Twenty years of SpeX: Accuracy limits of spectral slope measurements in asteroid spectroscopy

We examined two decades of SpeX/NASA Infrared Telescope Facility observations from the Small Main-Belt Asteroid Spectroscopic Survey (SMASS) and the MIT-Hawaii Near-Earth Object Spectroscopic Survey (MITHNEOS) to investigate uncertainties and systematic errors in reflectance spectral slope measurements of asteroids. From 628 spectra of 11 solar analogs used for calibration of the asteroid spectra, we derived an uncertainty of 4.2%/micron on slope measurements over 0.8 to 2.4 micron. Air mass contributes to -0.92%/micron per 0.1 unit air mass difference between the asteroid and the solar analog, and therefore for an overall 2.8%/micron slope variability in SMASS and MITHNEOS designed to operate within 1.0 to 1.3 air mass. No additional observing conditions (including parallactic angle, seeing and humidity) were found to contribute systematically to slope change. We discuss implications for asteroid taxonomic classification works. Uncertainties provided in this study should be accounted for in future compositional investigation of small bodies to distinguish intrinsic heterogeneities from possible instrumental effects.Comment: 15 pages, 11 figures, accepted for publication in ApJ

Cosmochemical and spectroscopic properties of Northwest Africa 7325 - A consortium study

This work is part of a project to build an infrared database in order to link IR data of planetary materials (and therefore possible Mercury material) with remote sensing observations of Mercury, which will probably be obtained by the MERTIS instrument on the forthcoming BepiColombo mission.The unique achondrite Northwest Africa (NWA) 7325, which has previously been suggested to represent the first sample from Mercury, was investigated by optical and electron microscopy, and infrared and Raman spectroscopy. In addition, the oxygen, strontium, xenon, and argon isotopes were measured and the abundance of selected trace elements determined. The meteorite is a cumulate rock with subchondritic abundances of HFSE and REE and elevated Sr contents, which underwent a second heating and partial remelting process. Oxygen isotope measurements show that NWA 7325 plots in the ureilite field, close to the ALM-A trachyandesitic fragment found in the unique Almahata Sitta meteorite breccia. On the other hand, mineralogical investigations of the pyroxenes in NWA 7325 provide evidence for similarities to the lodranites and acapulcoites. Furthermore, the rock is weakly shocked and argon isotope data record ancient (~4.5 Ga) plateau ages that have not been reset. The sample records a cosmogenic exposure age of ~19 Ma. Systematics of Rb-Sr indicate an extreme early volatile depletion of the precursor material, similar to many other achondrite groups. However, despite its compositional similarities to other meteorite groups, our results suggest that this meteorite is unique and unrelated to any other known achondrite group. An origin for NWA 7325 as a sample from the planet Mercury is not supported by the results of our investigation. In particular, the evidence from infrared spectroscopy indicates that a direct relationship between NWA 7325 and the planet Mercury can be ruled out: no acceptable spectral match between laboratory analyses and remote sensing observations from Mercury has been obtained. However, we demonstrate that infrared spectroscopy is a rapid and nondestructive method to characterize mineral phases and thus an excellent tool for planetary surface characterization in space missions

3D-Printable PP/SEBS Thermoplastic Elastomeric Blends: Preparation and Properties

Currently, material extrusion 3D printing (ME3DP) based on fused deposition modeling (FDM) is considered a highly adaptable and efficient additive manufacturing technique to develop components with complex geometries using computer-aided design. While the 3D printing process for a number of thermoplastic materials using FDM technology has been well demonstrated, there still exists a significant challenge to develop new polymeric materials compatible with ME3DP. The present work reports the development of ME3DP compatible thermoplastic elastomeric (TPE) materials from polypropylene (PP) and styrene-(ethylene-butylene)-styrene (SEBS) block copolymers using a straightforward blending approach, which enables the creation of tailorable materials. Properties of the 3D printed TPEs were compared with traditional injection molded samples. The tensile strength and Young’s modulus of the 3D printed sample were lower than the injection molded samples. However, no significant differences could be found in the melt rheological properties at higher frequency ranges or in the dynamic mechanical behavior. The phase morphologies of the 3D printed and injection molded TPEs were correlated with their respective properties. Reinforcing carbon black was used to increase the mechanical performance of the 3D printed TPE, and the balancing of thermoplastic elastomeric and mechanical properties were achieved at a lower carbon black loading. The preferential location of carbon black in the blend phases was theoretically predicted from wetting parameters. This study was made in order to get an insight to the relationship between morphology and properties of the ME3DP compatible PP/SEBS blends

Connecting asteroids and meteorites with visible and near-infrared spectroscopy

International audienceIn this work we identify spectral similarities between asteroids and meteorites. Using spectral features such as absorption bands and spectral curvature, we identify spectral matches between 500 asteroid spectra and over 1,000 samples of RELAB meteorite spectra over visible plus near-infrared wavelengths (0.45- 2 . 5 μm). We reproduce and confirm many major and previously known meteorite-asteroid connections and find possible new, more rare or less-established connections. Well-established connections include: ordinary chondrites with S-complex asteroids; pristine CM carbonaceous chondrites with Ch-type asteroids and heated CMs with C-type asteroids ; HED meteorites with V-types; enstatite chondrites with Xc-type asteroids; CV meteorites with K-type asteroids; Brachinites, Pallasites and R chondrites with olivine-dominated A-type asteroids. In addition to the link between ordinary chondrite meteorites with S-complex asteroids, we find a trend from Q, Sq, S, Sr to Sv correlates with LL to H, with Q-types matching predominately to L and LL ordinary chondrites, and Sr and Sv matching predominantly with L and H ordinary chondrites. We find ordinary chondrite samples that match to the X-complex. These are measurements of slabs and many are labeled as dark or black (shocked) ordinary chondrites. We find carbonaceous chondrite samples having spectral slopes large enough to match D-type asteroid spectra. We find in many cases the asteroid type to meteorite type links are not unique, for classes with and without distinct spectral features. While there are examples of dominant matches between an asteroid class and meteorite class that are well established, there are less common but still spectrally compatible matches between many asteroid types and meteorite types. This result emphasizes the diversity of asteroid and meteorite compositions and highlights the degeneracy of classification by spectral features alone requiring additional measurements to firmly establish asteroid-meteorite links. Recent and upcoming spacecraft missions will shed light on the compositions of many of the asteroid classes, particularly those without diagnostic features, (C-, B-, X-, and D-types), with measurements of C-type Ceres, C-type Ryugu, B-type Bennu, M-type Psyche, and C-, P-, and D-types as part of the Lucy mission