XPS characterization of silver electrodes and catalyst for oxygen reduction

The combined analysis of the silver GDE using an ex-situ surface sensitive technique (XPS) and in-situ electrochemical measurements (EIS, CV) show that the performance of the silver GDE is significantly influenced by the degree of degradation of the electrodes, e. g., the reduction of the active surface due to the decomposition of the PTFE. These findings indicate a different degree of decomposition of the PTFE on the on the GDE

Tunable multi-photon Rabi oscillations in an electronic spin system

We report on multi-photon Rabi oscillations and controlled tuning of a multi-level system at room temperature (S=5/2 for Mn2+:MgO) in and out of a quasi-harmonic level configuration. The anisotropy is much smaller than the Zeeman splittings, such as the six level scheme shows only a small deviation from an equidistant diagram. This allows us to tune the spin dynamics by either compensating the cubic anisotropy with a precise static field orientation, or by microwave field intensity. Using the rotating frame approximation, the experiments are very well explained by both an analytical model and a generalized numerical model. The calculated multi-photon Rabi frequencies are in excellent agreement with the experimental data

Stationary distributions of sums of marginally chaotic variables as renormalization group fixed points

We determine the limit distributions of sums of deterministic chaotic variables in unimodal maps assisted by a novel renormalization group (RG) framework associated to the operation of increment of summands and rescaling. In this framework the difference in control parameter from its value at the transition to chaos is the only relevant variable, the trivial fixed point is the Gaussian distribution and a nontrivial fixed point is a multifractal distribution with features similar to those of the Feigenbaum attractor. The crossover between the two fixed points is discussed and the flow toward the trivial fixed point is seen to consist of a sequence of chaotic band mergers.Comment: 7 pages, 2 figures, to appear in Journal of Physics: Conf.Series (IOP, 2010

International public administrations on Twitter: a comparison of digital authority in global climate policy

International organizations and their secretariats, called international public administrations (IPAs), have been found to hold considerable authority in world politics. This study conceptualizes and measures IPA authority in the digital sphere. It proposes the concept of digital authority to measure the authority of actors in online social networks (OSN), such as Twitter. Applying exponential random graph models (ERGMs) based on Twitter data during climate change negotiations the article compares the authority of IPAs to that of other actors. The findings show that IPAs are attributed as much authority as state actors in global climate communication networks on Twitter.info:eu-repo/semantics/acceptedVersio

Crystal structures and proton dynamics in potassium and cesium hydrogen bistrifluoroacetate salts with strong symmetric hydrogen bonds

The crystal structures of potassium and cesium bistrifluoroacetates were determined at room temperature and at 20 K and 14 K, respectively, with the single crystal neutron diffraction technique. The crystals belong to the I2/a and A2/a monoclinic space groups, respectively, and there is no visible phase transition. For both crystals, the trifluoroacetate entities form dimers linked by very short hydrogen bonds lying across a centre of inversion. Any proton disorder or double minimum potential can be rejected. The inelastic neutron scattering spectral profiles in the OH stretching region between 500 and 1000 cm^{-1} previously published [Fillaux and Tomkinson, Chem. Phys. 158 (1991) 113] are reanalyzed. The best fitting potential has the major characteristics already reported for potassium hydrogen maleate [Fillaux et al. Chem. Phys. 244 (1999) 387]. It is composed of a narrow well containing the ground state and a shallow upper part corresponding to dissociation of the hydrogen bond.Comment: 31 pages, 7 figure

Development of Lumped Element Kinetic Inductance Detectors for NIKA

Lumped-element kinetic inductance detectors(LEKIDs) have recently shown considerable promise as direct absorption mm-wavelength detectors for astronomical applications. One major research thrust within the N\'eel Iram Kids Array (NIKA) collaboration has been to investigate the suitability of these detectors for deployment at the 30-meter IRAM telescope located on Pico Veleta in Spain. Compared to microwave kinetic inductance detectors (MKID), using quarter wavelength resonators, the resonant circuit of a LEKID consists of a discrete inductance and capacitance coupled to a feedline. A high and constant current density distribution in the inductive part of these resonators makes them very sensitive. Due to only one metal layer on a silicon substrate, the fabrication is relatively easy. In order to optimize the LEKIDs for this application, we have recently probed a wide variety of individual resonator and array parameters through simulation and physical testing. This included determining the optimal feed-line coupling, pixel geometry, resonator distribution within an array (in order to minimize pixel cross-talk), and resonator frequency spacing. Based on these results, a 144-pixel Aluminum array was fabricated and tested in a dilution fridge with optical access, yielding an average optical NEP of ~2E-16 W/Hz^1/2 (best pixels showed NEP = 6E-17 W/Hz^1/2 under 4-8 pW loading per pixel). In October 2010 the second prototype of LEKIDs has been tested at the IRAM 30 m telescope. A new LEKID geometry for 2 polarizations will be presented. Also first optical measurements of a titanium nitride array will be discussed.Comment: 5 pages, 12 figures; ISSTT 2011 Worksho

The large scale dynamics of the outer heliosphere and the long-term modulation of galactic cosmic rays

The network of cosmic ray observatories reaching across the heliosphere has given new insight into the process of solar modulation, establishing that the decreases occur principally in the outer heliosphere and are produced by interplanetary flow systems; that the hysteresis effects appear to be produced by changes in the rigidity dependence of the diffusion coefficient and that the predicted effects on the cosmic ray gradients associated with the reversal of the solar magnetic field polarity are not observed

Renormalization group structure for sums of variables generated by incipiently chaotic maps

We look at the limit distributions of sums of deterministic chaotic variables in unimodal maps and find a remarkable renormalization group (RG) structure associated to the operation of increment of summands and rescaling. In this structure - where the only relevant variable is the difference in control parameter from its value at the transition to chaos - the trivial fixed point is the Gaussian distribution and a novel nontrivial fixed point is a multifractal distribution that emulates the Feigenbaum attractor, and is universal in the sense of the latter. The crossover between the two fixed points is explained and the flow toward the trivial fixed point is seen to be comparable to the chaotic band merging sequence. We discuss the nature of the Central Limit Theorem for deterministic variables.Comment: 14 pages, 5 figures, to appear in Journal of Statistical Mechanic

Global Bethe lattice consideration of the spin-1 Ising model

The spin-1 Ising model with bilinear and biquadratic exchange interactions and single-ion crystal field is solved on the Bethe lattice using exact recursion equations. The general procedure of critical properties investigation is discussed and full set of phase diagrams are constructed for both positive and negative biquadratic couplings. In latter case we observe all remarkable features of the model, uncluding doubly-reentrant behavior and ferrimagnetic phase. A comparison with the results of other approximation schemes is done.Comment: Latex, 11 pages, 13 ps figures available upon reques

NA49/NA61: results and plans on beam energy and system size scan at the CERN SPS

This paper presents results and plans of the NA49 and NA61/SHINE experiments at the CERN Super Proton Synchrotron concerning the study of relativistic nucleus-nucleus interactions. First, the NA49 evidence for the energy threshold of creating quark-gluon plasma, the onset of deconfinement, in central lead-lead collisions around 30A GeV is reviewed. Then the status of the NA61/SHINE systematic study of properties of the onset of deconfinement is presented. Second, the search for the critical point of strongly interacting matter undertaken by both experiments is discussed. NA49 measured large fluctuations at the top SPS energy, 158A GeV, in collisions of light and medium size nuclei. They seem to indicate that the critical point exists and is located close to baryonic chemical potential of about 250 MeV. The NA61/SHINE beam energy and system size scan started in 2009 will provide evidence for the existence of the critical point or refute the interpretation of the NA49 fluctuation data in terms of the critical point.Comment: 11 pages, invited talk at Quark Matter 201