596 research outputs found
Effect of Ru susbstitution on atomic displacements in the layered SmFe_{1-x}Ru_xAsO_{0.85}F_{0.15} superconductor
The effect of Ru substitution on the local structure of layered
SmFeRuAsOF superconductor has been studied by As
- and Sm - edges x-ray-absorption spectroscopy. The extended
x-ray-absorption fine-structure measurements reveal distinct Fe-As and Ru-As
bondlengths in the Ru substituted samples with the latter being 0.03 \AA\
longer. Local disorder induced by the Ru substitution is mainly confined to the
FeAs layer while the SmO spacer layer sustains a relative order, consistent
with the x-ray-absorption near-edge structure spectra. The results suggest
that, in addition to the order/disorder in the active active iron-arsenide
layer, its coupling to the rare-earth\textminus oxygen spacer layer needs to be
considered for describing the electronic properties of these layered
superconductors
Temperature dependence of iron local magnetic moment in phase-separated superconducting chalcogenide
We have studied local magnetic moment and electronic phase separation in
superconducting KFeSe by x-ray emission and absorption
spectroscopy. Detailed temperature dependent measurements at the Fe K-edge have
revealed coexisting electronic phases and their correlation with the transport
properties. By cooling down, the local magnetic moment of Fe shows a sharp drop
across the superconducting transition temperature (T) and the coexisting
phases exchange spectral weights with the low spin state gaining intensity at
the expense of the higher spin state. After annealing the sample across the
iron-vacancy order temperature, the system does not recover the initial state
and the spectral weight anomaly at T as well as superconductivity
disappear. The results clearly underline that the coexistence of the low spin
and high spin phases and the transitions between them provide unusual magnetic
fluctuations and have a fundamental role in the superconducting mechanism of
electronically inhomogeneous KFeSe system.Comment: 6 pages, 5 figure
Orbital occupancies and the putative jeff = 1/2 groundstate in Ba2IrO4: a combined oxygen K edge XAS and RIXS study
The nature of the electronic groundstate of Ba2IrO4 has been addressed using
soft X-ray absorption and inelastic scattering techniques in the vicinity of
the oxygen K edge. From the polarization and angular dependence of XAS we
deduce an approximately equal superposition of xy, yz and zx Ir4+ 5d orbitals.
By combining the measured orbital occupancies, with the value of the spin-orbit
coupling provided by RIXS, we estimate the crystal field splitting associated
with the tetragonal distortion of the IrO6 octahedra to be small, \Delta=50(50)
meV. We thus conclude definitively that Ba2IrO4 is a close realization of a
spin-orbit Mott insulator with a jeff = 1/2 groundstate, thereby overcoming
ambiguities in this assignment associated with the interpretation of X-ray
resonant scattering experiments.Comment: 5 pages, 5 figure
Bimagnon studies in cuprates with Resonant Inelastic X-ray Scattering at the O K edge. I - An assessment on La2CuO4 and a comparison with the excitation at Cu L3 and Cu K edges
We assess the capabilities of magnetic Resonant Inelastic X-ray Scattering
(RIXS) at the O edge in undoped cuprates by taking La_{2}CuO_{4} as a
benchmark case, based on a series of RIXS measurements that we present here. By
combining the experimental results with basic theory we point out the
fingerprints of bimagnon in the O edge RIXS spectra. These are a dominant
peak around 450 meV, the almost complete absence of dispersion both with
and polarization and the almost constant intensity vs. the transferred
momentum with polarization. This behavior is quite different from Cu
edge RIXS giving a strongly dispersing bimagnon tending to zero at the
center of the Brillouin zone. This is clearly shown by RIXS measurements at the
Cu edge that we present. The Cu bimagnon spectra and those at Cu
edge - both from the literature and from our data - however, have the same
shape. These similarities and differences are understood in terms of different
sampling of the bimagnon continuum. This panorama points out the unique
possibilities offered by O RIXS in the study of magnetic excitations in
cuprates near the center of the BZ
Determination of the local structure of SrMIrO (M = K, La) as a function of doping and temperature
The local structure of correlated spin-orbit insulator SrMIrO
(M = K, La) has been investigated by Ir L-edge extended x-ray absorption
fine structure measurements. The measurements were performed as a function of
temperature for different dopings induced by substitution of Sr with La or K.
It is found that Ir-O bonds have strong covalency and they hardly show any
change across the N\'eel temperature. In the studied doping range, neither Ir-O
bonds nor their dynamics, measured by their mean square relative displacements,
show any appreciable change upon carrier doping, indicating possibility of a
nanoscale phase separation in the doped system. On the other hand, there is a
large increase of the static disorder in Ir-Sr correlation, larger for K doping
than La doping. Similarities and differences with respect to the local lattice
displacements in cuprates are briefly discussed.Comment: Main text: 6 pages, 4 figures, Supplemental information: 2 pages, 2
figure
Dissolution of coccolithophorid calcite by microzooplankton and copepod grazing
International audienceIndependent of the ongoing acidification of surface seawater, the majority of the calcium carbonate produced in the pelagial is dissolved by natural processes above the lysocline. We investigate to what extent grazing and passage of coccolithophorids through the guts of copepods and the food vacuoles of microzooplankton contribute to calcite dissolution. In laboratory experiments where the coccolithophorid Emiliania huxleyi was fed to the rotifer Brachionus plicatilis, the heterotrophic flagellate Oxyrrhis marina and the copepod Acartia tonsa, calcite dissolution rates of 45?55%, 37?53% and 5?22% of ingested calcite were found. We ascribe higher loss rates in microzooplankton food vacuoles as compared to copepod guts to the strongly acidic digestion and the individual packaging of algal cells. In further experiments, specific rates of calcification and calcite dissolution were also measured in natural populations during the PeECE III mesocosm study under differing ambient pCO2 concentrations. Microzooplankton grazing accounted for between 27 and 70% of the dynamic calcite stock being lost per day, with no measurable effect of CO2 treatment. These measured calcite dissolution rates indicate that dissolution of calcite in the guts of microzooplankton and copepods can account for the calcite losses calculated for the global ocean using budget and model estimates
Electronic Structure of CeFeAsO1-xFx (x=0, 0.11/x=0.12) compounds
We report an extensive study on the intrinsic bulk electronic structure of
the high-temperature superconductor CeFeAsO0.89F0.11 and its parent compound
CeFeAsO by soft and hard x-ray photoemission, x-ray absorption and soft-x-ray
emission spectroscopies. The complementary surface/bulk probing depth, and the
elemental and chemical sensitivity of these techniques allows resolving the
intrinsic electronic structure of each element and correlating it with the
local structure, which has been probed by extended-x-ray absorption fine
structure spectroscopy. The measurements indicate a predominant 4f1 (i.e. Ce3+)
initial state configuration for Cerium and an effective valence-band-to-4f
charge-transfer screening of the core hole. The spectra also reveal the
presence of a small Ce f0 initial state configuration, which we assign to the
occurrence of an intermediate valence state. The data reveal a reasonably good
agreement with the partial density of states as obtained in standard density
functional calculations over a large energy range. Implications for the
electronic structure of these materials are discussed.Comment: Accepted for publication in Phys. Rev.
Insights into drop-on-demand metal additive manufacturing through an integrated experimental and computational study
Drop-on-demand metal jetting is a recent additive manufacturing technology opening new opportunities for the fabrication of complex single and multi-metal components. MetalJet, the Océ developed technique used in this study, has the capacity to produce molten micro-droplets (60-80 µm) at temperatures up to 2000 °C to form single and multi-material objects. Applications for this technology include flexible circuits, advanced electronic components and biotechnologies. However, full exploitation of this technology is impeded by a lack of understanding of various aspects of the process, including droplet bonding and interface formation, residual stress development and the evolution of microstructure. This paper uses an integrated numerical and experimental approach to provide insights into these research questions. Thermal models were used to investigate droplet-to-substrate adhesion and explain the experimentally-observed morphology of droplets. Thermo-mechanical modelling was used to investigate residual stress development and its role in the observed droplet warping and delamination. The knowledge obtained from this study can be used to underpin the development of functional multi-material printing
The GINGER Project and status of the ring-laser of LNGS
A ring-laser attached to the Earth measures the absolute angular velocity of the Earth summed
to the relativistic precessions, de Sitter and Lense-Thirring. GINGER (Gyroscopes IN GEneral
Relativity) is a project aiming at measuring the LenseThirring effect with a ground based detector;
it is based on an array of ring-lasers. Comparing the Earth angular velocity measured
by IERS and the measurement done with the GINGER array, the Lense-Thirring effect can be
evaluated. Compared to the existing space experiments, GINGER provides a local measurement,
not the averaged value and it is unnecessary to model the gravitational field. It is a proposal,
but it is not far from being a reality. In fact the GrossRing G of the Geodesy Observatory of
Wettzell has a sensitivity very close to the necessary one. G ofWettzell is part of the IERS system
which provides the measure of the Length Of the DAY (LOD); G provides information on the fast
component of LOD. In the last few years, a roadmap toward GINGER has been outlined. The
experiment G-GranSasso, financed by the INFN Commission II, is developing instrumentations
and tests along the roadmap of GINGER. In this short paper the main activities of G-GranSasso
and some results will be presented. The first results of GINGERino will be reported, GINGERino
is the large ring-laser installed inside LNGS and now in the commissioning phase. Ring-lasers
provide as well important informations for geophysics, in particular the rotational seismology,
which is an emerging field of science. GINGERino is one of the three experiments of common
interest between INFN and INGV
Combined inkjet printing and infrared sintering of silver nanoparticles using a swathe-by-swathe and layer-by-layer approach for 3-dimensional structures
Despite the advancement of additive manufacturing (AM)/3-dimensional (3D) printing, single-step fabrication of multifunctional parts using AM is limited. With the view of enabling multifunctional AM (MFAM), in this study, sintering of metal nanoparticles was performed to obtain conductivity for continuous line inkjet printing of electronics. This was achieved using a bespoke three dimensional (3D) inkjet-printing machine, JETx®, capable of printing a range of materials and utilizing different post processing procedures to print multi-layered 3D structures in a single manufacturing step. Multiple layers of silver were printed from an ink containing silver nanoparticles (AgNPs) and infra-red sintered using a swathe-by-swathe (SS) and layer-by-layer sintering (LS) regime. The differences in the heat profile for the SS and LS was observed to influence the coalescence of the AgNPs. Void percentage of both SS and LS samples was higher towards the top layer than the bottom layer due to relatively less IR exposure in the top than the bottom. The results depicted a homogeneous microstructure for LS of AgNPs and showed less deformation compared to the SS. Electrical resistivity of the LS tracks (13.6 ± 1μΩ cm) was lower than the SS tracks (22.5 ± 1 μΩ cm). This study recommends the use of LS method to sinter the AgNPs to obtain a conductive track in 25% less time than SS method for MFAM
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