Correlating phase behavior with photophysical properties in mixed‐cation mixed‐halide perovskite thin films

Mixed cation perovskites currently achieve very promising efficiency and operational stability when used as the active semiconductor in thin‐film photovoltaic devices. However, an in‐depth understanding of the structural and photophysical properties that drive this enhanced performance is still lacking. Here the prototypical mixed‐cation mixed‐halide perovskite (FAPbI3)0.85(MAPbBr3)0.15 is explored, and temperature‐dependent X‐ray diffraction measurements that are correlated with steady state and time‐resolved photoluminescence data are presented. The measurements indicate that this material adopts a pseudocubic perovskite α phase at room temperature, with a transition to a pseudotetragonal β phase occurring at ≈260 K. It is found that the temperature dependence of the radiative recombination rates correlates with temperature‐dependent changes in the structural configuration, and observed phase transitions also mark changes in the gradient of the optical bandgap. The work illustrates that temperature‐dependent changes in the perovskite crystal structure alter the charge carrier recombination processes and photoluminescence properties within such hybrid organic–inorganic materials. The findings have significant implications for photovoltaic performance at different operating temperatures, as well as providing new insight on the effect of alloying cations and halides on the phase behavior of hybrid perovskite materials

Resistive Exercise for Arthritic Cartilage Health (REACH): A randomized double-blind, sham-exercise controlled trial

<p>Abstract</p> <p>Background</p> <p>This article provides the rationale and methodology, of the first randomised controlled trial to our knowledge designed to assess the efficacy of progressive resistance training on cartilage morphology in women with knee osteoarthritis.</p> <p>Development and progression of osteoarthritis is multifactorial, with obesity, quadriceps weakness, joint malalignment, and abnormal mechanical joint forces particularly relevant to this study. Progressive resistance training has been reported to improve pain and disability in osteoarthritic cohorts. However, the disease-modifying potential of progressive resistance training for the articular cartilage degeneration characteristic of osteoarthritis is unknown. Our aim was to investigate the effect of high intensity progressive resistance training on articular cartilage degeneration in women with knee osteoarthritis.</p> <p>Methods</p> <p>Our cohort consisted of women over 40 years of age with primary knee osteoarthritis, according to the American College of Rheumatology clinical criteria. Primary outcome was blinded measurement of cartilage morphology via magnetic resonance imaging scan of the tibiofemoral joint. Secondary outcomes included walking endurance, balance, muscle strength, endurance, power, and velocity, body composition, pain, disability, depressive symptoms, and quality of life.</p> <p>Participants were randomized into a supervised progressive resistance training or sham-exercise group. The progressive resistance training group trained muscles around the hip and knee at 80% of their peak strength and progressed 3% per session, 3 days per week for 6 months. The sham-exercise group completed all exercises except hip adduction, but without added resistance or progression. Outcomes were repeated at 3 and 6 months, except for the magnetic resonance imaging scan, which was only repeated at 6 months.</p> <p>Discussion</p> <p>Our results will provide an evaluation of the disease-modifying potential of progressive resistance training for osteoarthritis.</p> <p>Trial Registration</p> <p>ANZCTR Reference No. 12605000116628</p

The Fishery Performance Indicators: A Management Tool for Triple Bottom Line Outcomes

Pursuit of the triple bottom line of economic, community and ecological sustainability has increased the complexity of fishery management; fisheries assessments require new types of data and analysis to guide science-based policy in addition to traditional biological information and modeling. We introduce the Fishery Performance Indicators (FPIs), a broadly applicable and flexible tool for assessing performance in individual fisheries, and for establishing cross-sectional links between enabling conditions, management strategies and triple bottom line outcomes. Conceptually separating measures of performance, the FPIs use 68 individual outcome metrics—coded on a 1 to 5 scale based on expert assessment to facilitate application to data poor fisheries and sectors—that can be partitioned into sector-based or triple-bottom-line sustainability-based interpretative indicators. Variation among outcomes is explained with 54 similarly structured metrics of inputs, management approaches and enabling conditions. Using 61 initial fishery case studies drawn from industrial and developing countries around the world, we demonstrate the inferential importance of tracking economic and community outcomes, in addition to resource status

Guidelines and Safety Practices for Improving Patient Safety

AbstractThis chapter explains why clinical practice guidelines are needed to improve patient safety and how further research into safety practices can successfully influence the guideline development process. There is a description of the structured process by which guidelines that aim to increase the likelihood of a higher score are created. Proposals are made relating to (a) the live updating of individual guideline recommendations and (b) tackling challenges related to the improvement of guidelines

Robust Arduino controlled spin coater using a novel and simple gravity chuck design

Spin coaters offer an invaluable method of thin film fabrication. Various implementations, both proprietary and open-source exist, offering vacuum and gravity samples chucks. These implementations vary in their reliability, ease-of-use, cost, and versatility. Here we present a novel easy-to-use open-source gravity-chuck type spin coater with minimal points of failure at a material cost of around 100 USD (1500 ZAR). The unique chuck design makes use of interchangeable brass plate sample masks, each specific to a sample size, these can be made with basic skills and common hand tools. In comparison, replacement chucks for commercial alternatives can cost as much as the entire spin coater we present. Open-source hardware such as this provides an example for individuals in the field on the design and development of hardware where reliability, cost, and flexibility are most important, as is the case for many institutions in developing countries

Robust Arduino controlled spin coater using a novel and simple gravity chuck design

Spin coaters offer an invaluable method of thin film fabrication. Various implementations, both proprietary and open-source exist, offering vacuum and gravity samples chucks. These implementations vary in their reliability, ease-of-use, cost, and versatility. Here we present a novel easy-to-use open-source gravity-chuck type spin coater with minimal points of failure at a material cost of around 100 USD (1500 ZAR). The unique chuck design makes use of interchangeable brass plate sample masks, each specific to a sample size, these can be made with basic skills and common hand tools. In comparison, replacement chucks for commercial alternatives can cost as much as the entire spin coater we present. Open-source hardware such as this provides an example for individuals in the field on the design and development of hardware where reliability, cost, and flexibility are most important, as is the case for many institutions in developing countries

Robust Arduino controlled spin coater using a novel and simple gravity chuck design

Spin coaters offer an invaluable method of thin film fabrication. Various implementations, both proprietary and open-source exist, offering vacuum and gravity samples chucks. These implementations vary in their reliability, ease-of-use, cost, and versatility. Here we present a novel easy-to-use open-source gravity-chuck type spin coater with minimal points of failure at a material cost of around 100 USD (1500 ZAR). The unique chuck design makes use of interchangeable brass plate sample masks, each specific to a sample size, these can be made with basic skills and common hand tools. In comparison, replacement chucks for commercial alternatives can cost as much as the entire spin coater we present. Open-source hardware such as this provides an example for individuals in the field on the design and development of hardware where reliability, cost, and flexibility are most important, as is the case for many institutions in developing countries.THIS DATASET IS ARCHIVED AT DANS/EASY, BUT NOT ACCESSIBLE HERE. TO VIEW A LIST OF FILES AND ACCESS THE FILES IN THIS DATASET CLICK ON THE DOI-LINK ABOV

Robust Arduino controlled spin coater using a novel and simple gravity chuck design

Spin coaters offer an invaluable method of thin film fabrication. Various implementations, both proprietary and open-source exist, offering vacuum and gravity samples chucks. These implementations vary in their reliability, ease-of-use, cost, and versatility. Here we present a novel easy-to-use open-source gravity-chuck type spin coater with minimal points of failure at a material cost of around 100 USD (1500 ZAR). The unique chuck design makes use of interchangeable brass plate sample masks, each specific to a sample size, these can be made with basic skills and common hand tools. In comparison, replacement chucks for commercial alternatives can cost as much as the entire spin coater we present. Open-source hardware such as this provides an example for individuals in the field on the design and development of hardware where reliability, cost, and flexibility are most important, as is the case for many institutions in developing countries.THIS DATASET IS ARCHIVED AT DANS/EASY, BUT NOT ACCESSIBLE HERE. TO VIEW A LIST OF FILES AND ACCESS THE FILES IN THIS DATASET CLICK ON THE DOI-LINK ABOV