Esterification of Acetic Acid with Butanol: Operation in a Packed Bed Reactive Distillation Column

The esterification reaction between acetic acid and butanol was investigated in a reactive distillation column. The thermodynamic aspects of considered system are discussed, equilibrium constant, vapor pressures and UNIQUAC interaction parameters were investigated. Reactive distillation experiments were carried out to provide high purity butyl acetate. For this purpose, a 2 m column with nonreactive and reactive zones filled with Amberlyst 15 and Raschig rings, were used in the experiments. Several operating conditions such as total feed flow rate, molar ratio of butanol to acetic acid, amount of catalyst and reboiler temperature and three different column configurations were realized experimentally. The experimental optimum values of these parameters obtained were 1.6 mol h–1, 1, 25 g and 383 K, respectively within the range of study. The butyl acetate purity of 82 % and acetic acid conversion of 80.5 % were obtained at the optimum operating conditions

Anisotropic cosmological solutions to the Y(R)F2Y(R)F^2 gravity

We investigate anisotropic cosmological solutions of the theory with non-minimal couplings between electromagnetic fields and gravity in $Y(R) F^2$ form. After we derive the field equations by the variational principle, we look for spatially flat cosmological solutions with magnetic fields or electric fields. Then we give exact anisotropic solutions by assuming the hyperbolic expansion functions. We observe that the solutions approach to the isotropic case in late-times.Comment: 16 pages, 5 figure

Civil Society in Turkey: At a Turning Point

Civil society in Turkey is going through a rapid transformation. Civil society's building blocks, civil society organisations, are emerging as important actors in Turkey's development and democratisation agendas, while increasing in their numbers and impact. In this context, generating a useful and comprehensive knowledge base has a crucial role to play in promoting the health of the third sector in Turkey. TUSEV has strengthened the sector through its Publications and Research Programme, which has produced over 50 valuable publications on the third sector in Turkey. The CIVICUS Civil Society Index (CSI) project holds a special place among these initiatives. Not only did the first CSI implementation result in the first comprehensive and internationally comparative study on civil society in Turkey, but now the second implementation expands its scope even further and offers readers an opportunity to make comparisons over a five year period

FT-IR and Raman vibrational analysis, B3LYP and M06-2X simulations of 4-bromomethyl-6-tert-butyl-2H-chromen-2-one

In this study, the experimental and theoretical vibrational frequencies of a newly synthesized bacteriostatic and anti-tumor molecule namely, 4-bromomethyl-6-tert-butyl-2H-chromen-2-one have been investigated. The experimental FT-IR (4000-400 cm- 1) and Raman spectra (4000-100 cm- 1) of the compound in solid phase have been recorded. The theoretical vibrational frequencies and optimized geometric parameters have been calculated using density functional theory (DFT/B3LYP: Becke, 3-parameter, Lee-Yang-Parr and DFT/M06-2X: highly parametrized, empirical exchange correlation function) with 6-311++G(d, p) basis set by Gaussian 03 software, for the first time. The assignments of the vibrational frequencies have been done by potential energy distribution (PED) analysis using VEDA 4 software. The theoretical optimized geometric parameters and vibrational frequencies have been found to be in good agreement with the corresponding experimental data and results in the literature. In addition, the highest occupied molecular orbital (HOMO) energy, the lowest unoccupied molecular orbital (LUMO) energy and the other related molecular energy values of the compound have been investigated using the same theoretical calculations. © 2014 Elsevier B.V. All rights reserved

Yeast biota of naturally fermented black olives in different brines made from cv. Gemlik grown in various districts of the Cukurova region of Turkey

In this study, the yeast microbiota of naturally fermented black olives made from cv. Gemlik, grown in three different districts of the Çukurova region of Turkey, were investigated. Fermentations were conducted for 180 days in three different brines, including NaCl 10% w/v, NaCl 8% w/v and NaCl 8% w/v added with glucose 0.5%. In total, 223 yeasts were isolated and then identified by PCR–RFLP analysis of the 5.8S ITS rRNA region and sequence information for the D1/D2 domains of the 26S rRNA gene. A broad range of yeast biodiversity was identified, including eight genera and nine species. Candida boidinii (41%), Wickerhamomyces anomalus (32%) and Saccharomyces sp. (18%) were predominant yeasts throughout the fermentations. To a lesser extent, the other species, Candida aaseri, Meyerozyma sp., Zygoascus hellenicus, Pichia kudriavzevii, Schwanniomyces etchellsii and Candida atlantica were also members of the olive-fermenting microbiota. In Tarsus and Bahçe districts C. boidinii and in Serinyol district Saccharomyces sp. were the most frequently identified species. W. anomalus was the most frequently isolated species (by 48% of total yeasts) in NaCl 10% brines. C. boidinii was the most dominant species in the brines, including NaCl 8% and NaCl 8% + glucose 0.5%, with frequencies of 42% and 61%, respectively. At the end of the 180 days of fermentation, total acidity values of the brines were in the range 1.04–8.1 g/l lactic acid. Copyright © 2016 John Wiley & Sons, Ltd

Comparative pharmacodynamic and pharmacokinetic characteristics of subcutaneous insulin glulisine and insulin aspart prior to a standard meal in obese subjects with type 2 diabetes

Aims: A multinational, randomized, double-blind, two-way crossover trial to compare the pharmacokinetic and pharmacodynamic properties of bolus, subcutaneously administered insulin glulisine (glulisine) and insulin aspart (aspart) in insulin-naÏve, obese subjects with type 2 diabetes

Towards detecting media bias by utilizing user comments

Automatic detection of media bias is an important and challenging problem. We propose to leverage user comments along with the content of the online news articles to automatically identify the latent aspects of a given news topic, as a first step of detecting the news resources that are biased towards a particular subset of such aspects. © 2016 Copyright held by the owner/author(s)

Dirac field in topologically massive gravity

We consider a Dirac field coupled minimally to the Mielke-Baekler model of gravity and investigate cosmological solutions in three dimensions. We arrive at a family of solutions which exists even in the limit of vanishing cosmological constant.Comment: 12 pages. Title changed. Conclusion extended. Appendix added. To appear in Gen. Rel. Gra

Enhanced He-alpha emission from "smoked" Ti targets irradiated with 400nm, 45 fs laser pulses

We present a study of He-like 1s(2)-1s2p line emission from solid and low-density Ti targets under similar or equal to 45 fs laser pulse irradiation with a frequency doubled Ti: Sapphire laser. By varying the beam spot, the intensity on target was varied from 10(15) W/cm(2) to 10(19) W/cm(2). At best focus, low density "smoked" Ti targets yield similar to 20 times more He-alpha than the foil targets when irradiated at an angle of 45 degrees with s-polarized pulses. The duration of He-alpha emission from smoked targets, measured with a fast streak camera, was similar to that from Ti foils