Comparison of dimensionally-split and multi-dimensional atmospheric transport schemes for long time-steps

Dimensionally split advection schemes are attractive for atmospheric modelling due to their efficiency and accuracy in each spatial dimension. Accurate long time steps can be achieved without significant cost using the flux-form semi-Lagrangian technique. The dimensionally split scheme used in this paper is constructed from the one-dimensional Piecewise Parabolic Method and extended to two dimensions using COSMIC splitting. The dimensionally split scheme is compared with a genuinely multi-dimensional, method of lines scheme which, with implicit time-stepping, is stable for Courant numbers significantly larger than one. Two-dimensional advection test cases on Cartesian planes are proposed that avoid the complexities of a spherical domain or multi-panel meshes. These are solid body rotation, horizontal advection over orography and deformational flow. The test cases use distorted non-orthogonal meshes either to represent sloping terrain or to mimic the distortions near cubed-sphere edges. Mesh distortions are expected to accentuate the errors associated with dimension splitting, however, the accuracy of the dimensionally split scheme decreases only a little in the presence of mesh distortions. The dimensionally split scheme also loses some accuracy when long time-steps are used. The multi-dimensional scheme is almost entirely insensitive to mesh distortions and asymptotes to second-order accuracy at high resolution. As is expected for implicit time-stepping, phase errors occur when using long time-steps but the spatially well-resolved features are advected at the correct speed and the multi-dimensional scheme is always stable. A naive estimate of computational cost (number of multiplies) reveals that the implicit scheme is the most expensive, particularly for large Courant numbers. If the multi-dimensional scheme is used instead with explicit time-stepping, the Courant number is restricted to less than one, the accuracy is maintained and the cost becomes similar to the dimensionally split scheme

Laboratory Method to Estimate Rain-Induced Splitting in Cultivated Blueberries

Preharvest rainfall that occurs when fruit are fully ripe or approaching full ripeness can result in detrimental fruit splitting in rabbiteye and southern highbush blueberries. This study was initiated to develop a laboratory method to model rain-related incidence of splitting in cultivated blueberries with the goal of predicting the incidence of splitting in blueberry cultivars and selections. Multiyear field surveys of rabbiteye and southern highbush cultivars show that the incidence of rain-related splitting is strongly cultivar-dependent. Laboratory values for forced splitting and naturally occurring rain-related field splitting data show a strong correlation indicating that the incidence of fruit splitting can be accurately estimated by this laboratory method. Soaking the berries in distilled water 14 h at room temperature gives a confident determination of splitting tendencies. Blueberry breeders and geneticists can use this method to evaluate new potential blueberry cultivars for splitting tendencies as part of routine screening. This would lead to a long-term goal of reducing splitting susceptible blueberry cultivars in commercial plantings

An efficient stable optical polariser module for calibration of the S4UVN earth observation satellite

We describe here an optical polariser module intended to deliver well characterised polarised light to an imaging spectrometer instrument. The instrument in question is the Sentinel-4/UVN Earth observation imaging spectrometer due to be deployed in 2019 in a geostationary orbit. The polariser module described here will be used in the ground based calibration campaign for this instrument. One critical task of the calibration campaign will be the highly accurate characterisation of the polarisation sensitivity of instrument. The polariser module provides a constant, uniform source of linearly polarised light whose direction can be adjusted without changing the output level or uniformity of the illumination. A critical requirement of the polariser module is that the illumination is uniform across the exit pupil. Unfortunately, a conventional Glan-Taylor arrangement cannot provide this uniformity due to the strong variation in transmission at a refractive surface for angles close to the critical angle. Therefore a modified prism arrangement is proposed and this is described in detail. Detailed tolerance modelling and straylight modelling is also reported here

Eighteenth Year of the Gulf of Maine Environmental Monitoring Program

This report summarizes the metals and organic contaminant data associated with the collection and analyses of blue mussel (Mytilus edulis) tissue from selected sites along the Gulf of Maine coast during the 2008 sampling season. Contaminant monitoring is conducted by the Gulfwatch Program for the Gulf of Maine Council on the Marine Environment (GOMC). A subset of these data is compared with analytical results from earlier Gulfwatch monitoring (2001-2007). Statistical analyses are limited to descriptive measures of replicates from selected sampling sites and include: arithmetic means, and appropriate measures of variance. The primary purpose of this report is to present the current annual results, present graphical representation of spatial and temporal trends and identify potential outliers in order to provide investigators and other interested persons with contemporary information concerning water quality in the Gulf of Maine, as reflected by uptake into resident shellfish (mussels and clams)

Orbit Determination and Navigation of the Solar Terrestrial Relations Observatory (STEREO)

This paper provides an overview of the required upgrades necessary for navigation of NASA's twin heliocentric science missions, Solar TErestrial RElations Observatory (STEREO) Ahead and Behind. The orbit determination of the STEREO spacecraft was provided by the NASA Goddard Space Flight Center's (GSFC) Flight Dynamics Facility (FDF) in support of the mission operations activities performed by the Johns Hopkins University Applied Physics Laboratory (APL). The changes to FDF's orbit determination software included modeling upgrades as well as modifications required to process the Deep Space Network X-band tracking data used for STEREO. Orbit results as well as comparisons to independently computed solutions are also included. The successful orbit determination support aided in maneuvering the STEREO spacecraft, launched on October 26, 2006 (00:52 Z), to target the lunar gravity assists required to place the spacecraft into their final heliocentric drift-away orbits where they are providing stereo imaging of the Sun

Redox-active metallodithiolene groups separated by insulating tetraphosphinobenzene spacers

Compounds of the type [(S2C2R2)M(μ-tpbz)M(S2C2R2)] (R = CN, Me, Ph, p-anisyl; M = Ni, Pd, Pt; tpbz = 1,2,4,5-tetrakis(diphenylphosphino)benzene) have been prepared by transmetalation with [(S2C2R2)SnR′2] reagents, by direct displacement of dithiolene ligand from [M(S2C2R2)2] with 0.5 equiv of tpbz, or by salt metathesis using Na2[S2C2(CN)2] in conjunction with X2M(μ-tpbz)MX2 (X = halide). X-ray crystallography reveals a range of topologies (undulating, chair, bowed) for the (S2C2)M(P2C6P2)M(S2C2) core. The [(S2C2R2)M(μ-tpbz)M(S2C2R2)] (R = Me, Ph, p-anisyl) compounds support reversible or quasireversible oxidations corresponding to concurrent oxidation of the dithiolene terminal ligands from ene-1,2-dithiolates to radical monoanions, forming [(−S•SC2R2)M(μ-tpbz)M(−S•SC2R2)]2+. The R = Ph and p-anisyl compounds support a second, reversible oxidation of the dithiolene ligands to their α-dithione form. In contrast, [(S2C2(CN)2)Ni(tpbz)Ni(S2C2(CN)2)] sustains only reversible, metal-centered reductions. Spectroscopic examination of [(−S•SC2(p-anisyl)2)Ni(μ-tpbz)Ni(−S•SC2(p-anisyl)2)]2+ by EPR reveals a near degenerate singlet–triplet ground state, with spectral simulation revealing a remarkably small dipolar coupling constant of 18 × 10–4 cm–1 that is representative of an interspin distance of 11.3 Å. This weak interaction is mediated by the rigid tpbz ligand, whose capacity to electronically insulate is an essential quality in the development of molecular-based spintronic devices

Perception of Barbell Velocity: Can Individuals Accurately Perceive Changes in Velocity?

The aim of the study was to investigate whether resistance-trained participants can accurately predict changes in barbell velocity, specifically in the deadlift exercise, without feedback from velocity based training (VBT) devices. Seventeen participants (16 male, 1 female; age = 24.7 ± 3.8) were randomized in a counterbalanced, crossover design two experimental sessions that consisted of three sets of Deadlift at 60-and-80% one-repetition maximum (1RM). The number of repetitions were determined by the participants as they were asked to terminate each set when they felt the barbell velocity had reduced by 20%, relative to repetition one. A binomial mixed effects regression model was used to assess the accuracy of participants ability to stop after reaching at least 20% velocity loss. Participants tended to underestimate their proximity to 20% velocity loss and thus had relatively low probability of correctly stopping after reaching this threshold. There was only a 10.49% probability that people could perceive at least 20% velocity loss greater than chance (i.e., 50% probability). Our data, suggests that most participants cannot accurately perceive changes in velocity without exposure to augmented feedback