Model of management of competitiveness of a machine-building complex

At the present stage of the economic relations development, competitive fight both in domestic and on the world market becomes more and more tougher. Thus it should be noted that connection between competitiveness of the enterprise and condition of its economic situation. Therefore, for the enterprise that seeks to break forth to the world market, management of competitiveness becomes a decisive factor. © IDOSI Publications, 2013

Optical and magnetooptical properties of manganese-zinc ferrospinels

The use of optical methods for the investigation of the electronic structure of oxide ferrimagnets is complicated by the large variety of possible types of electron transitions whose energies are close to each other and lie in the near infrared, visible, and near ultraviolet regions of the spectrum. Therefore, for the correct identification of the transitions, it is desirable to apply traditional optical spectroscopy, which permits quantitative evaluation of the transition intensities (oscillator strength), in conjunction with magnetooptical (MO) methods providing information on weak intraconfigurational transitions which are not manifest in ordinary absorption or reflection spectra. © 1984 Plenum Publishing Corporation

Self-diffusion of molecules in aqueous solutions of tetramethylurea

Solutions of tetramethylurea (I) in light and heavy water were studied by the proton spin echo method over a wide concentration range at different temperatures. The energies of self-diffusion activation for species in these systems were calculated. In the both systems, the lowest coefficient of self-diffusion and the highest energy of activation for all the temperatures studied (288 to 313 K) were found for its ∼20 mol % solution, which corresponds to a congruently melting compound in the solid phase and to maximum sound viscosity, density, and speed in aqueous solutions of tetramethylurea. The low-concentration range of compound I (from 1.2 to 5 mol %) proved to be featureless

Rheology of liquid crystalline phases of alkyloxybenzylidene toluidines

A unique viscometer of the CS rheometer viscometer class designed at the Kazan State University of Technology is used to measure viscosities of two p-n-alkyloxybenzylidene-p-toluidines in the entire temperature range of the liquid crystalline state and transition into an isotropic liquid. The measured shear stresses and flow rates are used to calculate shear rates and plot flow and viscosity curves. The liquid crystalline phase and isotropic liquid are demonstrated to possess Newtonian viscosity, whose viscous flow activation parameters are calculated in the temperature range under study. The results are discussed from the standpoint of intermolecular interactions and structural details of the liquid crystalline phase. © 2010 Pleiades Publishing, Ltd

A viscometric study of the liquid crystalline phase of alkyloxybenzoic acids

The viscosities of three benzoic acid derivatives (p-n-heptyloxy-, p-n-decyloxy-, and p-n-dodecyloxy-) were measured on a unique viscometer of the class of CS-rheometer-viscometers with controlled shear stress over the whole temperature range of the liquid crystalline state. Shear rates were calculated and flow and viscosity curves constructed from the experimental shear stress values taking into account the Rabinovich-Moony correction. The smectic and nematic phases were characterized by non-Newton and Newton viscosities, respectively, in all the samples studied. The activation parameters of viscous flow were calculated for Newton viscosity. The results are discussed in terms of intermolecular interactions and structural peculiarities of liquid crystalline phases. © 2009 Pleiades Publishing, Ltd

Search for sterile neutrinos at the DANSS experiment

DANSS is a highly segmented 1~m${}^3$ plastic scintillator detector. Its 2500 one meter long scintillator strips have a Gd-loaded reflective cover. The DANSS detector is placed under an industrial 3.1~$\mathrm{GW_{th}}$ reactor of the Kalinin Nuclear Power Plant 350~km NW from Moscow. The distance to the core is varied on-line from 10.7~m to 12.7~m. The reactor building provides about 50~m water-equivalent shielding against the cosmic background. DANSS detects almost 5000 $\widetilde\nu_e$ per day at the closest position with the cosmic background less than 3$\%$. The inverse beta decay process is used to detect $\widetilde\nu_e$. Sterile neutrinos are searched for assuming the $4\nu$ model (3 active and 1 sterile $\nu$). The exclusion area in the $\Delta m_{14}^2,\sin^22\theta_{14}$ plane is obtained using a ratio of positron energy spectra collected at different distances. Therefore results do not depend on the shape and normalization of the reactor $\widetilde\nu_e$ spectrum, as well as on the detector efficiency. Results are based on 966 thousand antineutrino events collected at 3 distances from the reactor core. The excluded area covers a wide range of the sterile neutrino parameters up to $\sin^22\theta_{14}<0.01$ in the most sensitive region.Comment: 10 pages, 13 figures, version accepted for publicatio

Novel B(Ar')2(Ar'') hetero-tri(aryl)boranes: a systematic study of Lewis acidity

A series of homo- and hetero-tri(aryl)boranes incorporating pentafluorophenyl, 3,5-bis(trifluoromethyl)phenyl, and pentachlorophenyl groups, four of which are novel species, have been studied as the acidic component of frustrated Lewis pairs for the heterolytic cleavage of H2. Under mild conditions eight of these will cleave H2; the rate of cleavage depending on both the electrophilicity of the borane and the steric bulk around the boron atom. Electrochemical studies allow comparisons of the electrophilicity with spectroscopic measurements of Lewis acidity for different series of boranes. Discrepancies in the correlation between these two types of measurements, combined with structural characterisation of each borane, reveal that the twist of the aryl rings with respect to the boron-centred trigonal plane is significant from both a steric and electronic perspective, and is an important consideration in the design of tri(aryl)boranes as Lewis acids

De novo sequencing and characterization of floral transcriptome in two species of buckwheat (Fagopyrum)

<p>Abstract</p> <p>Background</p> <p>Transcriptome sequencing data has become an integral component of modern genetics, genomics and evolutionary biology. However, despite advances in the technologies of DNA sequencing, such data are lacking for many groups of living organisms, in particular, many plant taxa. We present here the results of transcriptome sequencing for two closely related plant species. These species, <it>Fagopyrum esculentum </it>and <it>F. tataricum</it>, belong to the order Caryophyllales - a large group of flowering plants with uncertain evolutionary relationships. <it>F. esculentum </it>(common buckwheat) is also an important food crop. Despite these practical and evolutionary considerations <it>Fagopyrum </it>species have not been the subject of large-scale sequencing projects.</p> <p>Results</p> <p>Normalized cDNA corresponding to genes expressed in flowers and inflorescences of <it>F. esculentum </it>and <it>F. tataricum </it>was sequenced using the 454 pyrosequencing technology. This resulted in 267 (for <it>F. esculentum</it>) and 229 (<it>F. tataricum</it>) thousands of reads with average length of 341-349 nucleotides. <it>De novo </it>assembly of the reads produced about 25 thousands of contigs for each species, with 7.5-8.2× coverage. Comparative analysis of two transcriptomes demonstrated their overall similarity but also revealed genes that are presumably differentially expressed. Among them are retrotransposon genes and genes involved in sugar biosynthesis and metabolism. Thirteen single-copy genes were used for phylogenetic analysis; the resulting trees are largely consistent with those inferred from multigenic plastid datasets. The sister relationships of the Caryophyllales and asterids now gained high support from nuclear gene sequences.</p> <p>Conclusions</p> <p>454 transcriptome sequencing and <it>de novo </it>assembly was performed for two congeneric flowering plant species, <it>F. esculentum </it>and <it>F. tataricum</it>. As a result, a large set of cDNA sequences that represent orthologs of known plant genes as well as potential new genes was generated.</p

Gene Expression Profiling of Two Distinct Neuronal Populations in the Rodent Spinal Cord

BACKGROUND: In the field of neuroscience microarray gene expression profiles on anatomically defined brain structures are being used increasingly to study both normal brain functions as well as pathological states. Fluorescent tracing techniques in brain tissue that identifies distinct neuronal populations can in combination with global gene expression profiling potentially increase the resolution and specificity of such studies to shed new light on neuronal functions at the cellular level. METHODOLOGY/PRINCIPAL FINDINGS: We examine the microarray gene expression profiles of two distinct neuronal populations in the spinal cord of the neonatal rat, the principal motor neurons and specific interneurons involved in motor control. The gene expression profiles of the respective cell populations were obtained from amplified mRNA originating from 50-250 fluorescently identified and laser microdissected cells. In the data analysis we combine a new microarray normalization procedure with a conglomerate measure of significant differential gene expression. Using our methodology we find 32 genes to be more expressed in the interneurons compared to the motor neurons that all except one have not previously been associated with this neuronal population. As a validation of our method we find 17 genes to be more expressed in the motor neurons than in the interneurons and of these only one had not previously been described in this population. CONCLUSIONS/SIGNIFICANCE: We provide an optimized experimental protocol that allows isolation of gene transcripts from fluorescent retrogradely labeled cell populations in fresh tissue, which can be used to generate amplified aRNA for microarray hybridization from as few as 50 laser microdissected cells. Using this optimized experimental protocol in combination with our microarray analysis methodology we find 49 differentially expressed genes between the motor neurons and the interneurons that reflect the functional differences between these two cell populations in generating and transmitting the motor output in the rodent spinal cord

A Functional Phylogenomic View of the Seed Plants

A novel result of the current research is the development and implementation of a unique functional phylogenomic approach that explores the genomic origins of seed plant diversification. We first use 22,833 sets of orthologs from the nuclear genomes of 101 genera across land plants to reconstruct their phylogenetic relationships. One of the more salient results is the resolution of some enigmatic relationships in seed plant phylogeny, such as the placement of Gnetales as sister to the rest of the gymnosperms. In using this novel phylogenomic approach, we were also able to identify overrepresented functional gene ontology categories in genes that provide positive branch support for major nodes prompting new hypotheses for genes associated with the diversification of angiosperms. For example, RNA interference (RNAi) has played a significant role in the divergence of monocots from other angiosperms, which has experimental support in Arabidopsis and rice. This analysis also implied that the second largest subunit of RNA polymerase IV and V (NRPD2) played a prominent role in the divergence of gymnosperms. This hypothesis is supported by the lack of 24nt siRNA in conifers, the maternal control of small RNA in the seeds of flowering plants, and the emergence of double fertilization in angiosperms. Our approach takes advantage of genomic data to define orthologs, reconstruct relationships, and narrow down candidate genes involved in plant evolution within a phylogenomic view of species' diversification