38 research outputs found
A new approach in the use of microelements as tracers for identification and differentiation of natural and anthropogenic impacts in the sediments
Моbilizаciја mikrоеlеmеnаtа y biоsfеru pоd uticајеm lјudskе аktivnоsti je pоstаlа vаžаn prоcеs u gеоhеmiјskоm ciklusu оvih еlеmеnаtа. To je pоstаlо pоsеbnо izrаžеnо u urbаnim srеdinаmа, gdе sе iz rаzličitih izvоrа оslоbаđајu vеlikе kоličinе tоksičnih еlеmеnаtа u аtmоsfеru, vоdеnе tоkоvе, zеmlјištе i sеdimеnt. Sа pоvеćаnjеm еmisiје оvih еlеmеnаtа, pоvеćаvајu sе i njihоvе prirоdnе kоncеntrаciје u svim srеdinаmа. Ha tај nаčin tоksični еlеmеnti pоstајu znаčајni trаsеri zаgаđеnjа živоtiе srеdinе. Dеtаlјnоm аnаlizоm uzоrаkа sеdimеntа, primеnоm mеtоdе еlеmеntаrnе аnаlizе, grаnulоmеtriјskе i rеndgеnskе difrаkciоnе аnаlizе, mеtоdе sеkvеnciјаlnе еkstrаkciје, kао i primеnоm kоmbinоvаnоg еkоhеmiјskоg i gеоhеmiјskоg pristupа u intеrprеtаciјi dоbiјеnih rеzultаtа, kојim je оbuhvаćеnа аnаlizа rеzultаtа dоbiјеnih mеtоdоm sеkvеnciјаlnе еkstrаciје, diskusiја о rаspоdеli еlеmеnаtа no lоkаlitеtimа i dubinаmа, primеnа mеtоdе gеоhеmiјskоg nоrmirаnjа, оdrеđivаnjе fоnskih kоncеntrаciја u sеdimеntimа, оdrеđivаnjе fаktоrа оbоgаćеnjа i stаtističkа оbrаdа lоdаtаkа, u оvоm rаdu je izvеdеnо idеntifikоvаnjе i difеrеnciјаciја аntrоpоgеnоg uticаја i prirоdnоg fоnа tоksičnih i pоtеnciјаlnо tоksičnih mikrоеlеmеnаtа u rеčnоm sеdimеntu Тisе i аluviјаlnоm sеdimеntu Dunаvа, izvršеnа je prоcеnа njihоvоg аntrоpоgеnоg pоrеklа i kvаntifikоvаnjе аntrоpоgеnоg udеlа i dеfinisаni su mоgući izvоri kоntаminаciје u ispitivаnim sеdimеntimа.
Аnаlizоm rеzultаtа kоntаminаciје аluviјаlnоg sеdimеntа Dunаvа u Pаnčеvu je pоkаzаnо dа je sа pоvеćаnjеm rаstојаnjа оd Rаfinеriје, аntrоpоgеni uticај nа sаdržај еlеmеnаtа slаbi i pоstаје znаčајniја gеоhеmiјskа kоntrоlа. Rаzdvојеni su uticајi dvа dоprinоsа kоја znаčајnо оdrеđuјu sаdržај ispitivаnih mikrоеlеmеnаtа i tо: аntrоpоgеni unоs Cr, Zn, Cd, Ni, V i Pb kао pоslеdicа uticаја blizinе industriјskоg kоmplеksа, dоkје pоrеklо Cu i Pb pоvеzаnо sа pоstојаnjеm drugih lоkаlnih izvоrа kоntаminаciје i uticајеm sаоbrаćаја, prvеnstvеnо еmisiјаmа iz аutоmоbilа. Sеdimеnt rеkе Тisе prеdstаvlја rеzеrvоаr zа аkumulаciјu tоksičnih i pоtеnciјаlnо tоksičnih еlеmеnаtа iz оkоlnih urbаnih i industriјskih srеdinа, kао i аkumulаciјu еlеmеnаtа kојi su dоnеti rеkоm Тisоm, uslеd еmisiје u zеmlјаmа iz njеnоg slivа. U sеdimеntu оvе rеkеје оdrеđеn vеći sаdržај Cu, Cr, Zn, Pb, Cd, As i Hg i mаnjе V i Ni u оdnоsu nа sеdimеnt njеnih lritоkа.Mobilization of microelements in the biosphere under the influence of human activities has become an important process in the geochemical cycle of these elements. It has become particularly pronounced in urban areas, where different sources release large amounts of toxic elements in the atmosphere, waterways, soil and sediment. With increasing emission of these elements increases and their concentration in all natural environments. In this way, toxic elements become important tacers of environmental pollution.
Detailed analysis of sediment samples, using methods of elementary analysis, granulometric and X-ray diffraction analysis, sequential extraction methods, and applying the combined ecochemical and geochemical approach to the interpretation of results, which included analysis of the results obtained by the method of sequential extraction, discussion on the distribution of elements by localities and depths, the application of geochemical normalization, determination background concentration, the determination of enrichment factors and statistical analysis, in this thesis was conducted to identify and differentiation of natural and anthropogenic influences of toxic and potentially toxic microelements in the Tisza river sediments and alluvial sediments of the Danube, was made assessment of their anthropogenic origin and quantification of anthropogenic contribution and defined a possible sources of contamination in the sediments.
The analysis results of contamination Danube alluvial sediments from Pančevo was shown that with increasing distance from refineries, anthropogenic impact on the content elements weakens and becomes more important geochemical control. Separated by two contributions, which impacts significantly determine the content of microelements: anthropogenic input Cr, Zn, Cd, Ni, V and Pb as a result of the proximity of the impact of industrial complexes, while the origin of Cu and Pb associated with the existence of other local sources of contamination and the influence of traffic, primarily emissions from cars. Tisa river sediment is a reservoir for the accumulation of toxic and potentially toxic elements from the surrounding urban and industrial areas, and accumulation of elements in the Tisa river sediment, due to emissions from countries in its basin. The sediments of this river is determined by a higher content of Cu, Cr, Zn, Pb, Cd, As and Hg and less V and Ni in relation to the sediment of its tributaries
Supplementary data for the article: Sakan, S.; Popović, A.; Škrivanj, S.; Sakan, N.; Đorđević, D. Comparison of Single Extraction Procedures and the Application of an Index for the Assessment of Heavy Metal Bioavailability in River Sediments. Environmental Science and Pollution Research 2016, 23 (21), 21485–21500. https://doi.org/10.1007/s11356-016-7341-6
Supplementary material for: [https://doi.org/10.1007/s11356-016-7341-6]Related to published version: [http://cherry.chem.bg.ac.rs/handle/123456789/2347
Supplementary data for article: Sakan, S.; Dević, G.; Relić, D.; Anđelković, I.; Sakan, N.; Đorđević, D. Risk Assessment of Trace Element Contamination in River Sediments in Serbia Using Pollution Indices and Statistical Methods: A Pilot Study. Environmental Earth Sciences 2015, 73 (10), 6625–6638. https://doi.org/10.1007/s12665-014-3886-1
Supplementary material for: [https://doi.org/10.1007/s12665-014-3886-1]Related to published version: [http://cherry.chem.bg.ac.rs/handle/123456789/1701
Supplementary data for the article: Sakan, S.; Popović, A.; Škrivanj, S.; Sakan, N.; Đorđević, D. Comparison of Single Extraction Procedures and the Application of an Index for the Assessment of Heavy Metal Bioavailability in River Sediments. Environmental Science and Pollution Research 2016, 23 (21), 21485–21500. https://doi.org/10.1007/s11356-016-7341-6
Supplementary material for: [https://doi.org/10.1007/s11356-016-7341-6]Related to published version: [http://cherry.chem.bg.ac.rs/handle/123456789/2347
Supplementary data for article: Sakan, S.; Dević, G.; Relić, D.; Anđelković, I.; Sakan, N.; Đorđević, D. Risk Assessment of Trace Element Contamination in River Sediments in Serbia Using Pollution Indices and Statistical Methods: A Pilot Study. Environmental Earth Sciences 2015, 73 (10), 6625–6638. https://doi.org/10.1007/s12665-014-3886-1
Supplementary material for: [https://doi.org/10.1007/s12665-014-3886-1]Related to published version: [http://cherry.chem.bg.ac.rs/handle/123456789/1701
Supplementary material for the article: Relić, D.; Héberger, K.; Sakan, S.; Škrbić, B.; Popović, A.; Đorđević, D. Ranking and Similarity of Conventional, Microwave and Ultrasound Element Sequential Extraction Methods. Chemosphere 2018, 198, 103–110. https://doi.org/10.1016/j.chemosphere.2017.12.200
Supplementary material for: [https://doi.org/10.1016/j.chemosphere.2017.12.200]Related to published version: [http://cherry.chem.bg.ac.rs/handle/123456789/2109]Related to accepted version: [http://cherry.chem.bg.ac.rs/handle/123456789/3250
Supplementary material for the article: Sakan, S.; Popović, A.; Anđelković, I.; Đorđević, D. Aquatic Sediments Pollution Estimate Using the Metal Fractionation, Secondary Phase Enrichment Factor Calculation, and Used Statistical Methods. Environmental Geochemistry and Health 2016, 38 (3), 855–867. https://doi.org/10.1007/s10653-015-9766-0
Supplementary material for: [https://doi.org/10.1007/s10653-015-9766-0]Related to published version: [http://cherry.chem.bg.ac.rs/handle/123456789/1940
Supplementary data for the article: Spahić, M. P.; Manojlović, D.; Tančić, P.; Cvetković, Ž.; Nikić, Z.; Kovačević, R.; Sakan, S. Environmental Impact of Industrial and Agricultural Activities to the Trace Element Content in Soil of Srem (Serbia). Environmental Monitoring and Assessment 2019, 191 (3). https://doi.org/10.1007/s10661-019-7268-8
Supplementary material for: [https://doi.org/10.1007/s10661-019-7268-8]Related to published version: [http://cherry.chem.bg.ac.rs/handle/123456789/2845
Supplementary material for the article: Spahić, M. P.; Sakan, S.; Cvetković, Ž.; Tančić, P.; Trifković, J.; Nikić, Z.; Manojlović, D. Assessment of Contamination, Environmental Risk, and Origin of Heavy Metals in Soils Surrounding Industrial Facilities in Vojvodina, Serbia. Environmental Monitoring and Assessment 2018, 190 (4). https://doi.org/10.1007/s10661-018-6583-9
Supplementary material for: [https://doi.org/10.1007/s10661-018-6583-9]Related to published version: [http://cherry.chem.bg.ac.rs/handle/123456789/2123
Supplementary material for the article: Spahić, M. P.; Sakan, S.; Cvetković, Ž.; Tančić, P.; Trifković, J.; Nikić, Z.; Manojlović, D. Assessment of Contamination, Environmental Risk, and Origin of Heavy Metals in Soils Surrounding Industrial Facilities in Vojvodina, Serbia. Environmental Monitoring and Assessment 2018, 190 (4). https://doi.org/10.1007/s10661-018-6583-9
Supplementary material for: [https://doi.org/10.1007/s10661-018-6583-9]Related to published version: [http://cherry.chem.bg.ac.rs/handle/123456789/2123