427 research outputs found
Diblock copolymers at a homopolymer-homopolymer-interface: a Monte Carlo simulation
The properties of diluted symmetric A-B diblock copolymers at the interface
between A and B homopolymer phases are studied by means of Monte Carlo (MC)
simulations of the bond fluctuation model. We calculate segment density
profiles as well as orientational properties of segments, of A and B blocks,
and of the whole chain. Our data support the picture of oriented ``dumbbells'',
which consist of mildly perturbed A and B Gaussian coils. The results are
compared to a self consistent field theory (SCFT) for single copolymer chains
at a homopolymer interface. We also discuss the number of interaction contacts
between monomers, which provide a measure for the ``active surface'' of
copolymers or homopolymers close to the interface
A symmetric polymer blend confined into a film with antisymmetric surfaces: interplay between wetting behavior and phase diagram
We study the phase behavior of a symmetric binary polymer blend which is
confined into a thin film. The film surfaces interact with the monomers via
short range potentials. We calculate the phase behavior within the
self-consistent field theory of Gaussian chains. Over a wide range of
parameters we find strong first order wetting transitions for the semi-infinite
system, and the interplay between the wetting/prewetting behavior and the phase
diagram in confined geometry is investigated. Antisymmetric boundaries, where
one surface attracts the A component with the same strength than the opposite
surface attracts the B component, are applied. The phase transition does not
occur close to the bulk critical temperature but in the vicinity of the wetting
transition. For very thin films or weak surface fields one finds a single
critical point at . For thicker films or stronger surface fields
the phase diagram exhibits two critical points and two concomitant coexistence
regions. Only below a triple point there is a single two phase coexistence
region. When we increase the film thickness the two coexistence regions become
the prewetting lines of the semi-infinite system, while the triple temperature
converges towards the wetting transition temperature from above. The behavior
close to the tricritical point, which separates phase diagrams with one and two
critical points, is studied in the framework of a Ginzburg-Landau ansatz.
Two-dimensional profiles of the interface between the laterally coexisting
phases are calculated, and the interfacial and line tensions analyzed. The
effect of fluctuations and corrections to the self-consistent field theory are
discussed.Comment: Phys.Rev.E in prin
A closer look at the uncertainty relation of position and momentum
We consider particles prepared by the von Neumann-L\"uders projection. For
those particles the standard deviation of the momentum is discussed. We show
that infinite standard deviations are not exceptions but rather typical. A
necessary and sufficient condition for finite standard deviations is given.
Finally, a new uncertainty relation is derived and it is shown that the latter
cannot be improved.Comment: 3 pages, introduction shortened, content unchange
Direct measurement of antiferromagnetic domain fluctuations
Measurements of magnetic noise emanating from ferromagnets due to domain
motion were first carried out nearly 100 years ago and have underpinned much
science and technology. Antiferromagnets, which carry no net external magnetic
dipole moment, yet have a periodic arrangement of the electron spins extending
over macroscopic distances, should also display magnetic noise, but this must
be sampled at spatial wavelengths of order several interatomic spacings, rather
than the macroscopic scales characteristic of ferromagnets. Here we present the
first direct measurement of the fluctuations in the nanometre-scale spin-
(charge-) density wave superstructure associated with antiferromagnetism in
elemental Chromium. The technique used is X-ray Photon Correlation
Spectroscopy, where coherent x-ray diffraction produces a speckle pattern that
serves as a "fingerprint" of a particular magnetic domain configuration. The
temporal evolution of the patterns corresponds to domain walls advancing and
retreating over micron distances. While the domain wall motion is thermally
activated at temperatures above 100K, it is not so at lower temperatures, and
indeed has a rate which saturates at a finite value - consistent with quantum
fluctuations - on cooling below 40K. Our work is important because it provides
an important new measurement tool for antiferromagnetic domain engineering as
well as revealing a fundamental new fact about spin dynamics in the simplest
antiferromagnet.Comment: 19 pages, 4 figure
FUSE Observations of Molecular Hydrogen in Translucent Interstellar Clouds: The Line of Sight Toward HD 73882
We report the results of initial FUSE observations of molecular hydrogen (H2)
in translucent clouds. These clouds have greater optical depth than any of the
diffuse clouds previously observed for far-UV H2 absorption, and provide new
insights into the physics and chemistry of such regions. Our initial results
involve observations of HD 73882, a well-studied southern hemisphere star lying
behind substantial interstellar material (E(B-V) = 0.72; A_V = 2.44). We find a
total H2 column density, N(H2) = 1.2 x 10^{21} cm^{-2}, about three times
larger than the values for diffuse clouds previously measured in the far-UV.
The gas kinetic temperature indicated by the ratio N(J=1)/N(J=0) is 58 +/- 10
K. With the aid of ground-based data to calculate an appropriate
multi-component curve of growth, we have determined column densities for all
rotational levels up to J = 7. The J >= 2 states can be reasonably fitted with
a rotational excitation temperature of 307 +/- 23 K. Both the kinetic and
rotational temperatures are similar to those found in previous investigations
of diffuse clouds. The ratios of carbonaceous molecules to hydrogen molecules
are also similar to ratios in diffuse clouds, suggesting a similar chemistry
for this line of sight.Comment: 7 pages, 3 figures, to appear in ApJ Letters (FUSE first-results
issue
Overview of the Far Ultraviolet Spectroscopic Explorer Mission
The Far Ultraviolet Spectroscopic Explorer satellite observes light in the
far-ultraviolet spectral region, 905 - 1187 A with high spectral resolution.
The instrument consists of four coaligned prime-focus telescopes and Rowland
spectrographs with microchannel plate detectors. Two of the telescope channels
use Al:LiF coatings for optimum reflectivity from approximately 1000 to 1187 A
and the other two use SiC coatings for optimized throughput between 905 and
1105 A. The gratings are holographically ruled to largely correct for
astigmatism and to minimize scattered light. The microchannel plate detectors
have KBr photocathodes and use photon counting to achieve good quantum
efficiency with low background signal. The sensitivity is sufficient to examine
reddened lines of sight within the Milky Way as well as active galactic nuclei
and QSOs for absorption line studies of both Milky Way and extra-galactic gas
clouds. This spectral region contains a number of key scientific diagnostics,
including O VI, H I, D I and the strong electronic transitions of H2 and HD.Comment: To appear in FUSE special issue of the Astrophysical Journal Letters.
6 pages + 4 figure
DETERMINATION OF TYPES OF INDIVIDUALS IN APHIDS, ROTIFERS AND CLADOCERA 1
Peer Reviewedhttp://deepblue.lib.umich.edu/bitstream/2027.42/72827/1/j.1469-185X.1929.tb00888.x.pd
Statistical characteristics of formation and evolution of structure in the universe
An approximate statistical description of the formation and evolution of
structure of the universe based on the Zel'dovich theory of gravitational
instability is proposed. It is found that the evolution of DM structure shows
features of self-similarity and the main structure characteristics can be
expressed through the parameters of initial power spectrum and cosmological
model. For the CDM-like power spectrum and suitable parameters of the
cosmological model the effective matter compression reaches the observed scales
20 -- 25Mpc with the typical mean separation of
wall-like elements 50 -- 70Mpc. This description can be
directly applied to the deep pencil beam galactic surveys and absorption
spectra of quasars. For larger 3D catalogs and simulations it can be applied to
results obtained with the core-sampling analysis.
It is shown that the interaction of large and small scale perturbations
modulates the creation rate of early Zel'dovich pancakes and generates bias on
the SLSS scale. For suitable parameters of the cosmological model and reheating
process this bias can essentially improve the characteristics of simulated
structure of the universe.
The models with give the best description of the
observed structure parameters. The influence of low mass "warm" dark matter
particles, such as a massive neutrino, will extend the acceptable range of
and .Comment: 20pages, 7 figures, MNRAS in pres
The Interstellar Environment of our Galaxy
We review the current knowledge and understanding of the interstellar medium
of our galaxy. We first present each of the three basic constituents - ordinary
matter, cosmic rays, and magnetic fields - of the interstellar medium, laying
emphasis on their physical and chemical properties inferred from a broad range
of observations. We then position the different interstellar constituents, both
with respect to each other and with respect to stars, within the general
galactic ecosystem.Comment: 39 pages, 12 figures (including 3 figures in 2 parts
- …