7,509 research outputs found
Vibrational effects in the quantum dynamics of the H + D_2^+ charge transfer reaction
The H + D_2^+(v=0,1 and 2) charge transfer reaction is studied using an
accurate wave packet method, using recently proposed coupled diabatic potential
energy surfaces. The state-to-state cross section is obtained for three
different channels: non-reactive charge transfer, reactive charge transfer, and
exchange reaction. The three processes proceed via the electronic transition
from the first excited to the ground electronic state. The cross section for
the three processes increases with the initial vibrational excitation. The
non-reactive charge transfer process is the dominant channel, whose branching
ratio increases with collision energy, and it compares well with experimental
measurements at collision energies around 0.5 eV. For lower energies the
experimental cross section is considerably higher, suggesting that it
corresponds to higher vibrational excitation of D_2^+(v) reactants. Further
experimental studies of this reaction and isotopic variants are needed, where
conditions are controlled to obtain a better analysis of the vibrational
effects of the D_2^+ reagents.Comment: 15 pages, 7 figure
Protein adsorption onto Fe3O4 nanoparticles with opposite surface charge and its impact on cell uptake
Nanoparticles (NPs) engineered for biomedical applications are meant to be in
contact with protein-rich physiological fluids. These proteins are usually
adsorbed onto the NP surface, forming a swaddling layer called protein corona
that influences cell internalization. We present a study on protein adsorption
onto different magnetic NPs (MNPs) when immersed in cell culture medium, and
how these changes affect the cellular uptake. Two colloids with magnetite cores
of 25 nm, same hydrodynamic size and opposite surface charge were in situ
coated with (a) positive polyethyleneimine (PEI-MNPs) and (b) negative
poly(acrylic acid) (PAA-MNPs). After few minutes of incubation in cell culture
medium the wrapping of the MNPs by protein adsorption resulted in a 5-fold size
increase. After 24 h of incubation large MNP-protein aggregates with
hydrodynamic sizes 1500 to 3000 nm (PAA-MNPs and PEI-MNPs respectively) were
observed. Each cluster contained an estimated number of magnetic cores between
450 and 1000, indicating the formation of large aggregates with a "plum
pudding" structure of MNPs embedded into a protein network of negative surface
charge irrespective of the MNP_core charge. We demonstrated that PEI-MNPs are
incorporated in much larger amounts than the PAA-MNPs units. Quantitative
analysis showed that SH-SY5Y cells can incorporate 100 per cent of the added
PEI-MNPs up to about 100 pg per cell, whereas for PAA-MNPs the uptake was less
than 50 percent. The final cellular distribution showed also notable
differences regarding partial attachment to the cell membrane. These results
highlight the need to characterize the final properties of MNPs after protein
adsorption in biological media, and demonstrate the impact of these properties
on the internalization mechanisms in neural cells.Comment: 32 pages, 10 figure
Pion and Kaon Decay Constants: Lattice vs. Resonance Chiral Theory
The Lattice results for the pion and kaon decay constants are analysed within
the Resonance Chiral Theory framework in the large NC limit. The approximately
linear behaviour of the observable at large light-quark mass is explained
through the interaction with the lightest multiplet of scalar resonances. The
analysis of the Lattice results allows to obtain the resonance mass MS=1049 +-
25 MeV and the Chiral Perturbation Theory parameters at leading order in 1/NC.Comment: 10 pages, 2 figure
Wave packet dynamics of entangled two-mode states
We consider a model Hamiltonian describing the interaction of a single-mode
radiation field with the atoms of a nonlinear medium, and study the dynamics of
entanglement for specific non-entangled initial states of interest: namely,
those in which the field mode is initially in a Fock state, a coherent state,
or a photon-added coherent state. The counterparts of near-revivals and
fractional revivals are shown to be clearly identifiable in the entropy of
entanglement. The ``overlap fidelity'' of the system is another such indicator,
and its behaviour corroborates that of the entropy of entanglement in the
vicinity of near-revivals. The expectation values and higher moments of
suitable quadrature variables are also examined, with reference to possible
squeezing and higher-order squeezing.Comment: 18 pages, 7 figure
Setting up tunneling conditions by means of Bohmian mechanics
Usually tunneling is established after imposing some matching conditions on
the (time-independent) wave function and its first derivative at the boundaries
of a barrier. Here an alternative scheme is proposed to determine tunneling and
estimate transmission probabilities in time-dependent problems, which takes
advantage of the trajectory picture provided by Bohmian mechanics. From this
theory a general functional expression for the transmission probability in
terms of the system initial state can be reached. This expression is used here
to analyze tunneling properties and estimate transmissions in the case of
initial Gaussian wave packets colliding with ramp-like barriers.Comment: 18 pages, 4 figure
Technical Evolution of Ceramic Tile Printing
[EN] Ceramic tile decorating techniques have evolved significantly in recent years. Digital inkjet printing technology has enabled digital systems to be used for the direct decoration of ceramic tiles, revolutionizing ceramic tile decoration and providing many advantages over traditional decoration techniques. It was the formulation of inks with soluble and vitrifiable stains that allowed inkjet printing technology to be introduced into ceramic tile decoration. The incorporation of milled inorganic pigments into the inks broadened the available color palette. However, the colloidal instability of these inks and the constraints of the printing heads themselves made it necessary to reduce pigment particle size, thus limiting color saturation and the color gamut. In order to increase color saturation and obtain a set of pigmented inks with colors more closely resembling CMYK colors, pigments with larger particle sizes need to be used. Indeed, other digital decorating techniques, such as xerography, allow larger particle sizes to be used, while also providing the advantages associated with digital decoration. However, the implementation of this technique for ceramic tile decoration requires the development of appropriate ceramic toners and adaptation of printing machines. This article reviews the technical evolution of ceramic tile printing and describes the development of a prototype, based on xerographic printing, that is able to print ceramic tiles directly and provides greater color intensity and a wider color gamut.40140756
Complex dynamics of elementary cellular automata emerging from chaotic rules
We show techniques of analyzing complex dynamics of cellular automata (CA)
with chaotic behaviour. CA are well known computational substrates for studying
emergent collective behaviour, complexity, randomness and interaction between
order and chaotic systems. A number of attempts have been made to classify CA
functions on their space-time dynamics and to predict behaviour of any given
function. Examples include mechanical computation, \lambda{} and Z-parameters,
mean field theory, differential equations and number conserving features. We
aim to classify CA based on their behaviour when they act in a historical mode,
i.e. as CA with memory. We demonstrate that cell-state transition rules
enriched with memory quickly transform a chaotic system converging to a complex
global behaviour from almost any initial condition. Thus just in few steps we
can select chaotic rules without exhaustive computational experiments or
recurring to additional parameters. We provide analysis of well-known chaotic
functions in one-dimensional CA, and decompose dynamics of the automata using
majority memory exploring glider dynamics and reactions
On the generalized logistic random differential equation: Theoretical analysis and numerical simulations with real-world data
[EN] Based on the previous literature about the random logistic and Gompertz models, the aim of this paper is to extend the investigations to the generalized logistic differential equation in the random setting. First, this is done by rigorously constructing its solution in two different ways, namely, the sample-path approach and the mean-square calculus. Secondly, the probability density function at each time instant is derived in two ways: by applying the random variable transformation technique and by solving the associated Liouville's partial differential equation. It is also proved that both the stochastic solution and its density function converge, under specific conditions, to the corresponding solution and density function of the logistic and Gompertz models, respectively. The investigation finishes showing some examples, where a number of computational techniques are combined to construct reliable approximations of the probability density of the stochastic solution. In particular, we show, step-by-step, how our findings can be applied to a real-world problem. (c) 2022 The Author(s). Published by Elsevier B.V.This work has been supported by the Spanish Agencia Estatal de Investigacion grant PID2020-115270GB-I00. Vicente Bevia acknowledges the doctorate scholarship granted by Programa de Ayudas de Investigacion y Desarrollo (PAID), Universitat Politecnica de Valencia.Bevia, V.; Calatayud-Gregori, J.; Cortés, J.; Jornet-Sanz, M. (2023). On the generalized logistic random differential equation: Theoretical analysis and numerical simulations with real-world data. Communications in Nonlinear Science and Numerical Simulation. 116. https://doi.org/10.1016/j.cnsns.2022.10683211
Non elliptic SPDEs and ambit fields: existence of densities
Relying on the method developed in [debusscheromito2014], we prove the
existence of a density for two different examples of random fields indexed by
(t,x)\in(0,T]\times \Rd. The first example consists of SPDEs with Lipschitz
continuous coefficients driven by a Gaussian noise white in time and with a
stationary spatial covariance, in the setting of [dalang1999]. The density
exists on the set where the nonlinearity of the noise does not vanish.
This complements the results in [sanzsuess2015] where is assumed to be
bounded away from zero. The second example is an ambit field with a stochastic
integral term having as integrator a L\'evy basis of pure-jump, stable-like
type.Comment: 23 page
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