204 research outputs found

    The Association of Large-Scale Climate Variability and Teleconnections on Wind Energy Resource over Europe and its Intermittency

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    In times of increasing importance of wind power in the world’s energy mix, this study focuses on a better understanding of the influences of large-scale climate variability on wind power resource over Europe. The impact of the North Atlantic Oscillation (NAO), the Arctic Oscillation (AO), the El Niño Southern Oscillation (ENSO) and the Atlantic Multidecadal Oscillation (AMO) are investigated in terms of their correlation with wind power density (WPD) at 80 m hub height. These WPDs are calculated based on the MERRA Reanalysis data set covering 31 years of measurements. Not surprisingly, AO and NAO are highly correlated with the time series of WPD. This correlation can also be found in the first principal component of a Principal Component Analysis (PCA) of WPD over Europe explaining 14% of the overall variation. Further, cross-correlation analyses indicates the strongest associated variations are achieved with AO/NAO leading WPD by at most one day. Furthermore, the impact of high and low phases of the respective oscillations has been assessed to provide a more comprehensive illustration. The fraction of WPD for high and low AO/NAO increases considerably for northern Europe, whereas the opposite pattern can be observed for southern Europe. Similar results are obtained by calculating the energy output of three hypothetical wind turbines for every grid point over Europe. Thus, we identified a high interconnection potential between wind farms in order to reduce intermittency, one of the primary challenges in wind power generation. In addition, we observe significant correlations between WPD and AMO

    Atomic Dipole Traps with Amplified Spontaneous Emission: A Proposal

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    We propose what we believe to be a novel type of optical source for ultra-cold atomic Far Off-Resonance optical-dipole Traps (FORTs). The source is based on an Erbium Amplified Spontaneous Emission (ASE) source that seeds a high power Erbium Doped Fiber Amplifier (EDFA). The main interest of this source is its very low coherence length, thus allowing an incoherent superposition of several trapping beams without any optical interference. The behavior of the superimposed beams is then a scalar sum greatly simplifying complex configurations. As an illustration, we report an estimation of the intensity noise of this source and an estimation of the atomic excess heating rate for an evaporative cooling experiment application. They are both found to be suitable for cold atoms experiments

    EnquĂȘte diagnostique des connaissances en information-documentation des Ă©lĂšves du secondaire en France

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    Cette enquĂȘte menĂ©e sur 6 ans (2009-2015) avait pour but de faire un Ă©tat des lieux des connaissances et des Ă©lĂšves du secondaire. L\u27objectif Ă©tait dĂ©terminer les manques en terme de formation des Ă©lĂšves, les points forts, afin de renforcer l\u27expertise didactique des professeurs documentalistes dans les processus de transposition didactique externe (l\u27Ă©laboration des savoirs scolaires) et interne (la mise en situation didactique de ces savoirs dans la classe) en leur apportant des donnĂ©es objectives sur l\u27Ă©tat des acquisitions des Ă©lĂšves Ă  l\u27entrĂ©e et Ă  la sortie du collĂšge et du lycĂ©e. Enfin, cette Ă©tude permet d\u27Ă©tablir des comparaisons Ă  partir des rĂ©sultats enregistrĂ©s en Terminale avec deux enquĂȘtes nationales rĂ©alisĂ©es au QuĂ©bec (CREPUQ) et en Belgique (EDUDOC) en 2003 et 2008 pour des Ă©tudiants en dĂ©but d\u27annĂ©e de premier cycle

    A Versatile Route to Assemble Semiconductor Nanoparticles into Functional Aerogels by Means of Trivalent Cations

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    3D nanoparticle assemblies offer a unique platform to enhance and extend the functionality and optical/electrical properties of individual nanoparticles. Especially, a self-supported, voluminous, and porous macroscopic material built up from interconnected semiconductor nanoparticles provides new possibilities in the field of sensing, optoelectronics, and photovoltaics. Herein, a method is demonstrated for assembling semiconductor nanoparticle systems containing building blocks possessing different composition, size, shape, and surface ligands. The method is based on the controlled destabilization of the particles triggered by trivalent cations (Y3+, Yb3+, and Al3+). The effect of the cations is investigated via X-ray photoelectron spectroscopy. The macroscopic, self-supported aerogels consist of the hyperbranched network of interconnected CdSe/ CdS dot-in-rods, or CdSe/CdS as well as CdSe/CdTe core-crown nanoplatelets is used to demonstrate the versatility of the procedure. The non-oxidative assembly method takes place at room temperature without thermal activation in several hours and preserves the shape and the fluorescence of the building blocks. The assembled nanoparticle network provides longer exciton lifetimes with retained photoluminescence quantum yields, that make these nanostructured materials a perfect platform for novel multifunctional 3D networks in sensing. Various sets of photoelectrochemical measurements on the interconnected semiconductor nanorod structures also reveal the enhanced charge carrier separation

    Versatile Route for Multifunctional Aerogels Including Flaxseed Mucilage and Nanocrystals

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    Preparation of low density monolithic and free-standing organic-inorganic hybrid aerogels of various properties is demonstrated using green chemistry from a biosafe natural source (flaxseed mucilage) and freeze-casting and subsequent freeze drying. Bio-aerogels, luminescent aerogels, and magneto-responsive aerogels are obtained by combination of the flaxseed mucilage with different types of nanoparticles. Moreover, the aerogels are investigated as possible drug release systems using curcumin as a model. Various characterization techniques like thermogravimetric analysis, nitrogen physisorption, electron microscopy, UV/Vis absorption, and emission spectroscopy, bulk density, and mechanical measurements, as well as in vitro release profile measurements, are employed to investigate the obtained materials. The flaxseed-inspired organic-inorganic hybrid aerogels exhibit ultra-low densities as low as 5.6 mg cm−3 for 0.5% (w/v) the mucilage polymer, a specific surface area of 4 to 20 m2 g−1, high oil absorption capacity (23 g g−1), and prominent compressibility. The natural biopolymer technique leads to low cost and biocompatible functional lightweight materials with tunable properties (physicochemical and mechanical) and significant potential for applications as supporting or stimuli responsive materials, carriers, reactors, microwave- and electromagnetic radiation protective (absorbing)-materials, as well as in drug delivery and oil absorption

    Interparticle Distance Variation in Semiconductor Nanoplatelet Stacks

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    In the large field of research on nanoplatelets (NPLs), their strong tendency to self-assemble into ordered stacks and the resulting changes in their properties are of great interest. The assembly reveals new characteristics such as the charge carrier transport through the NPL assembly or altered optical properties. In particular, a reduced distance should enhance the charge carrier transport due to higher electronic coupling of neighboring NPLs, and therefore, is the focus of this work. To modify the inter-particle distances, the straightforward method of ligand exchange is applied. Various CdSe and CdSe/CdX (hetero-) NPLs serve as building blocks, which not only display different material combinations but also different types of hetero-structures. The surface-to-surface distance between the stacked NPLs can be reduced to below 1 nm, thus, to less than the half compared to assemblies of pristine NPLs. Moreover, for certain NPLs stacking is only enabled by the ligand exchange. To characterize the ligand exchanges and to investigate the influences of the reduced distances, photo-electrochemical measurements, fluorescence spectroscopy, energy dispersive X-ray spectroscopy, nuclear magnetic resonance, and X-ray photoelectron spectroscopy are performed. It is possible to show higher photocurrents for smaller distances, indicating enhanced charge transport ability within those stacks

    Netboost: boosting-supported network analysis improves high-dimensional omics prediction in acute myeloid leukemia and Huntington’s disease

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    State-of-the art selection methods fail to identify weak but cumulative effects of features found in many high-dimensional omics datasets. Nevertheless, these features play an important role in certain diseases. We present Netboost, a three-step dimension reduction technique. First, a boosting-based filter is combined with the topological overlap measure to identify the essential edges of the network. Second, sparse hierarchical clustering is applied on the selected edges to identify modules and finally module information is aggregated by the first principal components. We demonstrate the application of the newly developed Netboost in combination with CoxBoost for survival prediction of DNA methylation and gene expression data from 180 acute myeloid leukemia (AML) patients and show, based on cross-validated prediction error curve estimates, its prediction superiority over variable selection on the full dataset as well as over an alternative clustering approach. The identified signature related to chromatin modifying enzymes was replicated in an independent dataset, the phase II AMLSG 12-09 study. In a second application we combine Netboost with Random Forest classification and improve the disease classification error in RNA-sequencing data of Huntington's disease mice. Netboost is a freely available Bioconductor R package for dimension reduction and hypothesis generation in high-dimensional omics applications

    Versatile Route for Multifunctional Aerogels Including Flaxseed Mucilage and Nanocrystals

    Get PDF
    Preparation of low density monolithic and free-standing organic-inorganic hybrid aerogels of various properties is demonstrated using green chemistry from a biosafe natural source (flaxseed mucilage) and freeze-casting and subsequent freeze drying. Bio-aerogels, luminescent aerogels, and magneto-responsive aerogels are obtained by combination of the flaxseed mucilage with different types of nanoparticles. Moreover, the aerogels are investigated as possible drug release systems using curcumin as a model. Various characterization techniques like thermogravimetric analysis, nitrogen physisorption, electron microscopy, UV/Vis absorption, and emission spectroscopy, bulk density, and mechanical measurements, as well as in vitro release profile measurements, are employed to investigate the obtained materials. The flaxseed-inspired organic-inorganic hybrid aerogels exhibit ultra-low densities as low as 5.6 mg cm(-3) for 0.5% (w/v) the mucilage polymer, a specific surface area of 4 to 20 m(2) g(-1), high oil absorption capacity (23 g g(-1)), and prominent compressibility. The natural biopolymer technique leads to low cost and biocompatible functional lightweight materials with tunable properties (physicochemical and mechanical) and significant potential for applications as supporting or stimuli responsive materials, carriers, reactors, microwave- and electromagnetic radiation protective (absorbing)-materials, as well as in drug delivery and oil absorption
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