order of magnitude of these criteria

Trends in reported flooding in the UK: 1884-2013

A long term dataset of reported flooding based on reports from the UK Meteorological Office and the UK Centre for Ecology and Hydrology is described. This is possibly a unique dataset as the authors are unaware of any other 100+ year records of flood events and their consequences on a national scale. Flood events are classified by severity based upon qualitative descriptions. There is an increase in the number of reported flood events over time associated with an increased exposure to flooding as floodplain areas were developed. The data was de-trended for exposure, using population and dwelling house data. The adjusted record shows no trend in reported flooding over time, but there is significant decade to decade variability. This study opens a new approach considering flood occurrence over a long timescale using reported information (and thus likely effects on society) rather than just considering trends in extreme hydrological conditions.<br/

A 1200-micron MAMBO survey of ELAISN2 and the Lockman Hole - I. Maps, sources and number counts

The definitive version is available at www.blackwell-synergy.com '.--Copyright Blackwell Publishing. DOI : 10.1111/j.1365-2966.2004.08235.xWe present a deep, new 1200μm survey of the ELAISN2 and Lockman Hole fields using the Max Planck Millimeter Bolometer array (MAMBO). The areas surveyed are 160 arcmin2 in ELAISN2 and 197 arcmin2 in the Lockman Hole, covering the entire SCUBA ‘8mJy Survey’. In total, 27 (44) sources have been detected at a significance 4.0 ( 3.5 ). The primary goals of the survey were to investigate the reliability of (sub)millimetre galaxy (SMG) samples, to analyse SMGs using flux ratios sensitive to redshift at z > 3, and to search for ‘SCUBA drop-outs’, i.e. galaxies at z >> 3. We present the 1200μm number counts and find evidence of a fall at bright flux levels. Employing parametric models for the evolution of the local 60μm IRAS luminosity function (LF), we are able to account simultaneously for the 1200 and 850μm counts, suggesting that the MAMBO and SCUBA sources trace the same underlying population of high-redshift, dust-enshrouded galaxies. From a nearest-neighbour clustering analysis we find tentative evidence that themost significantMAMBO sources come in pairs, typically separated by 23′′. Our MAMBO observations unambiguously confirm around half of the SCUBA sources. In a robust sub-sample of 13 SMGs detected by both MAMBO and SCUBA at a significance 3.5 , only one has no radio counterpart. Furthermore, the distribution of 850/1200μmflux density ratios for this sub-sample is consistent with the spectroscopic redshift distribution of radio-detected SMGs (Chapman et al. 2003). Finally, we have searched for evidence of a high-redshift tail of SMGs amongst the 18 MAMBO sources which are not detected by SCUBA. While we cannot rule out that some of them are SCUBA drop-outs at z >> 3, their overall 850-to-1200μm flux distribution is statistically indistinguishable from that of the 13 SMGS which were robustly identified by both MAMBO and SCUBA.Peer reviewe

Estimating the long-term historic evolution of exposure to flooding of coastal populations

Coastal managers face the task of assessing and managing flood risk. This requires knowledge of the area of land, the number of people, properties and other infrastructure potentially affected by floods. Such analyses are usually static; i.e. they only consider a snapshot of the current situation. This misses the opportunity to learn about the role of key drivers of historical changes in flood risk, such as development and population rise in the coastal flood plain and sea-level rise.In this paper, we develop and apply a method to analyse the temporal evolution of residential population exposure to coastal flooding. It uses readily available data in a GIS environment. We examine how population and sea level change modify exposure over two centuries in two neighbouring coastal sites: Portsea and Hayling Islands on the UK south coast. The analysis shows that flood exposure changes as a result of increases in population, changes in coastal population density and sea level rise. The results indicate that to date, population change is the dominant driver of the increase in exposure to flooding in the study sites, but climate change may outweigh this in the future. A full analysis of flood risk is not possible as data on historic defences and wider vulnerability are not available. Hence, the historic evolution of flood exposure is as close as we can get to a historic evolution of flood risk.The method is applicable anywhere that suitable floodplain geometry, sea level and population datasets are available and could be widely applied, and will help inform coastal managers of the time evolution in coastal flood drivers<br/

Nature does not rely on long-lived electronic quantum coherence for photosynthetic energy transfer

During the first steps of photosynthesis, the energy of impinging solar photons is transformed into electronic excitation energy of the light-harvesting biomolecular complexes. The subsequent energy transfer to the reaction center is commonly rationalized in terms of excitons moving on a grid of biomolecular chromophores on typical timescales [Formula: see text]100 fs. Today's understanding of the energy transfer includes the fact that the excitons are delocalized over a few neighboring sites, but the role of quantum coherence is considered as irrelevant for the transfer dynamics because it typically decays within a few tens of femtoseconds. This orthodox picture of incoherent energy transfer between clusters of a few pigments sharing delocalized excitons has been challenged by ultrafast optical spectroscopy experiments with the Fenna-Matthews-Olson protein, in which interference oscillatory signals up to 1.5 ps were reported and interpreted as direct evidence of exceptionally long-lived electronic quantum coherence. Here, we show that the optical 2D photon echo spectra of this complex at ambient temperature in aqueous solution do not provide evidence of any long-lived electronic quantum coherence, but confirm the orthodox view of rapidly decaying electronic quantum coherence on a timescale of 60 fs. Our results can be considered as generic and give no hint that electronic quantum coherence plays any biofunctional role in real photoactive biomolecular complexes. Because in this structurally well-defined protein the distances between bacteriochlorophylls are comparable to those of other light-harvesting complexes, we anticipate that this finding is general and directly applies to even larger photoactive biomolecular complexes

Interferometric imaging of the high-redshift radio galaxy, 4C60.07: An SMA, Spitzer and VLA study reveals a binary AGN/starburst

‘The definitive version is available at www3.interscience.wiley.com '. Copyright Blackwell / RAS. DOI: 10.1111/j.1365-2966.2008.13811.xPeer reviewe

Low Timing Jitter Detector for Gigahertz Quantum Key Distribution

A superconducting single-photon detector based on a niobium nitride nanowire is demonstrated in an optical-fibre-based quantum key distribution test bed operating at a clock rate of 3.3 GHz and a transmission wavelength of 850 nm. The low jitter of the detector leads to significant reduction in the estimated quantum bit error rate and a resultant improvement in the secrecy efficiency compared to previous estimates made by use of silicon single-photon avalanche detectors.Comment: 11 pages, including 2 figure

A Simple Game-Theoretic Approach to Checkonly QVT Relations

The QVT Relations (QVT-R) transformation language allows the def-inition of bidirectional model transformations, which are required in cases where a two (or more) models must be kept consistent in the face of changes to either. A QVT-R transformation can be used either in check-only mode, to determine whether a target model is consistent with a given source model, or in enforce mode, to change the target model. Al-though the most obvious semantic issues in the QVT standard concern the restoration of consistency, in fact even checkonly mode is not completely straightforward; this mode is the focus of this paper. We need to consider the overall structure of the transformation as given by when and where clauses, and the role of trace classes. In the standard, the semantics of QVT-R are given both directly, and by means of a translation to QVT Core, a language which is intended to be simpler. In this paper, we argue that there are irreconcilable differences between the intended semantics of QVT-R and those of QVT Core, so that the translation cannot be helpful. Treating QVT-R directly, we propose a simple game-theoretic semantics. We demonstrate its behaviour on examples and show how it can be used to compare QVT-R transformations. We demonstrate that consistent models may not possess a single trace model whose objects can be read as traceability links in either direction. We briefly discuss the ef-fect of variations in the rules of the game, to elucidate some design choices available to the designers of the QVT-R language.

The SCUBA Half Degree Extragalactic Survey (SHADES) - III : Identification of radio and mid-infrared counterparts to submillimetre galaxies

Peer reviewe

Direct seeding of chenopod shrubs for saltland and rangeland environments

There are currently two ways of establishing chenopod shrubs: sowing from seed using a niche seeder, or planting nursery-raised seedlings with a tree planter. Planting seedlings is the more reliable method, but is relatively expensive (in excess of $450 per hectare). On the other hand, direct seeding using the specialised “niche seeder” is much less expensive ($100-150 per hectare), but is also less reliable. This project aimed to investigate alternative methods of direct seeding chenopod shrubs for saltland and rangeland areas by developing a greater understanding of their seed biology and agronomic requirements. Our aspiration was that shrubs should be established using more conventional farm machinery. This bulletin reports on a combination of seed biology and agronomic research to develop reliable, low-cost direct seeding options for chenopod shrubs. Experiments into the impact of changing environmental conditions on seeds were studied in the laboratory, and field experiments were conducted to test the applicability of these insights in the field using conventional modified farm seeding machinery. As a result of this work, a successful direct seeding package using farm seeding equipment (modified for wide row spacings and depth control) was developed for Atriplex nummularia (old man saltbush), the most widely planted saltbush species across southern Australia. The nine key elements of the package are: 1. Select suitable paddocks for introduction of new shrubs 2. Prepare a weed-free seedbed using two knockdown herbicide applications (4-6 weeks and 1-2 weeks before seeding) and commence control of rabbits and kangaroos 3. Sow the best seed, by ensuring: a. Large fruits, with a high proportion of viable seeds, have been selected b. Seed is of subspecies nummularia (not subsp. spathulata) c. Fruits have been harvested within the previous six months and stored in a cool, dry environment d. Bracts are retained around the seeds 4. Sow into moisture in late winter - early spring (depending on district) a. If the area to be sown is waterlogged, defer sowing until later in spring b. If insufficient soil moisture, defer sowing until the following year 5. Use a sowing rate of ~10 fruits/m (if germination rate is 15%) to provide at least one plant for every 2 m of row; use higher rates for seed of lower germination 6. Set the seeder up to sow into furrows with trailing press wheels 7. Sow to a depth of 5-10 mm (very critical) 8. Control weeds and pests (insects, mites, kangaroos and rabbits) 9. Defer grazing until seedlings are well established This establishment method has also been shown to work for Rhagodia preissii (mallee saltbush). This project was not able to develop reliable direct seeding packages for other Atriplex species, including A. amnicola and A. undulata. Further work is needed to understand the triggers for their germination, before these species can be direct-seeded with conventional machinery. Direct sowing of M. brevifolia and M. pyramidata appears to be problematic in much of southern Australia, due to their requirement for temperatures >30°C for germination, which do not occur within the normal winter growing season. An exception to this would be areas with more reliable summer rainfall, such as northern New South Wales, where sowing could be deferred until late spring-early summer. An alternative strategy for establishing M. brevifolia, is to encourage natural recruitment of seedlings from seed produced on surrounding bushes (if it is already present in the area), or to transplant a low density of nursery-raised seedlings, which could then act as a seed source for natural recruitment (if it is not already present)