603 research outputs found

    Surface modification through oxide ALD to improve oxygen exchange rate on perovskite surface

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    Segregation and phase separation on perovskite oxide (ABO3) surface have been considered as a key detrimental factor to the performance of energy conversion devices such as solid oxide/electrolysis cells. Recently, the overcoat of less reducible cations has been suggested as a way to suppress the surface Sr segregation on Sr-containing perovskite oxides. However, the detailed requirements of the coating layer to sufficiently stabilize the perovskite surface hasnā€™t been systematically investigated yet. In this wok, we fabricate La0.6Sr0.4CoO3 (LSC) thin-film model electrode via pulse layer deposition and observe how the degree of Sr segregation varies with the type and thickness of the overcoat layer. Al2O3 and HfO2 with different thickness are coated on LSC via ALD, and the oxygen exchange rate of both bare and ALD-coated samples is measured via electrical conductivity relaxation. It is found that both Al2O3 and HfO2 layers suppress the Sr segregation only within a narrow thickness range, i.e., 1-2 nm for Al2O3 and 0.2 ā€“ 0.4 nm for HfO2, respectively. These observations are discussed with solubility and diffusivity of Al and Hf in the host oxide lattice, providing a critical guideline of a new surface modification method to stabilize the perovskite surface at high temperatures. Please click Additional Files below to see the full abstract

    Spatial Clustering based Meteorological Fields Construction for Regional Vulnerability Assessment

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    Chemical accidents have affected the social-environmental system. For the regional vulnerability assessment, which is the baseline work to assess the impact on the environment, a meteorological field is needed to determine how chemicals from multiple adjacent companies are propagated. In this study, we present the method of meteorological field based on the spatial cluster which is the main component of vulnerability assessment on regional chemical accident scenario. To integrate spatially dense chemical companies into a cluster, we adopt spatial clustering algorithms. Experiment result shows that DBSCAN-based approach reduces 80.5% total area of the meteorological field against brute-force algorithm, and shows good performance on the average of the overlap ratio, and utility ratio for clustering results

    Deployable Hook Retrieval System for UAV Rescue and Delivery

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    The rapid development of unmanned aerial vehicles (UAVs) has helped expand their practical use to many industrial applications. However, UAVs sometimes suffer from a flight time limitation and/or a loss in communication. Such undesired malfunctions can endanger public safety and incur economic losses. This paper presents a new class of UAV that can retrieve a disabled or malfunctioned UAV from the ground. We developed a deployable hook retrieval system (DHRS) which integrates three principal mechanisms (i.e., deployment, slider-linkage-release, and hook release). Each mechanism plays a role in deploying and retrieving multiple hooks while using a simple control strategy. Through a Finite Element Method simulation, the hook was topologically optimized in order to achieve a high strength while reducing weight. The deployed multiple hooks allow the device to capture the target regardless of its orientation. Due to these design strategies, object recognition using a computer vision was simply demonstrated by exploiting ORB and FLANN algorithms. Through an experimental study, we discussed the target range, success rate, and the practical uses that the DHRS could achieve. The results show that the proposed designs were versatile and consistently successful in capturing the targets while addressing constraints such as power consumption, computational load, and lack of prior knowledge or information about the target

    Epidermal Growth Factor Receptor Mutation and Pathologic-Radiologic Correlation Between Multiple Lung Nodules with Ground-Glass Opacity Differentiates Multicentric Origin from Intrapulmonary Spread

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    IntroductionNo standard guidelines detailing recommendations for the selection and treatment for multiple lung nodules with ground-glass opacity (GGO) have been established. For treatment decision, we analyzed epidermal growth factor receptor (EGFR)/K-ras somatic aberrations and pathologic-radiologic correlation in multiple lung nodules presented as GGO to differentiate multifocal lesions from intrapulmonary spread.MethodsTwenty-four patients with multiple lung nodules presented as GGO were identified to investigate somatic mutations of EGFR (exon 18ā€“21) and K-ras (codons 2, 13, and 61). This series included 18 atypical adenomatous hyperplasias (AAH), 15 bronchioloalveolar carcinomas (BAC), and 23 adenocarcinomas (ADC) obtained from 24 patients.ResultsHigh frequency of discordant EGFR mutations (17 of 24, 70.8%) could discriminate tumor clonality (18 of 24, 75%) of multiple lung neoplastic nodules presented as GGO. EGFR mutations were common in AAH (38.9%), BAC (46.7%), and ADC (39.1%). In case 4, AAH and BAC had different mutational changes, and in case 10, the BAC lesion contains EGFR mutation that is not in the invasive ADC. In case 17, the BAC had more mutational changes than the carcinoma. The pure GGO appearance in the radiologic examination corresponded preinvasive pathologic change.ConclusionsThis study showed that synchronous BAC and/or ADC can have different EGFR or K-ras mutational profiles suggesting these lesions arise as independent events rather than intrapulmonary spread or systemic metastasis. This has significant implication in staging and treatment. These findings might be a clue to establish guidelines of the multiple neoplastic lung nodules with GGO

    Permanent Pacemaker for Syncope after Heart Transplantation with Bicaval Technique

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    Sinus node dysfunction occurs occasionally after heart transplantation and may be caused by surgical trauma, ischemia to the sinus node, rejection, drug therapy, and increasing donor age. However, the timing and indication of permanent pacemaker insertion due to sinus node dysfunction following heart transplantation is contentious. Here, we report a case of a permanent pacemaker insertion for syncope due to sinus arrest after heart transplantation, even with a bicaval technique, which has been known to associate with few incidences of sinus node dysfunction

    Packaging and Antenna-Assembled Hybrid Stacked PCB with Novel Vertical Transition for 39 GHz 5G Base Stations

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    This paper proposes a novel packaging and large-scale antenna-assembled structure for a printed circuit board (PCB) that reinforces productivity, facilitates cost reduction, and maintains reliability. This was achieved by splitting the antenna from the main board and packaging it into a radio-frequency integrated circuit. In addition, two innovative solutionsā€”an externally attachable flexible PCB antenna and a PCB-embedded coaxial lineā€”are introduced to overcome the degradation in antenna performance and vertical RF transition loss in the proposed low-cost hybrid PCB. First, the proposed externally attachable flexible PCB antenna and a parasitic air-coupled antenna, which were easily assembled on the PCB, achieved an antenna efficiency of 95% and an impedance bandwidth of 7 GHz. Second, the fabricated coaxial line exhibited enhanced impedance matching over a wide frequency range of 30ā€“40 GHz and improved insertion loss of approximately 1.4 dB. Furthermore, the packaged antenna, composed of 256 dual-polarized antenna elements per stream, incorporated a 39 GHz CMOS-based 16-channel phased-array transceiver IC. The set-level beam-forming measurements were verified considering an effective isotropic radiated power of 55 dBm at boresight and a steering range >Ā±60Ā°. In addition to being suitable for mass production in terms of cost and reliability, the proposed structures and solutions met the required antenna and beam-forming performance for commercial 39 GHz base stations without sacrificing performance
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