The Origin of Nitrogen on Jupiter and Saturn from the 15^{15}N/14^{14}N Ratio

The Texas Echelon cross Echelle Spectrograph (TEXES), mounted on NASA's Infrared Telescope Facility (IRTF), was used to map mid-infrared ammonia absorption features on both Jupiter and Saturn in February 2013. Ammonia is the principle reservoir of nitrogen on the giant planets, and the ratio of isotopologues ($^{15}$N/$^{14}$N) can reveal insights into the molecular carrier (e.g., as N$_2$ or NH$_3$) of nitrogen to the forming protoplanets, and hence the source reservoirs from which these worlds accreted. We targeted two spectral intervals (900 and 960 cm$^{-1}$) that were relatively clear of terrestrial atmospheric contamination and contained close features of $^{14}$NH$_3$ and $^{15}$NH$_3$, allowing us to derive the ratio from a single spectrum without ambiguity due to radiometric calibration (the primary source of uncertainty in this study). We present the first ground-based determination of Jupiter's $^{15}$N/$^{14}$N ratio (in the range from $1.4\times10^{-3}$ to $2.5\times10^{-3}$), which is consistent with both previous space-based studies and with the primordial value of the protosolar nebula. On Saturn, we present the first upper limit on the $^{15}$N/$^{14}$N ratio of no larger than $2.0\times10^{-3}$ for the 900-cm$^{-1}$ channel and a less stringent requirement that the ratio be no larger than $2.8\times10^{-3}$ for the 960-cm$^{-1}$ channel ($1\sigma$ confidence). Specifically, the data rule out strong $^{15}$N-enrichments such as those observed in Titan's atmosphere and in cometary nitrogen compounds. To the extent possible with ground-based radiometric uncertainties, the saturnian and jovian $^{15}$N/$^{14}$N ratios appear indistinguishable, implying that $^{15}$N-enriched ammonia ices could not have been a substantial contributor to the bulk nitrogen inventory of either planet, favouring the accretion of primordial N$_2$ from the gas phase or as low-temperature ices.Comment: 33 pages, 19 figures, manuscript accepted for publication in Icaru

Onto the farm, into the home: how intrahousehold gender dynamics shape land restoration in Eastern Kenya

While attention has been paid largely to forest restoration, meeting global land restoration pledges will require scaling-up restoration of ecosystem services on agricultural land. This paper contributes to the literature on restoration practice and agricultural technology adoption, by shifting the focus onto the farm and considering the role of intrahousehold dynamics in the uptake of farmland restoration practices. We examine the intrahousehold decisions and gender relations surrounding the trial of two on-farm restoration practices: tree planting and planting basins; with over 2,500 farmers in the eastern drylands of Kenya. Combining results from household surveys, interviews and focus group discussions, our findings reveal that decisions over the uptake of restoration practices, although usually initiated by women who attend agricultural workshops, are often discussed between husband and wife and that multiple social dimensions intersect to shape men's and women's interest in, contribution to, and benefit from different practices. Furthermore, our study demonstrates that these intrahousehold relations are, in turn, shaped by women's participation in innovation processes and broader societal changes, particularly the outmigration of rural men. Based on these insights, we offer recommendations for improving the dissemination and uptake of on-farm restoration practices in eastern Kenya and achieving more inclusive and gender-equitable outcomes

Zinc and DHA have opposing effects on the expression levels of histones H3 and H4 in human neuronal cells

Zn and DHA have putative neuroprotective effects and these two essential nutrients are known to interact biochemically. We aimed to identify novel protein candidates that are differentially expressed in human neuronal cell line M17 in response to Zn and DHA that would explain the molecular basis of this interaction. Two-dimensional gel electrophoresis and MS were applied to identify major protein expression changes in the protein lysates of human Ml7 neuronal cells that had been grown in the presence and absence of Zn and DHA. Proteomic findings were further investigated using Western immunoblot and real-time PCR analyses. Four protein spots, which had significant differential expression, were identified and selected for in-gel trypsin digestion followed by matrix-assisted laser desorption ionisation MS analysis. The resultant peptide mass fingerprint for each spot allowed their respective identities to be deduced. Two human histone variants H3 and H4 were identified. Both H3 and H4 were downregulated by Zn in the absence of DHA (Zn effect) and upregulated by DHA (DHA effect) in the presence of Zn (physiological condition). These proteomic findings were further supported by Western immunoblot and real-time PCR analyses using H3- and H4-specific monoclonal antibodies and oligonucleotide primers, respectively. We propose that dietary Zn and DHA cause a global effect on gene expression, which is mediated by histones. Such novel information provides possible clues to the molecular basis of neuroprotection by Zn and DHA that may contribute to the future treatment, prevention and management of neurodegenerative diseases such as Alzheimer\u27s disease.<br /

Working from Home and Walking during and after COVID

We investigate the relationship between people who worked from home during the pandemic and how often they walked before, during, and after COVID. We find that people who worked from home during the pandemic had the largest increases in walking frequency compared to people who did not work from home and people who were unemployed. Similarly, people who work from home also expect to walk more after the pandemic subsides compared to others. After controlling for socio-economic, demographic, and transportation factors, we found that working from home and having a high income are associated with a higher propensity of walking during and after the pandemic

Investigating Thermal Contrasts Between Jupiter's Belts, Zones, and Polar Vortices with VLT/VISIR

Using images at multiple mid-infrared wavelengths, acquired in May 2018 using the VISIR instrument on ESO's Very Large Telescope (VLT), we study Jupiter's pole-to-pole thermal, chemical and aerosol structure in the troposphere and stratosphere. We confirm that the pattern of cool and cloudy anticyclonic zones and warm cloud-free cyclonic belts persists throughout the mid-latitudes, up to the polar boundaries, and evidence a strong correlation with the vertical maximum windshear and the locations of Jupiter's zonal jets. At high latitudes, VISIR images reveal a large region of mid-infrared cooling poleward $\sim$64$^{\circ}$N and $\sim$67$^{\circ}$S extending from the upper troposphere to the stratosphere, co-located with the reflective aerosols observed by JunoCam, and suggesting that aerosols play a key role in the radiative cooling at the poles. Comparison of zonal-mean thermal properties and high-resolution visible imaging from Juno allows us to study the variability of atmospheric properties as a function of altitude and jet boundaries, particularly in the cold southern polar vortex. However, the southern stratospheric polar vortex is partly masked by a warm mid-infrared signature of the aurora. Co-located with the southern main auroral oval, this warming results from the auroral precipitation and/or joule heating which heat the atmosphere and thus cause a significant stratospheric emission. This high emission results from a large enhancement of both ethane and acetylene in the polar region, reinforcing the evidence of enhanced ion-related chemistry in Jupiter's auroral regions

Seasonal Evolution of Saturn's Polar Temperatures and Composition

The seasonal evolution of Saturn's polar atmospheric temperatures and hydrocarbon composition is derived from a decade of Cassini Composite Infrared Spectrometer (CIRS) 7-16 $\mu$m thermal infrared spectroscopy. We construct a near-continuous record of atmospheric variability poleward of 60$^\circ$ from northern winter/southern summer (2004, $L_s=293^\circ$) through the equinox (2009, $L_s=0^\circ$) to northern spring/southern autumn (2014, $L_s=56^\circ$). The hot tropospheric polar cyclones and the hexagonal shape of the north polar belt are both persistent features throughout the decade of observations. The hexagon vertices rotated westward by $\approx30^\circ$ longitude between March 2007 and April 2013, confirming that they are not stationary in the Voyager-defined System III longitude system as previously thought. The extended region of south polar stratospheric emission has cooled dramatically poleward of the sharp temperature gradient near 75$^\circ$S, coinciding with a depletion in the abundances of acetylene and ethane, and suggestive of stratospheric upwelling with vertical wind speeds of $w\approx+0.1$ mm/s. This is mirrored by a general warming of the northern polar stratosphere and an enhancement in acetylene and ethane abundances that appears to be most intense poleward of 75$^\circ$N, suggesting subsidence at $w\approx-0.15$ mm/s. However, the sharp gradient in stratospheric emission expected to form near 75$^\circ$N by northern summer solstice (2017, $L_s=90^\circ$) has not yet been observed, so we continue to await the development of a northern summer stratospheric vortex. North polar minima in tropospheric and stratospheric temperatures were detected in 2008-2010 (lagging one season, or 6-8 years, behind winter solstice); south polar maxima appear to have occurred before the start of the Cassini observations (1-2 years after summer solstice). [Abridged]Comment: Preprint of article accepted for publication in Icaru

Saturn's Seasonal Variability from Four Decades of Ground-Based Mid-Infrared Observations

A multi-decade record of ground-based mid-infrared (7-25 $\mu$m) images of Saturn is used to explore seasonal and non-seasonal variability in thermal emission over more than a Saturnian year (1984-2022). Thermal emission measured by 3-m and 8-m-class observatories compares favourably with synthetic images based on both Cassini-derived temperature records and the predictions of radiative climate models. 8-m class facilities are capable of resolving thermal contrasts on the scale of Saturn's belts, zones, polar hexagon, and polar cyclones, superimposed onto large-scale seasonal asymmetries. Seasonal changes in brightness temperatures of $\sim30$ K in the stratosphere and $\sim10$ K in the upper troposphere are observed, as the northern and southern polar stratospheric vortices (NPSV and SPSV) form in spring and dissipate in autumn. The timings of the first appearance of the warm polar vortices is successfully reproduced by radiative climate models, confirming them to be radiative phenomena, albeit entrained within sharp boundaries influenced by dynamics. Axisymmetric thermal bands (4-5 per hemisphere) display temperature gradients that are strongly correlated with Saturn's zonal winds, indicating winds that decay in strength with altitude, and implying meridional circulation cells forming the system of cool zones and warm belts. Saturn's thermal structure is largely repeatable from year to year (via comparison of infrared images in 1989 and 2018), with the exception of low-latitudes. Here we find evidence of inter-annual variations because the equatorial banding at 7.9 $\mu$m is inconsistent with a $\sim15$-year period for Saturn's equatorial stratospheric oscillation, i.e., it is not strictly semi-annual. Finally, observations between 2017-2022 extend the legacy of the Cassini mission, revealing the continued warming of the NPSV during northern summer. [Abr.]Comment: 25 pages, 15 figures, accepted for publication in Icaru