Determination of trace amounts of Brown HT as a food dye by a CPE-scanometry method

AbstractIn this study, trace amounts of Brown HT were extracted, pre-concentrated and determined by cloud point extraction-scanometry (CPE-scanometry) as a simple, fast and inexpensive method. The procedure is based on CPE of Brown HT from an aqueous solution, diluting the extracted surfactant-rich phase with ethanol to 500μL, transferring the appropriate volume to Plexiglas® cells and scanning the cells. Then, the colour of each cell was analyzed by software written in visual basic (VB 6) into red, green and blue values. Effective parameters for the extraction efficiency, such as the pH of the system, the concentration of surfactant, the equilibration temperature and equilibration time, were investigated and optimized. Under optimal conditions, the calibration curve was linear in the range of 0.06–2.60mgL−1. The detection limit of the proposed method was 0.04mgL−1. In addition, the effects of some foreign species, including cations, anions and dyes, were investigated. The method was applied successfully for the determination of Brown HT in some water samples

Online Coding for Reliable Data Transfer in Lossy Wireless Sensor Networks

Abstract. Bulk transport underlies data exfiltration and code update facilities in WSNs, but existing approaches are not designed for highly lossy and variable-quality links. We observe that Maymounkov’s rateless online codes are asymptotically more efficient, but can perform poorly in the WSN operating region. We analyze and optimize coding parameters and present the design and evaluation of RTOC, a protocol for bulk transport that recovered over 95 % of application data despite up to 84% packet loss in a MicaZ network.

Network coding as a coloring problem (Invited paper)

We consider a multicast configuration with two sources, and translate the network code design problem to vertex coloring of an appropriately defined graph. This observation enables to derive code design algorithms and alphabet size bounds, as well as establish a connection with a number of well-known results from discrete mathematics that increase our insight in the different trade-offs possible for network coding

Coding Schemes for Line Networks

We consider a simple network, where a source and destination node are connected with a line of erasure channels. It is well known that in order to achieve the min-cut capacity, the intermediate nodes are required to process the information. We propose coding schemes for this setting, and discuss each scheme in terms of complexity, delay, achievable rate, memory requirement, and adaptability to unknown channel parameters. We also briefly discuss how these schemes can be extended to more general networks

Long Distance Continuous-Variable Quantum Key Distribution with a Gaussian Modulation

We designed high-efficiency error correcting codes allowing to extract an errorless secret key in a continuous-variable quantum key distribution protocol using a Gaussian modulation of coherent states and a homodyne detection. These codes are available for a wide range of signal-to-noise ratios on an AWGN channel with a binary modulation and can be combined with a multidimensional reconciliation method proven secure against arbitrary collective attacks. This improved reconciliation procedure considerably extends the secure range of a continuous-variable quantum key distribution with a Gaussian modulation, giving a secret key rate of about 10^{-3} bit per pulse at a distance of 120 km for reasonable physical parameters.Comment: 8 pages, 5 figures, 5 table

Photodynamic antimicrobial chemotherapy coupled with the use of the photosensitizers methylene blue and temoporfin as a potential novel treatment for Staphylococcus aureus in burn infections

Photodynamic antimicrobial chemotherapy (PACT) is a novel alternative antimicrobial therapy that elicits a broad mechanism of action and therefore has a low probability of generating resistance. Such properties make PACT ideally suited for utilization in localized applications such as burn wounds. The aim of this study was to determine the antimicrobial activity of MB and temoporfin against both a S. aureus isolate and a P. aeruginosa isolate in light (640 nm) and dark conditions at a range of time points (0–20 min). A Staphylococcus aureus isolate and a Pseudomonas aeruginosa isolate were treated in vitro with methylene blue (MB) and temoporfin under different conditions following exposure to light at 640 nm and in no-light (dark) conditions. Bacterial cell viability [colony-forming units (c.f.u.) ml−1] was then calculated. Against P. aeruginosa , when MB was used as the photosensitizer, no phototoxic effect was observed in either light or dark conditions. After treatment with temoporfin, a reduction of less than one log (7.00×107 c.f.u. ml−1) was observed in the light after 20 min of exposure. However, temoporfin completely eradicated S. aureus in both light and dark conditions after 1 min (where a seven log reduction in c.f.u. ml−1 was observed). Methylene blue resulted in a loss of S. aureus viability, with a two log reduction in bacterial viability (c.f.u. ml−1) reported in both light and dark conditions after 20 min exposure time. Temoporfin demonstrated greater antimicrobial efficacy than MB against both the S. aureus and P. aeruginosa isolates tested. At 12.5 µM temoporfin resulted in complete eradication of S. aureus . In light of this study, further research into the validity of PACT, coupled with the photosensitizers (such as temoporfin), should be conducted in order to potentially develop alternative antimicrobial treatment regimes for burn wounds.</jats:p

Irregular behaviour of class numbers and Euler-Kronecker constants of cyclotomic fields: the log log log devil at play

Kummer (1851) and, many years later, Ihara (2005) both posed conjectures on invariants related to the cyclotomic field $\mathbb Q(\zeta_q)$ with $q$ a prime. Kummer's conjecture concerns the asymptotic behaviour of the first factor of the class number of $\mathbb Q(\zeta_q)$ and Ihara's the positivity of the Euler-Kronecker constant of $\mathbb Q(\zeta_q)$ (the ratio of the constant and the residue of the Laurent series of the Dedekind zeta function $\zeta_{\mathbb Q(\zeta_q)}(s)$ at $s=1$). If certain standard conjectures in analytic number theory hold true, then one can show that both conjectures are true for a set of primes of natural density 1, but false in general. Responsible for this are irregularities in the distribution of the primes. With this survey we hope to convince the reader that the apparently dissimilar mathematical objects studied by Kummer and Ihara actually display a very similar behaviour.Comment: 20 pages, 1 figure, survey, to appear in `Irregularities in the Distribution of Prime Numbers - Research Inspired by Maier's Matrix Method', Eds. J. Pintz and M. Th. Rassia

Statistical Mechanics Analysis of LDPC Coding in MIMO Gaussian Channels

Using analytical methods of statistical mechanics, we analyse the typical behaviour of a multiple-input multiple-output (MIMO) Gaussian channel with binary inputs under LDPC network coding and joint decoding. The saddle point equations for the replica symmetric solution are found in particular realizations of this channel, including a small and large number of transmitters and receivers. In particular, we examine the cases of a single transmitter, a single receiver and the symmetric and asymmetric interference channels. Both dynamical and thermodynamical transitions from the ferromagnetic solution of perfect decoding to a non-ferromagnetic solution are identified for the cases considered, marking the practical and theoretical limits of the system under the current coding scheme. Numerical results are provided, showing the typical level of improvement/deterioration achieved with respect to the single transmitter/receiver result, for the various cases.Comment: 25 pages, 7 figure