Ionisation and discharge in cloud-forming atmospheres of brown dwarfs and extrasolar planets

Brown dwarfs and giant gas extrasolar planets have cold atmospheres with rich chemical compositions from which mineral cloud particles form. Their properties, like particle sizes and material composition, vary with height, and the mineral cloud particles are charged due to triboelectric processes in such dynamic atmospheres. The dynamics of the atmospheric gas is driven by the irradiating host star and/or by the rotation of the objects that changes during its lifetime. Thermal gas ionisation in these ultra-cool but dense atmospheres allows electrostatic interactions and magnetic coupling of a substantial atmosphere volume. Combined with a strong magnetic field , a chromosphere and aurorae might form as suggested by radio and x-ray observations of brown dwarfs. Non-equilibrium processes like cosmic ray ionisation and discharge processes in clouds will increase the local pool of free electrons in the gas. Cosmic rays and lighting discharges also alter the composition of the local atmospheric gas such that tracer molecules might be identified. Cosmic rays affect the atmosphere through air showers in a certain volume which was modelled with a 3D Monte Carlo radiative transfer code to be able to visualise their spacial extent. Given a certain degree of thermal ionisation of the atmospheric gas, we suggest that electron attachment to charge mineral cloud particles is too inefficient to cause an electrostatic disruption of the cloud particles. Cloud particles will therefore not be destroyed by Coulomb explosion for the local temperature in the collisional dominated brown dwarf and giant gas planet atmospheres. However, the cloud particles are destroyed electrostatically in regions with strong gas ionisation. The potential size of such cloud holes would, however, be too small and might occur too far inside the cloud to mimic the effect of, e.g. magnetic field induced star spots

Triphilic ionic-liquid mixtures: fluorinated and non-fluorinated aprotic ionic-liquid mixtures

We present here the possibility of forming triphilic mixtures from alkyl- and fluoroalkylimidazolium ionic liquids, thus, macroscopically homogeneous mixtures for which instead of the often observed two domainspolar and nonpolarthree stable microphases are present: polar, lipophilic, and fluorous ones. The fluorinated side chains of the cations indeed self-associate and form domains that are segregated from those of the polar and alkyl domains. To enable miscibility, despite the generally preferred macroscopic separation between fluorous and alkyl moieties, the importance of strong hydrogen bonding is shown. As the long-range structure in the alkyl and fluoroalkyl domains is dependent on the composition of the liquid, we propose that the heterogeneous, triphilic structure can be easily tuned by the molar ratio of the components. We believe that further development may allow the design of switchable, smart liquids that change their properties in a predictable way according to their composition or even their environment

Synchronizing Sequencing Software to a Live Drummer

Copyright 2013 Massachusetts Institute of Technology. MIT allows authors to archive published versions of their articles after an embargo period. The article is available at

Detection of HI 21 cm-line absorption in the Warm Neutral Medium and in the Outer Arm of the Galaxy

Using the Westerbork Synthesis Radio Telescope, we have detected HI 21 cm-line absorption in the Warm Neutral Medium of the Galaxy toward the extragalactic source 3C147. This absorption, at an LSR velocity of -29+/-4 km/s with a full width at half maximum of 53+/-6 km/s, is associated with the Perseus Arm of the Galaxy. The observed optical depth is (1.9+/-0.2)*10**(-3). The estimated spin temperature of the gas is 3600+/-360 K. The volume density is 0.4 per cc assuming pressure equilibrium. Toward two other sources, 3C273 and 3C295, no wide HI 21 cm-line absorption was detected. The highest of the 3sigma lower limits on the spin temperature of the Warm Neutral Medium is 2600 K. In addition, we have also detected HI 21 cm-line absorption from high velocity clouds in the Outer Arm toward 3C147 and 3C380 at LSR velocities of -117.3, -124.5 and -113.7 km/s respectively. We find two distinct temperature components in the high velocity clouds with spin temperatures of greater than 1000 K and less than 200 K, respectively.Comment: 21 pages inclusive of 7 figures and 2 table

Single and Composite Hot Subdwarf Stars in the Light of 2MASS All-Sky Photometry

Utilizing the Two Micron All Sky Survey (2MASS) All-Sky Data Release Catalog, we have retrieved useful near-IR J, H, and Ks magnitudes for more than 800 hot subdwarfs (sdO and sdB stars) drawn from the "Catalogue of Spectroscopically Identified Hot Subdwarfs" (Kilkenny, Heber, & Drilling 1988, 1992). This sample size greatly exceeds previous studies of hot subdwarfs. We find that, of the hot subdwarfs in Kilkenny et al., ~40% in a magnitude limited sample have colors that are consistent with the presence of an unresolved late type (FGK) companion. Binary stars are over-represented in a magnitude limited sample. In an approximately volume limited sample the fraction of composite-color binaries is ~25%.Comment: 4 pages, 1 figure. To appear in "Extreme Horizontal Branch Stars and Related Objects", Astrophysics and Space Science, Kluwer Academic Publishers, proceedings of the meeting held in Keele, UK, June 16-20, 200

A Meinardus theorem with multiple singularities

Meinardus proved a general theorem about the asymptotics of the number of weighted partitions, when the Dirichlet generating function for weights has a single pole on the positive real axis. Continuing \cite{GSE}, we derive asymptotics for the numbers of three basic types of decomposable combinatorial structures (or, equivalently, ideal gas models in statistical mechanics) of size $n$, when their Dirichlet generating functions have multiple simple poles on the positive real axis. Examples to which our theorem applies include ones related to vector partitions and quantum field theory. Our asymptotic formula for the number of weighted partitions disproves the belief accepted in the physics literature that the main term in the asymptotics is determined by the rightmost pole.Comment: 26 pages. This version incorporates the following two changes implied by referee's remarks: (i) We made changes in the proof of Proposition 1; (ii) We provided an explanation to the argument for the local limit theorem. The paper is tentatively accepted by "Communications in Mathematical Physics" journa

Controls on nitrogen cycling in terrestrial ecosystems : a synthetic analysis of literature data

Author Posting. © Ecological Society of America, 2005. This article is posted here by permission of Ecological Society of America for personal use, not for redistribution. The definitive version was published in Ecological Monographs 75 (2005): 139–157, doi:10.1890/04-0988.Isotope pool dilution studies are increasingly reported in the soils and ecology literature as a means of measuring gross rates of nitrogen (N) mineralization, nitrification, and inorganic N assimilation in soils. We assembled data on soil characteristics and gross rates from 100 studies conducted in forest, shrubland, grassland, and agricultural systems to answer the following questions: What factors appear to be the major drivers for production and consumption of inorganic N as measured by isotope dilution studies? Do rates or the relationships between drivers and rates differ among ecosystem types? Across a wide range of ecosystems, gross N mineralization is positively correlated with microbial biomass and soil C and N concentrations, while soil C:N ratio exerts a negative effect on N mineralization only after adjusting for differences in soil C. Nitrification is a log-linear function of N mineralization, increasing rapidly at low mineralization rates but changing only slightly at high mineralization rates. In contrast, NH4+ assimilation by soil microbes increases nearly linearly over the full range of mineralization rates. As a result, nitrification is proportionately more important as a fate for NH4+ at low mineralization rates than at high mineralization rates. Gross nitrification rates show no relationship to soil pH, with some of the fastest nitrification rates occurring below pH 5 in soils with high N mineralization rates. Differences in soil organic matter (SOM) composition and concentration among ecosystem types influence the production and fate of mineralized N. Soil organic matter from grasslands appears to be inherently more productive of ammonium than SOM from wooded sites, and SOM from deciduous forests is more so than SOM in coniferous forests, but differences appear to result primarily from differing C:N ratios of organic matter. Because of the central importance of SOM characteristics and concentrations in regulating rates, soil organic matter depletion in agricultural systems appears to be an important determinant of gross process rates and the proportion of NH4+ that is nitrified. Addition of 15N appears to stimulate NH4+ consumption more than NO3− consumption processes; however, the magnitude of the stimulation may provide useful information regarding the factors limiting microbial N transformations.This research was supported by a grant from The Andrew W. Mellon Foundation to The Ecosystems Center of the Marine Biological Laboratory, Woods Hole, Massachusetts, and by a grant from the National Science Foundation to Utah State University, Logan, Utah