Focussing quantum states

Does the size of atoms present a lower limit to the size of electronic structures that can be fabricated in solids? This limit can be overcome by using devices that exploit quantum mechanical scattering of electron waves at atoms arranged in focussing geometries on selected surfaces. Calculations reveal that features smaller than a hydrogen atom can be obtained. These structures are potentially useful for device applications and offer a route to the fabrication of ultrafine and well defined tips for scanning tunneling microscopy.Comment: 4 pages, 4 figure

In-situ synchrotron X-ray diffraction data for the dynamic reaction processes between titanium and air under laser irradiation

This article presents data related to the research article entitled “Diffusion of oxygen and nitrogen into titanium under laser irradiation in air” [1]. When irradiated with varying laser parameters under ambient air, titanium surfaces are observed to exhibit differing colors. To better understand this phenomenon, the dynamic reaction steps between titanium and air under laser irradiation were investigated with in-situ synchrotron X-ray diffraction method. With a programmed laser profile, a set of diffraction patterns were collected by a 2D detector and then analyzed with the program FIT2D. Based on the data, the detailed high-temperature reactions between titanium and air during laser irradiation were clearly revealed. The presented raw in-situ synchrotron X-ray diffraction data can be reused for the further insights of laser surface modification of titanium in air, or for discovering the optimal laser conditions for industrial decoration or medical applications of titanium

Direct extraction of the Eliashberg function for electron-phonon coupling: A case study of Be(1010)

We propose a systematic procedure to directly extract the Eliashberg function for electron-phonon coupling from high-resolution angle-resolved photoemission data. The procedure is successfully applied to the Be(1010) surface, providing new insights to electron-phonon coupling at this surface. The method is shown to be robust against imperfections in experimental data and suitable for wider applications.Comment: 4 pages, 4 figures. More details concerning the procedure are include

Titanium and nitrogen interactions under laser additive manufacturing conditions

To understand how to make bulk titanium parts or coatings with desired levels of titanium nitrides, this paper investigates the dynamic interactions between titanium and nitrogen under representative laser-based additive manufacturing (AM) conditions. Under a set of gas environments containing different concentrations of nitrogen, the titanium and nitrogen reaction products—formed under typical Selective Laser Melting (SLM) and Laser Engineered Net Shaping (LENS) AM scanning conditions—are examined for compositions, phases, and microstructures. In-situ synchrotron X-ray diffraction (SXRD) test is performed to reveal the high temperature reaction steps between titanium and nitrogen

Looking at electronic wave functions on metal surfaces

The project described here is not only a beautiful example of the visual side tophysics, it is also a beautiful example of international cooperation. The first use of the idea—to apply a Fourier transform to STM pictures to see electron waves instead of just the surface atoms—came out of a collaboration between Plummer, Sprunger and the Aarhus group headed by Besenbacher. Hofman, who had beenworking at Tennessee, took Be(1010) samples to Berlin where the images shown in this pictorial were taken. All of the participants are now preparing a paper on the use of a Fourier transform to map the Fermi contour at metal surfaces

Real Space Observations of Magnesium Hydride Formation and Decomposition

The mechanisms of magnesium hydride formation and thermal decomposition are directly examined using in-situ imaging.Comment: 3 pages, 4 figure

Formation of environmentally persistent free radicals (EPFRs) on ZnO at room temperature: Implications for the fundamental model of EPFR generation.

Environmentally persistent free radicals (EPFRs) have significant environmental and public health impacts. In this study, we demonstrate that EPFRs formed on ZnO nanoparticles provide two significant surprises. First, EPR spectroscopy shows that phenoxy radicals form readily on ZnO nanoparticles at room temperature, yielding EPR signals similar to those previously measured after 250°C exposures. Vibrational spectroscopy supports the conclusion that phenoxy-derived species chemisorb to ZnO nanoparticles under both exposure temperatures. Second, DFT calculations indicate that electrons are transferred from ZnO to the adsorbed organic (oxidizing the Zn), the opposite direction proposed by previous descriptions of EPFR formation on metal oxides

Lattice-stiffening transition in copolymer films of vinylidene fluoride (70%) with trifluoroethylene (30%)

We report the discovery of a compressibility phase transition at 160 K in crystalline copolymer films of vinylidene fluoride (70%) with trifluoroethylene (30%). This phase transition is distinct from the known bulk ferroelectric-paraelectric phase transition at 353 K and surface ferroelectric phase transition at 295 K. The new phase transition is characterized by an increase in the effective Debye temperature from 48 to 245 K along the 〈010〉 direction as the temperature falls below 160 K. This phase transition is evident in neutron scattering, x-ray diffraction, angle-resolved photoemission, and in the dipole active phonon modes in electron energy-loss spectroscopy. © 1999 The American Physical Society