Weakening and strain localization produced by syn-deformational reaction of plagioclase

Abstract. : There are many observations in naturally deformed rocks on the effects of mineral reactions on deformation, but few experimental data. In order to study the effects of chemical disequilibrium on deformation we have investigated the hydration reaction plagioclase + H2O→ more albitic plagioclase + zoisite + kyanite + quartz. We utilized fine-grained (2-6µm) plagioclase aggregates of two compositions (An54 and An60), both dried and with 0.1-0.4wt% H2O present, in shear deformation experiments at two sets of conditions: 900°C, 1.0GPa (in the plagioclase stability field) and 750°C, 1.5GPa (in the zoisite stability field). Dry samples and those deformed in the plagioclase stability field underwent homogeneous shearing by dislocation creep, but samples with 0.1 to 0.4wt% water deformed in the zoisite stability field showed extreme strain localization into very narrow (~1-3µm) shear bands after low shear strain. In these samples the microstructures of reaction products in the matrix differ from those in the shear bands. In the matrix, large (up to 400µm) zoisite crystals grew in the direction of finite extension, and relict plagioclase grains are surrounded by rims of recrystallized grains that are more albitic. In the shear bands, the reaction products albitic plagioclase, zoisite, white mica, and traces of kyanite form polyphase aggregates of very fine-grained (<0.1µm) dislocation-free grains. Most of the sample strain after γ ~2 has occurred within the shear bands, within which the dominant deformation mechanism is inferred to be diffusion-accommodated grain boundary sliding (DAGBS). The switch from dislocation creep in dry samples deformed without reaction to DAGBS in reacted samples is associated with a decrease in flow stress from ~800 to <200MPa. These experiments demonstrate that heterogeneous nucleation driven in part by chemical disequilibrium can produce an extremely fine-grained polyphase assemblage, leading to a switch in deformation mechanism and significant weakening. Thus, localization of deformation in polyphase rocks may occur on any pressure (P),temperature (T)-path where the equilibrium composition of the constituent minerals change

Syn-kinematic hydration reactions, grain size reduction, and dissolution-precipitation creep in experimentally deformed plagioclase-pyroxene mixtures

Source at https://doi.org/10.5194/se-9-985-2018 .It is widely observed that mafic rocks are able to accommodate high strains by viscous flow. Yet, a number of questions concerning the exact nature of the involved deformation mechanisms continue to be debated. In this contribution, rock deformation experiments on four different water-added plagioclase–pyroxene mixtures are presented:(i) plagioclase(An60–70)–clinopyroxene–orthopyroxene,(ii) plagioclase(An60)–diopside,(iii) plagioclase(An60)–enstatite,and iv) plagioclase(An01)–enstatite. Samples were deformed in general shear at strain rates of 3×10−5 to 3×10−6 s−1, 800°C, and confining pressure of 1.0 or 1.5GPa. Results indicate that dissolution–precipitation creep (DPC) and grain boundary sliding (GBS) are the dominant deformation mechanisms and operate simultaneously. Coinciding with sample deformation, syn-kinematic mineral reactions yield abundant nucleation of new grains; the resulting intense gray size reduction is considered crucial for the activity of DPC and GBS. In high strain zones dominated by plagioclase, a weak, nonrandom, and geometrically consistent crystallographic preferred orientation (CPO) is observed. Usually, a CPO is considered a consequence of dislocation creep, but the experiments presented here demonstrate that a CPO can develop during DPC and GBS. This study provides new evidence for the importance of DPC and GBS in mid-crustal shear zones within mafic rocks, which has important implications for understanding and modeling mid-crustal rheology and flow

Modification of fluid inclusions in quartz by deviatoric stress. II: experimentally induced changes in inclusion volume and composition

Fluid inclusions in quartz are known to modify their densities during shear deformation. Modifications of chemical composition are also suspected. However, such changes have not been experimentally demonstrated, their mechanisms remain unexplained, and no criteria are available to assess whether deformed inclusions preserve information on paleofluid properties. To address these issues, quartz crystals containing natural CO2-H2O-NaCl fluid inclusions have been experimentally subjected to compressive deviatoric stresses of 90-250MPa at 700°C and ~600MPa confining pressure. The resulting microcracking of the inclusions leads to expansion by up to 20%, producing low fluid densities that bear no relation to physical conditions outside the sample. Nevertheless, the chemical composition of the precursor inclusions is preserved. With time the microcracks heal and form swarms of tiny satellite inclusions with a wide range of densities, the highest reflecting the value of the maximum principle stress, σ 1. These new inclusions lose H2O via diffusion, thereby passively increasing their salt and gas contents, and triggering plastic deformation of the surrounding quartz via H2O-weakening. Using microstructural criteria to identify the characteristic types of modified inclusions, both the pre-deformation fluid composition and syn-deformation maximum stress on the host mineral can be derived from microthermometric analysis and thermodynamic modellin

Modification of fluid inclusions in quartz by deviatoric stress I: experimentally induced changes in inclusion shapes and microstructures

Fluid inclusions in quartz are known to modify their shapes and microstructures (textures) during weak plastic deformation. However, such changes have not been experimentally demonstrated and criteria are not available to relate them to paleostress conditions. To address these issues, quartz crystals containing natural CO2-H2O-NaCl fluid inclusions have been experimentally subjected to compressive deviatoric stresses of 90-250MPa at 700°C and~600MPa confining pressure. Strains of up to 1% cause the inclusions to develop irregular shapes and to generate microcracks in crystallographic planes oriented subperpendicular to the major compression axis, σ 1. The uniform alignment of the microcracks imparts a planar fabric to the samples. The microcracks heal and form swarms of tiny satellite inclusions. These new inclusions lose H2O by diffusion, thereby triggering plastic deformation of the surrounding quartz via H2O-weakening. Consequently, the quartz samples deform plastically only in domains originally rich in inclusions. This study shows that fluid inclusions deformed by deviatoric stresses may indeed record information on paleostress orientations and that they play a key role in facilitating crystal-plastic deformation of quart

Experimental grain growth of quartz aggregates under wet conditions and its application to deformation in nature

Source at https://doi.org/10.5194/se-10-621-2019. Grain growth of quartz was investigated using two quartz samples (powder and novaculite) with water under pressure and temperature conditions of 1.0–2.5 GPa and 800–1100 ∘C. The compacted powder preserved a substantial porosity, which caused a slower grain growth than in the novaculite. We assumed a grain growth law of dn−dn0=k0frH2Oexp(−Q/RT)t with grain size d (µm) at time t (seconds), initial grain size d0 (µm), growth exponent n, a constant k0 (µmn MPa−r s−1), water fugacity fH2O (MPa) with the exponent r, activation energy Q (kJ mol−1), gas constant R, and temperature T in Kelvin. The parameters we obtained were n=2.5±0.4, k0=10−8.8±1.4, r=2.3±0.3, and Q=48±34 for the powder and n=2.9±0.4, k0=10−5.8±2.0, r=1.9±0.3, and Q=60±49 for the novaculite. The grain growth parameters obtained for the powder may be of limited use because of the high porosity of the powder with respect to crystalline rocks (novaculite), even if the differences between powder and novaculite vanish when grain sizes reach ∼70 µm. Extrapolation of the grain growth laws to natural conditions indicates that the contribution of grain growth to plastic deformation in the middle crust may be small. However, grain growth might become important for deformation in the lower crust when the strain rate is −12 s−1

Grain size distributions of fault rocks: a comparison between experimentally and naturally deformed granitoids.

International audienceWe have investigated the grain size distribution (GSD) of granitoid fault rock by comparing experimentally produced gouge with fault rock from the Nojima Fault Zone. Triaxial experiments were carried out on wet and dry intact samples of Verzasca Gneiss at T = 300 and 500°C, Pc = 500 and 1030 MPa, ε = 0.013-1.6 x 10-4s-1. The GSD has been determined from SEM-micrographs and is characterized by the slope, D, of its log(frequency)-log(radius) histogram. The GSD is not fractal; we observe two slopes for all GSDs. The larger grains in experimentally deformed samples have a D value, D>, of 2.04 and 2.26 for feldspar and quartz gouge. Cracked grains yield values of D = 1.5-1.6.Increasing the confining pressure or temperature decreases the D-value. For grains smaller than ~2 μm another D-value, D = 2.02 for gouge and 1.64 for cracked grains; D< = 0.97. Grain size reduction in fault zones develops by a two-stage process: rupturing creates cracked grains; further displacement of fragments causes further comminution by wear and attrition. Cracked grains have been used to calculate the surface energy associated with faulting; it follows that this energy forms a small fraction in the total energy-budget of earthquakes

Dislocation creep of dry quartz

International audienceSmall-scale shear zones within the Permian Truzzo meta-granite developed during the Alpine orogeny at amphibolite facies conditions. In these shear zones magmatic quartz deformed by dislocation creep and recrystallized dynamically by grain boundary migration with minor subgrain rotation recrystallization to a grain size of around 250–750 μm, consistent with flow at low differential stresses. Fourier transform infrared (FTIR) spectroscopy reveals very low water contents in the interior of recrystallized grains (in the form of discrete OH peaks, ~20 H/10 6 Si and very little broad band absorption, <100 H/10 6 Si). The spectral characteristics are comparable to those of dry Brazil quartz. In FTIR spectra, magmatic quartz grains show a broad absorption band related with high water concentrations only in those areas where fluid inclusions are present while other areas are dry. Drainage of fluid inclusions and synkinematic growth of hydrous minerals indicates that a hydrous fluid has been available during deformation. Loss of intragranular water during grain boundary migration recrystallization did not result in a microstructure indicative of hardening. These FTIR measurements provide the first evidence that quartz with extremely low intragranular water contents can deform in nature by dislocation creep at low differential stresses. Low intragranular water contents in naturally deformed quartz may not be necessarily indicative of a high strength, and the results are contrary to implications taken from deformation experiments where very high water contents are required to allow dislocation creep in quartz. It is suggested that dislocation creep of quartz in the Truzzo meta-granite is possible to occur at low differential stresses because sufficient amounts of intergranular water ensure a high recovery rate by grain boundary migration while the absence of significant amounts of intragranular water is not crucial at natural conditions

The south-western Black Forest and the Upper Rhine Graben Main Border Fault: thermal history and hydrothermal fluid flow

The thermal history of the south-westernmost Black Forest (Germany) and the adjacent Upper Rhine Graben were constrained by a combination of apatite and zircon fission-track (FT) and microstructural analyses. After intrusion of Palaeozoic granitic plutons in the Black Forest, the thermal regime of the studied area re-equilibrated during the Late Permian and the Mesozoic, interrupted by enhanced hydrothermal activity during the Jurassic. At the eastern flank of the Upper Rhine Graben along the Main Border Fault the analysed samples show microstructural characteristics related to repeated tectonic and hydrothermal activities. The integration of microstructural observations of the cataclastic fault gouge with the FT data identifies the existence of repeated tectonic-related fluid flow events characterised by different thermal conditions. The older took place during the Variscan and/or Mesozoic time at temperatures lower than 280°C, whereas the younger was probably contemporary with the Cenozoic rifting of the Upper Rhine Graben at temperatures not higher than 150°

Experimental grain growth of quartz aggregates under wet conditions and its application to deformation in nature

Grain growth of quartz was investigated using two quartz samples (powder and novaculite) with water under pressure and temperature conditions of 1.0–2.5&thinsp;GPa and 800–1100&thinsp;∘C. The compacted powder preserved a substantial porosity, which caused a slower grain growth than in the novaculite. We assumed a grain growth law of dn-d0n=k0fH2Orexp⁡(-Q/RT)t with grain size d (µm) at time t (seconds), initial grain size d0 (µm), growth exponent n, a constant k0 (µmn&thinsp;MPa−r&thinsp;s−1), water fugacity fH2O (MPa) with the exponent r, activation energy Q (kJ&thinsp;mol−1), gas constant R, and temperature T in Kelvin. The parameters we obtained were n=2.5±0.4, k0=10-8.8±1.4, r=2.3±0.3, and Q=48±34 for the powder and n=2.9±0.4, k0=10-5.8±2.0, r=1.9±0.3, and Q=60±49 for the novaculite. The grain growth parameters obtained for the powder may be of limited use because of the high porosity of the powder with respect to crystalline rocks (novaculite), even if the differences between powder and novaculite vanish when grain sizes reach ∼70&thinsp;µm. Extrapolation of the grain growth laws to natural conditions indicates that the contribution of grain growth to plastic deformation in the middle crust may be small. However, grain growth might become important for deformation in the lower crust when the strain rate is &lt;&thinsp;10−12&thinsp;s−1.</p

Anticlockwise metamorphic pressure–temperature paths and nappe stacking in the Reisa Nappe Complex in the Scandinavian Caledonides, northern Norway: evidence for weakening of lower continental crust before and during continental collision

This study investigates the tectonostratigraphy and metamorphic and tectonic evolution of the Caledonian Reisa Nappe Complex (RNC; from bottom to top: Vaddas, Kåfjord, and Nordmannvik nappes) in northern Troms, Norway. Structural data, phase equilibrium modelling, and U-Pb zircon and titanite geochronology are used to constrain the timing and pressure–temperature (P–T) conditions of deformation and metamorphism during nappe stacking that facilitated crustal thickening during continental collision. Five samples taken from different parts of the RNC reveal an anticlockwise P–T path attributed to the effects of early Silurian heating (D1) followed by thrusting (D2). At ca. 439&thinsp;Ma during D1 the Nordmannvik Nappe reached the highest metamorphic conditions at ca. 780&thinsp;∘C and ∼9–11&thinsp;kbar inducing kyanite-grade partial melting. At the same time the Kåfjord Nappe was at higher, colder, levels of the crust ca. 600&thinsp;∘C, 6–7&thinsp;kbar and the Vaddas Nappe was intruded by gabbro at &gt;&thinsp;650&thinsp;∘C and ca. 6–9&thinsp;kbar. The subsequent D2 shearing occurred at increasing pressure and decreasing temperatures ca. 700&thinsp;∘C and 9–11&thinsp;kbar in the partially molten Nordmannvik Nappe, ca. 600&thinsp;∘C and 9–10&thinsp;kbar in the Kåfjord Nappe, and ca. 640&thinsp;∘C and 12–13&thinsp;kbar in the Vaddas Nappe. Multistage titanite growth in the Nordmannvik Nappe records this evolution through D1 and D2 between ca. 440 and 427&thinsp;Ma, while titanite growth along the lower RNC boundary records D2 shearing at 432±6&thinsp;Ma. It emerges that early Silurian heating (ca. 440&thinsp;Ma) probably resulted from large-scale magma underplating and initiated partial melting that weakened the lower crust, which facilitated dismembering of the crust into individual thrust slices (nappe units). This tectonic style contrasts with subduction of mechanically strong continental crust to great depths as seen in, for example, the Western Gneiss Region further south.</p