181 research outputs found
Order by disorder and spiral spin liquid in frustrated diamond lattice antiferromagnets
Frustration refers to competition between different interactions that cannot
be simultaneously satisfied, a familiar feature in many magnetic solids. Strong
frustration results in highly degenerate ground states, and a large suppression
of ordering by fluctuations. Key challenges in frustrated magnetism are
characterizing the fluctuating spin-liquid regime and determining the mechanism
of eventual order at lower temperature. Here, we study a model of a diamond
lattice antiferromagnet appropriate for numerous spinel materials. With
sufficiently strong frustration a massive ground state degeneracy develops
amongst spirals whose propagation wavevectors reside on a continuous
two-dimensional ``spiral surface'' in momentum space. We argue that an
important ordering mechanism is entropic splitting of the degenerate ground
states, an elusive phenomena called order-by-disorder. A broad ``spiral
spin-liquid'' regime emerges at higher temperatures, where the underlying
spiral surface can be directly revealed via spin correlations. We discuss the
agreement between these predictions and the well characterized spinel MnSc2S4
Spin Liquid Phases in 2D Frustrated XY Model
In this paper we consider the classical and quantum 2D XY
model. Spin wave calculations show that a spin liquid phase still exists in the
quantum case as for Heisenberg models. We formulate a semiclassical approach of
these models based on spin wave action and use a variational method to study
the role played by vortices. Liquid and crystal phases of vortex could emerge
in this description. These phases seem to be directly correlated with the spin
liquid one and to its crystalline interpretation.Comment: 16 pages, Latex, 4 figures. To be published in Phys. Rev.
A new class of ratiometric small molecule intracellular pH sensors for Raman microscopy
Intracellular pH (pHi) homeostasis is intertwined with a myriad of normal cellular behaviors as well as pathological processes. As such, small molecule probes for the measurement of pHi are invaluable tools for chemical biology, facilitating the study of the role of pH in cellular function and disease. The field of small molecule pHi sensors has traditionally been dominated with probes based on fluorescent scaffolds. In this study, a series of low molecular weight (<260) oligoyne compounds have been developed which exhibit pH sensitive alkyne stretching frequencies (νalkyne) in Raman spectroscopy. The modular design of the compounds enabled tuneability of their pKa(H) through simple structural modification, such that continuous pH sensitivity is achieved over the range 2-10. Alkyne stretching bands reside in the 'cell-silent' region of the Raman spectrum (1800-2600 cm-1) and are readily detectable in a cellular environment with subcellular spatial resolution. This enabled the application of a pH sensitive oligoyne compound to the ratiometric sensing of pHi in prostate cancer (PC3) cells in response to drug treatment. We propose that probes based on Alkyne Tag Raman Imaging offer an entirely new platform for the sensing of pHi, complementary to fluorescence microscopy
The fully frustrated XY model with next nearest neighbor interaction
We introduce a fully frustrated XY model with nearest neighbor (nn) and next
nearest neighbor (nnn) couplings which can be realized in Josephson junction
arrays. We study the phase diagram for ( is the ratio
between nnn and nn couplings). When an Ising and a
Berezinskii-Kosterlitz-Thouless transitions are present. Both critical
temperatures decrease with increasing . For the array
undergoes a sequence of two transitions. On raising the temperature first the
two sublattices decouple from each other and then, at higher temperatures, each
sublattice becomes disorderd.Comment: 11 pages, 5 figure
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