Water-soluble ions and trace metals in airborne particles over urban areas of the state of São Paulo, Brazil: Influences of local sources and long range transport

10.1007/s11270-007-9465-2Water, Air, and Soil Pollution1861-463-73WAPL

Seasonal Distribution of Airborne Trace Elements and Water-Soluble Ions in Sao Paulo Megacity, Brazil

This study deals with the seasonal distribution of Al, Ca, Cu, Fe, K, Mg, Na, Pb and Zn and water soluble ions (Cl-, PO43-, NO3-, SO42-, HCOO-, CH3COO-, oxalate, succinate, Na+, NH4+, K+, Mg2+ and Ca2+) found in PM10 samples (particulate matter less than 10 mu m in diameter) Sao Paulo City, Brazil, (April 2003-May 2004). Higher atmospheric levels were found for SO42-, NO3-, Cl- and PO43- while the main organic anions were oxalate and formate. Atmospheric levels for elements were: Fe > Al > Ca > K > Na > Mg > Zn > Cu > Pb. Some sources were predominant for some species: (i) fuel burning and/or biomass burning (NO3-, HCOO-, C2O42-, K+, Mg2+, Ca2+, Fe, Pb, Zn, Al, Ca, K and Mg), (ii) gas-to-particle conversion (SO42- and NH4+) and (iii) sea salt spray (Cl-, Na+ and Na).Fundacao de Amparo a Pesquisa do Estado de Sao Paulo (FAPESP)Fundacao de Amparo a Pesquisa do Estado de Sao Paulo (FAPESP) [2001/01763-0]Conselho Nacional de Conselho Cientifico e Tecnologico (CNPq)Conselho Nacional de Conselho Cientifico e Tecnologico (CNPq)CNPqCNP

Synergetic measurements of aerosols over Sao Paulo, Brazil using LIDAR, sunphotometer and satellite data during the dry season

A backscattering LIDAR system, the first of this kind in Brazil, has been set-up in a suburban area in the city of Sao Paulo (23degrees33'S, 46degrees44' W) to provide the vertical profile of the aerosol backscatter coefficient at 532 nm up to an altitude of 4-6 km above sea level (asl). The measurements have been carried out during the second half of the so-called Brazilian dry season, September and October 2001 and during the first half of the dry season in August and September 2002. The LIDAR data are presented and analysed in synergy with aerosol optical thickness (AOT) measurements obtained by a CIMEL sun-tracking photometer in the visible spectral region and with satellite measurements obtained by the MODIS sensor. This synergetic approach has been used, not only to validate the LIDAR data, but also to derive a typical value ( 45 sr) of the so-called extinction-to-backscatter ratio (LIDAR ratio) during the dry season. The satellite data analysis offers additional information on the spatial distribution of aerosols over Brazil including the determination of aerosol source regions over the country. The LIDAR data were also used to retrieve the Planetary Boundary Layer (PBL) height, aerosol layering and the structure of the lower troposphere over the city of Sao Paulo. These first LIDAR measurements over the city of Sao Paulo during the dry season showed a significant variability of the AOT in the lower troposphere (0.5-5 km) at 532 nm. It was also found that the aerosol load is maximized in the 1-3 km height region, although up to 3 km thick aerosol layers were also detected in the 2.5-5.5 km region in certain cases. Three-dimensional 96-hours air mass back-trajectory analysis was also performed in selected cases to determine the source regions of aerosols around Sao Paulo during the dry season.Pages: 1523-153