Low-energy electrodynamics of superconducting diamond

Heavily-boron-doped diamond films become superconducting with critical temperatures $T_c$ well above 4 K. Here we first measure the reflectivity of such a film down to 5 cm$^{-1}$, by also using Coherent Synchrotron Radiation. We thus determine the optical gap, the field penetration depth, the range of action of the Ferrell-Glover-Tinkham sum rule, and the electron-phonon spectral function. We conclude that diamond behaves as a dirty BCS superconductor.Comment: 4 pages including 3 figure

Hubble Space Telescope imaging of the CFRS and LDSS redshift surveys - IV. Influence of mergers in the evolution of faint field galaxies from z~1

HST images of a sample of 285 galaxies with measured z from the CFRS and Autofib-LDSS redshift surveys are analysed to derive the evolution of the merger fraction out to z~1. We have performed visual and machine-based merger identifications, as well as counts of bright pairs of galaxies with magnitude differences less than 1.5 mag. We find that the pair fraction increases with z, with up to ~20% of the galaxies being in physical pairs at z~0.75-1. We derive a merger fraction varying with z as (1+z)^{3.2 +/- 0.6}, after correction for line-of-sight contamination, in excellent agreement with the merger fraction derived from the visual classification of mergers for which m = 3.4 +/- 0.6. After correcting for seeing effects on the ground-based selection of survey galaxies, we conclude that the pair fraction evolves as (1+z)^{2.7 +/- 0.6}. This implies that an average L* galaxy will have undergone 0.8 to 1.8 merger events from z=1 to 0, with 0.5 to 1.2 merger events occuring in a 2 Gyr time span at z~0.9. This result is consistent with predictions from semi-analytical models of galaxy formation. From the simple co-addition of the observed luminosities of the galaxies in pairs, physical mergers are computed to lead to a brightening of 0.5 mag for each pair on average, and a boost in star formation rate of a factor of 2, as derived from the average [O II] equivalent widths. Mergers of galaxies are therefore contributing significantly to the evolution of both the luminosity function and luminosity density of the Universe out to z~1.Comment: 14 pages, 6 PS figures included. Accepted for publication in MNRA

Six more quasars at redshift 6 discovered by the Canada-France High-z Quasar Survey

We present imaging and spectroscopic observations for six quasars at z>5.9 discovered by the Canada-France High-z Quasar Survey (CFHQS). The CFHQS contains sub-surveys with a range of flux and area combinations to sample a wide range of quasar luminosities at z~6. The new quasars have luminosities 10 to 75 times lower than the most luminous SDSS quasars at this redshift. The least luminous quasar, CFHQS J0216-0455 at z=6.01, has absolute magnitude M_1450=-22.21, well below the likely break in the luminosity function. This quasar is not detected in a deep XMM-Newton survey showing that optical selection is still a very efficient tool for finding high redshift quasars.Comment: 7 pages, 4 figures, AJ, in pres

Multiscale Photon Based In Situ and Operando Spectroscopies in Time and Energy Landscapes

Following catalytic reactions, in situ and operando are now the focus of a number of dedicated experiments at light sources which have been developed to track the electronic and molecular structural dynamics of catalysts. The challenges for this goal are two fold first, the development of spectroscopic tools in the energy domain and time domain is required. The photocatalytic processes have early dynamics of tens of femtoseconds, while further reaction takes seconds, minutes, and even hours. Second, a combination of tools to probe processes not only in solids, but also in solutions and at interfaces, is now needed. In this special issue, we present recent developments at the synchrotron facility BESSY II using photon energy from the infrared and extreme ultraviolet up to the soft X ray regime for in situ and operando applications addressing these two major challenges. As this work is a result of contributions from several groups, each section will present the group s activities and related team members involve

Vibrational signature of hydrated protons confined in MXene interlayers

The hydration structure of protons has been studied for decades in bulk water and protonated clusters due to its importance but has remained elusive in planar confined environments. Two dimensional 2D transition metal carbides known as MXenes show extreme capacitance in protic electrolytes, which has attracted attention in the energy storage field. We report here that discrete vibrational modes related to protons intercalated in the 2D slits between Ti3C2Tx MXene layers can be detected using operando infrared spectroscopy. The origin of these modes, not observed for protons in bulk water, is attributed to protons with reduced coordination number in confinement based on Density Functional Theory calculations. This study therefore demonstrates a useful tool for the characterization of chemical species under 2D confinemen