Flight/ground sample comparison relating to flight experiment M552, exothermic brazing

Comparisons were made between Skylab and ground-based specimens of nickel and stainless steel which were vacuum brazed using silver-copper-lithium alloy with various joint configurations. It was established that the absence of gravity greatly extends the scope of brazing since capillary flow can proceed without gravity interference. There was also evidence of enhanced transport, primarily in that liquid silver copper alloy dissolves nickel to a much greater extent in the zero gravity environment

A Robust and Universal Metaproteomics Workflow for Research Studies and Routine Diagnostics Within 24 h Using Phenol Extraction, FASP Digest, and the MetaProteomeAnalyzer

The investigation of microbial proteins by mass spectrometry (metaproteomics) is a key technology for simultaneously assessing the taxonomic composition and the functionality of microbial communities in medical, environmental, and biotechnological applications. We present an improved metaproteomics workflow using an updated sample preparation and a new version of the MetaProteomeAnalyzer software for data analysis. High resolution by multidimensional separation (GeLC, MudPIT) was sacrificed to aim at fast analysis of a broad range of different samples in less than 24 h. The improved workflow generated at least two times as many protein identifications than our previous workflow, and a drastic increase of taxonomic and functional annotations. Improvements of all aspects of the workflow, particularly the speed, are first steps toward potential routine clinical diagnostics (i.e., fecal samples) and analysis of technical and environmental samples. The MetaProteomeAnalyzer is provided to the scientific community as a central remote server solution at www.mpa.ovgu.de.Peer Reviewe

Quantum Manipulations of Small Josephson Junctions

Low-capacitance Josephson junction arrays in the parameter range where single charges can be controlled are suggested as possible physical realizations of the elements which have been considered in the context of quantum computers. We discuss single and multiple quantum bit systems. The systems are controlled by applied gate voltages, which also allow the necessary manipulation of the quantum states. We estimate that the phase coherence time is sufficiently long for experimental demonstration of the principles of quantum computation.Comment: RevTex, 15 pages,4 postscript figures, uuencoded, submitted to Phys. Rev. Lett., estimates of the experimental parameters correcte

Robustness of adiabatic passage trough a quantum phase transition

We analyze the crossing of a quantum critical point based on exact results for the transverse XY model. In dependence of the change rate of the driving field, the evolution of the ground state is studied while the transverse magnetic field is tuned through the critical point with a linear ramping. The excitation probability is obtained exactly and is compared to previous studies and to the Landau-Zener formula, a long time solution for non-adiabatic transitions in two-level systems. The exact time dependence of the excitations density in the system allows to identify the adiabatic and diabatic regions during the sweep and to study the mesoscopic fluctuations of the excitations. The effect of white noise is investigated, where the critical point transmutes into a non-hermitian ``degenerate region''. Besides an overall increase of the excitations during and at the end of the sweep, the most destructive effect of the noise is the decay of the state purity that is enhanced by the passage through the degenerate region.Comment: 16 pages, 15 figure

Lava channel formation during the 2001 eruption on Mount Etna: evidence for mechanical erosion

We report the direct observation of a peculiar lava channel that was formed near the base of a parasitic cone during the 2001 eruption on Mount Etna. Erosive processes by flowing lava are commonly attributed to thermal erosion. However, field evidence strongly suggests that models of thermal erosion cannot explain the formation of this channel. Here, we put forward the idea that the essential erosion mechanism was abrasive wear. By applying a simple model from tribology we demonstrate that the available data agree favorably with our hypothesis. Consequently, we propose that erosional processes resembling the wear phenomena in glacial erosion are possible in a volcanic environment.Comment: accepted for publication in Physical Review Letter

Field Emission Studies of Heat Treated Mo Substrates

Molybdenum can be used as a substrate for the bi alkali antimonide photocathodes utilized for the generation of high brightness electron beams in a superconducting radio frequency SRF photoinjector cavities. Operation at high field strength is required to obtain a low emittance beam, thus increasing the probability of field emission FE from the cathode surface. Usually, substrates are heated in situ before alkali de position to remove oxide layers from the surface. FE on Mo substrates was measured by means of a field emission scanning microscope FESM . It turned out that in situ heat treatment HT of the Mo surface significantly changes the FE behaviour by activation of new emitters. For a better understanding of the mechanism for enhanced emission after in situ heating a witness Mo sample was investigated using x ray photoelectron spectroscop

Reflection on multilayer mirrors beam profile and coherence properties

The main advantage of Bragg reflection from a multilayer mirror as a monochromator for hard X rays, is the higher photon flux density because of the larger spectral bandpass compared with crystal lattice reflection. The main disadvantage lies in the strong modulations of the reflected beam profile. This is a major issue for micro imaging applications, where multilayer based monochromators are frequently employed to deliver high photon flux density. A subject of particular interest is the origin of the beam profile modifications, namely the irregular stripe patterns, induced by the reflection on a multilayer. For multilayer coatings in general it is known that the substrate and its surface quality significantly influence the performance of mirrors, as the coating reproduces to a certain degree the roughness and shape of the substrate. This proceedings article reviews recent experiments that indicate potential options for producing wave front preserving multilayer mirrors, as well as new details on the particular mirrors our group has extensively studied in the pas

Charge Transport Processes in a Superconducting Single-Electron Transistor Coupled to a Microstrip Transmission Line

We have investigated charge transport processes in a superconducting single-electron transistor (S-SET) fabricated in close proximity to a two-dimensional electron gas (2DEG) in a GaAs/AlGaAs heterostructure. The macroscopic bonding pads of the S-SET along with the 2DEG form a microstrip transmission line. We observe a variety of current-carrying cycles in the S-SET which we attribute to simultaneous tunneling of Cooper pairs and emission of photons into the microstrip. We find good agreement between these experimental results and simulations including both photon emission and photon-assisted tunneling due to the electromagnetic environment.Comment: 4 pages, 4 figures, REVTeX

Sequential Voxel-Based Leaflet Segmentation of Complex Lipid Morphologies

[Image: see text] As molecular dynamics simulations increase in complexity, new analysis tools are necessary to facilitate interpreting the results. Lipids, for instance, are known to form many complicated morphologies, because of their amphipathic nature, becoming more intricate as the particle count increases. A few lipids might form a micelle, where aggregation of tens of thousands could lead to vesicle formation. Millions of lipids comprise a cell and its organelle membranes, and are involved in processes such as neurotransmission and transfection. To study such phenomena, it is useful to have analysis tools that understand what is meant by emerging entities such as micelles and vesicles. Studying such systems at the particle level only becomes extremely tedious, counterintuitive, and computationally expensive. To address this issue, we developed a method to track all the individual lipid leaflets, allowing for easy and quick detection of topological changes at the mesoscale. By using a voxel-based approach and focusing on locality, we forego costly geometrical operations without losing important details and chronologically identify the lipid segments using the Jaccard index. Thus, we achieve a consistent sequential segmentation on a wide variety of (lipid) systems, including monolayers, bilayers, vesicles, inverted hexagonal phases, up to the membranes of a full mitochondrion. It also discriminates between adhesion and fusion of leaflets. We show that our method produces consistent results without the need for prefitting parameters, and segmentation of millions of particles can be achieved on a desktop machine

Ordering a rhenium catalyst on Ag(001) through molecule-surface step interaction

In summary, our results present a comprehensive picture of the deposition and self-assembly of thermally stable rhenium com- plexes on the Ag(001) surface. All steps in the molecular growth of fac-Re(bpy)(CO)3Cl on silver rely on the availability of step edges aligned along 〈110〉. Using large-scale DFT calculations the growth hierarchy can be understood and interpreted in terms of the underlying molecular structures and the corresponding binding energies. Rearrangement of the substrate atoms is involved in the molecular cluster growth affecting the local step orientation. This promotes the formation of well-ordered struc- tures. The resulting long-range ordered 1D molecular wires are found to be the prerequisite for 2D growth resulting in long-range ordered molecular monolayers and finally for growing 3D structures. Our results show how well-designed surface mor- phology can be used to guide and control molecular self-assembly in 1D, 2D as well as 3D