129 research outputs found
"When I Enter": Black Women and Disruption of the White, Heteronormative Narrative of Librarianship
Book Chapter; Version of Recor
Vortex Reconnection as the Dissipative Scattering of Dipoles
We propose a phenomenological model of vortex tube reconnection at high
Reynolds numbers. The basic picture is that squeezed vortex lines, formed by
stretching in the region of closest approach between filaments, interact like
dipoles (monopole-antimonopole pairs) of a confining electrostatic theory. The
probability of dipole creation is found from a canonical ensemble spanned by
foldings of the vortex tubes, with temperature parameter estimated from the
typical energy variation taking place in the reconnection process. Vortex line
reshuffling by viscous diffusion is described in terms of directional
transitions of the dipoles. The model is used to fit with reasonable accuracy
experimental data established long ago on the symmetric collision of vortex
rings. We also study along similar lines the asymmetric case, related to the
reconnection of non-parallel vortex tubes.Comment: 8 pages, 3 postscript figure
Motile dislocations knead odd crystals into whorls
The competition between thermal fluctuations and potential forces governs the stability of matter in equilibrium, in particular the proliferation and annihilation of topological defects. However, driving matter out of equilibrium allows for a new class of forces that are neither attractive nor repulsive, but rather transverse. The possibility of activating transverse forces raises the question of how they affect basic principles of material self-organization and control. Here we show that transverse forces organize colloidal spinners into odd elastic crystals crisscrossed by motile dislocations. These motile topological defects organize into a polycrystal made of grains with tunable length scale and rotation rate. The self-kneading dynamics drive super-diffusive mass transport, which can be controlled over orders of magnitude by varying the spinning rate. Simulations of both a minimal model and fully resolved hydrodynamics establish the generic nature of this crystal whorl state. Using a continuum theory, we show that both odd and Hall stresses can destabilize odd elastic crystals, giving rise to a generic state of crystalline active matter. Adding rotations to a material’s constituents has far-reaching consequences for continuous control of structures and transport at all scales.The National Science Foundation (NSF) under award no. DMR-2011854.
NSF DMR-1905974, NSF EFRI NewLAW 1741685 and the Packard Foundation.
NSF grants DMR-1420073 (NYU-MRSEC) and DMR-2004469.
ARN grant WTF and IdexLyon Tore.
The National Science Foundation Graduate Research Fellowship under grant no. 1746045. D.B.
The Chicago-France FACCTS programme.
‘la Caixa’ Foundation (ID 100010434), fellowship LCF/BQ/PI20/11760014 and from the European Union’s Horizon 2020 research and innovation programme under Marie Skłodowska-Curie grant agreement no. 847648.
NSF DMR-1828629 and US NSF grant no. DMR-201185
Analytic solutions and Singularity formation for the Peakon b--Family equations
Using the Abstract Cauchy-Kowalewski Theorem we prove that the -family
equation admits, locally in time, a unique analytic solution. Moreover, if the
initial data is real analytic and it belongs to with , and the
momentum density does not change sign, we prove that the
solution stays analytic globally in time, for . Using pseudospectral
numerical methods, we study, also, the singularity formation for the -family
equations with the singularity tracking method. This method allows us to follow
the process of the singularity formation in the complex plane as the
singularity approaches the real axis, estimating the rate of decay of the
Fourier spectrum
Criticality in confined ionic fluids
A theory of a confined two dimensional electrolyte is presented. The positive
and negative ions, interacting by a potential, are constrained to move on
an interface separating two solvents with dielectric constants and
. It is shown that the Debye-H\"uckel type of theory predicts that
the this 2d Coulomb fluid should undergo a phase separation into a coexisting
liquid (high density) and gas (low density) phases. We argue, however, that the
formation of polymer-like chains of alternating positive and negative ions can
prevent this phase transition from taking place.Comment: RevTex, no figures, in press Phys. Rev.
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Isolation of Discrete Nanoparticle-DNA Conjugates for Plasmonic Applications
Discrete DNA-gold nanoparticle conjugates with DNA lengths as short as 15 bases for both 5 nm and 20 nm gold particles have been purified by anion-exchange HPLC. Conjugates comprising short DNA (_ 20 nm) are difficult to purify by other means, and are potential substrates for plasmon coupling experiments. Conjugate purity is demonstrated by hybridizing complementary conjugates to form discrete structures, which are visualized by TEM
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Enzymatic Ligation Creates Discrete Multi-Nanoparticle Building Blocks for Self-Assembly
Enzymatic ligation of discrete nanoparticle?DNA conjugates creates nanoparticle dimer and trimer structures in which the nanoparticles are linked by single-stranded DNA, rather than double-stranded DNA as in previous experiments. Ligation is verified by agarose gel and small-angle X-ray scattering. This capability is utilized in two ways: first to create a new class of multiparticle building blocks for nanoscale self-assembly; second to develop a system which can amplify a population of discrete nanoparticle assemblies
Dipolar origin of the gas-liquid coexistence of the hard-core 1:1 electrolyte model
We present a systematic study of the effect of the ion pairing on the
gas-liquid phase transition of hard-core 1:1 electrolyte models. We study a
class of dipolar dimer models that depend on a parameter R_c, the maximum
separation between the ions that compose the dimer. This parameter can vary
from sigma_{+/-} that corresponds to the tightly tethered dipolar dimer model,
to R_c --> infinity, that corresponds to the Stillinger-Lovett description of
the free ion system. The coexistence curve and critical point parameters are
obtained as a function of R_c by grand canonical Monte Carlo techniques. Our
results show that this dependence is smooth but non-monotonic and converges
asymptotically towards the free ion case for relatively small values of R_c.
This fact allows us to describe the gas-liquid transition in the free ion model
as a transition between two dimerized fluid phases. The role of the unpaired
ions can be considered as a perturbation of this picture.Comment: 16 pages, 13 figures, submitted to Physical Review
Roadmap on Li-ion battery manufacturing research
Growth in the Li-ion battery market continues to accelerate, driven primarily by the increasing need for economic energy storage for electric vehicles. Electrode manufacture by slurry casting is the first main step in cell production but much of the manufacturing optimisation is based on trial and error, know-how and individual expertise. Advancing manufacturing science that underpins Li-ion battery electrode production is critical to adding to the electrode manufacturing value chain. Overcoming the current barriers in electrode manufacturing requires advances in materials, manufacturing technology, in-line process metrology and data analytics, and can enable improvements in cell performance, quality, safety and process sustainability. In this roadmap we explore the research opportunities to improve each stage of the electrode manufacturing process, from materials synthesis through to electrode calendering. We highlight the role of new process technology, such as dry processing, and advanced electrode design supported through electrode level, physics-based modelling. Progress in data driven models of electrode manufacturing processes is also considered. We conclude there is a growing need for innovations in process metrology to aid fundamental understanding and to enable feedback control, an opportunity for electrode design to reduce trial and error, and an urgent imperative to improve the sustainability of manufacture
An Integrated TCGA Pan-Cancer Clinical Data Resource to Drive High-Quality Survival Outcome Analytics
For a decade, The Cancer Genome Atlas (TCGA) program collected clinicopathologic annotation data along with multi-platform molecular profiles of more than 11,000 human tumors across 33 different cancer types. TCGA clinical data contain key features representing the democratized nature of the data collection process. To ensure proper use of this large clinical dataset associated with genomic features, we developed a standardized dataset named the TCGA Pan-Cancer Clinical Data Resource (TCGA-CDR), which includes four major clinical outcome endpoints. In addition to detailing major challenges and statistical limitations encountered during the effort of integrating the acquired clinical data, we present a summary that includes endpoint usage recommendations for each cancer type. These TCGA-CDR findings appear to be consistent with cancer genomics studies independent of the TCGA effort and provide opportunities for investigating cancer biology using clinical correlates at an unprecedented scale. Analysis of clinicopathologic annotations for over 11,000 cancer patients in the TCGA program leads to the generation of TCGA Clinical Data Resource, which provides recommendations of clinical outcome endpoint usage for 33 cancer types
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