An eco-friendly dyeing of woolen yarn by Terminalia chebula extract with evaluations of kinetic and adsorption characteristics

In the present study Terminalia chebula was used as an eco-friendly natural colorant for sustainable textile coloration of woolen yarn with primary emphasis on thermodynamic and kinetic adsorption aspects of dyeing processes. Polyphenols and ellagitannins are the main coloring components of the dye extract. Assessment of the effect of pH on dye adsorption showed an increase in adsorption capacity with decreasing pH. Effect of temperature on dye adsorption showed 80 °C as optimum temperature for wool dyeing with T. chebula dye extract. Two kinetic equations, namely pseudo first-order and pseudo second-order equations, were employed to investigate the adsorption rates. Pseudo second-order model provided the best fit (R2 = 0.9908) to the experimental data. The equilibrium adsorption data were fitted by Freundlich and Langmuir isotherm models. The adsorption behavior accorded well (R2 = 0.9937) with Langmuir isotherm model. Variety of eco-friendly and sustainable shades were developed in combination with small amount of metallic mordants and assessed in terms of colorimetric (CIEL∗a∗b∗ and K/S) properties measured using spectrophotometer under D65 illuminant (10° standard observer). The fastness properties of dyed woolen yarn against light, washing, dry and wet rubbing were also evaluated

Dyeing studies and fastness properties of brown naphtoquinone colorant extracted from Juglans regia L on natural protein fiber using different metal salt mordants

In this study, wool fibers are dyed with a natural colorant extracted from walnut bark in presence and absence of mordants. The effect of aluminum sulfate, ferrous sulfate, and stannous chloride mordants on colorimetric and fastness properties of wool fibers was investigated. Juglone was identified as the main coloring component in walnut bark extract by UV visible and FTIR spectroscopic techniques. The results showed that pretreatment with metallic mordants substantially improved the colorimetric and fastness properties of wool fibers dyed with walnut bark extract. Ferrous sulfate and stannous chloride mordanted wool fibers shows best results than potassium aluminum sulfate mordanted and unmordanted wool fibers. This is ascribed due to strong chelating power of ferrous sulfate and stannous chloride mordants

Square pegs in round holes: the mental health needs of young adults and how well these are met by services – an explorative study

YesPurpose – This research paper aims to examine the mental health needs of young adults and to discuss how well these are met from the vantage‐point of the patients. Young adulthood is identified as an epidemiological risk for developing mental health problems and so the care provided during these developmental years is investigated to assess efficacy and experience. Design/methodology/approach – After interviewing 35 young adults, it was found most people are aware of the genesis to their problems and have strong views about the level of support and types of treatments offered. Findings – Like other writings, this research finds that many of the needs presented by young adults are unique to this transitional phase in life and administratively determined age structures on which current mental health care is configured do not adequately meet these needs. Research limitations/implications – The small sample size (35) and the geographical region covered means caution should be exercised in drawing any generalisations. Further research on outcomes after the mid‐20s by reflecting on service experience during the 18‐25 transformational years would be a useful area for exploration. Practical implications – This paper makes some powerful recommendations on why service provision must meet service user needs and how the recent equality legislation may provide impetus to this. All of this needs to start with examining the age boundaries on which mental healthcare is designed

Yield and water productivity of rice as influenced by responsive drip irrigation, alternate wetting and drying versus conventional flooding under silty loam soil texture

Rice is a semi-aquatic crop, thus demands waterlogged condition in root zone, hence farmers generally puddle the land before transplanting to control deep drainage losses, which is destructive to the soil physical, chemical and biological health. Addressing these issues, this research study evaluated the yield and water productivity (WP) benefits of rice (PK 1121) for the un-puddled alternate wetting and drying (AWD) and responsive drip irrigation (RDI) against the conventional flooding (CF) with puddling, as control during 2021, using randomized complete block design with three replicates. The results indicated significantly less (p ≤ 0.05) irrigation application (76% < CF) but with larger (18%) yield trade-off for the RDI treatment. Although, the AWD treatment showed comparatively less water saving (32% < CF) but resulted relatively higher yield (4% > CF). Nevertheless, the WP of RDI was significantly higher (249% > CF) but reduction in irrigation application was the main contributor. In contrast, both higher yield and reduced irrigation contributed to the higher WP (52% > CF) of AWD treatment. The study shows the prospects of increased WP by AWD at convenience and less cost, than the RDI system for PK 1121 rice variety. However, increasing the water release capacity of RDI or using drought tolerant variety may increase the WP of rice under RDI system at no yield trade-off, which may be instrumental for growing rice without puddling in the water scarce areas of the country

A Monte Carlo Comparative Simulation Study for Identification of the Best Performing Panel Cointegration Tests

In this paper the performance of nine panel cointegration tests, having the null hypothesis of no cointegration, with respect to weighted average rank scores under the whole space of alternative using Monte Carlo simulations have been carried out. Our results indicate that PdPtp, PAWS and PdP_V tests are the only three best performing tests among all panel cointegration tests whether time and cross sectional dimensions are small, medium or large. However, PDFTstar, PDFTrhostar and PdGtp panel cointegration tests have also identified as best performer at large cross sectional dimensions

Dairy Staphylococcus aureus: Epidemiology, Drug Susceptibilities, Drug Modulation, and Preventive Measures

Staphylococcus aureus is an emerging pathogen from dairy animals’ mammary glands. Among various risk factors associated with this pathogen are unhygienic milking procedures, improper preventive techniques, and lack of germicidal teat dipping before and after milking. Methicillin-resistant S. aureus, coagulase positive S. aureus, vancomycin-resistant S. aureus, and biofilm-producing S. aureus are common strains of S. aureus being isolated from dairy milk these days. They have huge economic and public health concerns. Trials of antibiotic susceptibility proposed variable responses, while drug modulation and drug synergistic proved to be hope for its treatment. Some of the plant derivative, phages, and nanoparticles are non-antibiotic sources to treat S. aureus. Various attempts to treat S. aureus at the world level have been carried out but require more researches to be undertaken in order to prevent it. The chapter concludes that S. aureus from dairy needs equal attention as is given to S. aureus from the human origin, and researches are required to probe solutions

Revolutionizing Agriculture: Nano Fertilizers for Sustainable Crop Improvement

The abundant metalloid element silicon (Si) is present in the crust of the Earth and is important for improving many aspects of plant characteristics. The potential of silicon in agriculture is examined in this article with particular attention to how it affects crop improvement, stress management, and plant growth. Under certain pH circumstances, plant roots absorb orthosilicic acid, the form of silicon that is accessible to plants in soil. The benefits of Si application, including improved vegetative growth, development, and resistance to biotic and abiotic stress, have been demonstrated by numerous studies. Additionally, silica plays a role in decreased transpiration, enhanced photosynthesis, and UV-B radiation protection. Agricultural crops encounter a multitude of difficulties, such as pathogens, pests, drought, flooding, salinity, and metal toxicity, which are frequently intensified by inadequate silicon availability in soils. To remedy this deficiency, si fertilizers are used, which improves plant function. It is further important to fertilize with Si because certain crops actively accumulate Si in their tissues. Applications of Si take into account the fertility of the soil, the amount of moisture present, and the uptake of nutrients, resulting in enhanced growth, productivity, and resilience to stress. Si increases stem strength, stress tolerance, and lodging resistance, for instance, in rice. Moreover, silica boosts water use efficiency in drought-stricken maize and modifies proline levels in upland rice in response to water restrictions. Eventually, Si-based compounds have a great deal of promise to improve crop yield and solve the problems facing contemporary agriculture. The numerous advantages of applying Si in supporting resilient and sustainable agriculture are highlighted in this review

Analysis of Human Gait Cycle with Body Equilibrium based on leg Orientation

Gait analysis identifies the posture during movement in order to provide the correct actions for a normal gait. A person\u27s gait may differ from others and can be recognized by specific patterns. Healthy individuals exhibit normal gait patterns, while lower limb amputees exhibit abnormal gait patterns. To better understand the pitfalls of gait, it is imperative to develop systems capable of capturing the gait patterns of healthy individuals. The main objective of this research was to introduce a new concept in gait analysis by computing the static and dynamic equilibrium in a real-world environment. A relationship was also presented among the parameters stated as static \& dynamic equilibrium, speed, and body states. A sensing unit was installed on the designed metal-based leg mounting assembly on the lateral side of the leg. An algorithm was proposed based on two variables: the position of the leg in space and the angle of the knee joint measured by an IMU sensor and a rotary encoder. It was acceptable to satisfy the static conditions when the body was in a fixed position and orientation, whether lying down or standing. While walking and running, the orientation is determined by the position and knee angle variables, which fulfill the dynamic condition. High speed reveals a rapid change in orientation, while slow speed reveals a slow change in orientation. The proposed encoder-based feedback system successfully determined the flexion at 47$^\circ$, extension at 153$^\circ$, and all seven gait cycle phases were recognized within this range of motion. Body equilibrium facilitates individuals when they are at risk of falling or slipping