Science at the end of empire

This book produces a major rethinking of the history of development after 1940 through an exploration of Britain’s ambitions for industrialisation in its Caribbean colonies. Industrial development is a neglected topic in histories of the British Colonial Empire, and we know very little of plans for Britain’s Caribbean colonies in general in the late colonial period, despite the role played by riots in the region in prompting an increase in development spending. This account shows the importance of knowledge and expertise in the promotion of a model of Caribbean development that is best described as liberal rather than state-centred and authoritarian. It explores how the post-war period saw an attempt by the Colonial Office to revive Caribbean economies by transforming cane sugar from a low-value foodstuff into a lucrative starting compound for making fuels, plastics and medical products. In addition, it shows that as Caribbean territories moved towards independence and America sought to shape the future of the region, scientific and economic advice became a key strategy for the maintenance of British control of the West Indian colonies. Britain needed to counter attempts by American-backed experts to promote a very different approach to industrial development after 1945 informed by the priorities of US foreign policy

Integrating cultural ecosystem services valuation into coastal wetlands restoration : a case study from South Australia

Elaborating the benefits humans receive from coastal wetlands using a Cultural Ecosystem Services assessment is an emergent and important field linking human wellbeing to ecosystem function. Translating these benefits into useable concepts for environmental policymakers, and managers is challenging yet important for supporting landscape restoration projects. This study responds to the call for Cultural Ecosystem Services case studies beyond the northern hemisphere. A household survey of residents adjacent to a peri-urban coastal wetland in South Australia and an online survey of interest groups were administered to identify co-benefits associated with a coastal restoration project in the region. A dynamic/relational cultural values framework guided the analysis. Findings reveal that visitation has a positive influence; people valued most the places with which they were familiar. The analysis confirms a mutual connection between: ‘doing’ (undertaking an activity), environmental awareness and appreciation, the formation of attachment to place, and having positive experiences. The analysis also points out that the naturalness of this coastline is highly valued. The findings here diverge from previous coastal landscape assessments based singularly on scenic value. The implication is that localised, place-based landscape assessments which include cultural values, offer a more deliberative approach to policy development and planning and will more likely incorporate what matters most to people. © 2020 The Author(s

Pyrethrum and the Second World War : Recontextualising DDT in the Narrative of Wartime Insect Control

Historians have long recognised that DDT’s fame began with extraordinary propaganda late in the Second World War, yet heroic narratives that centre the chemical still shape historical understanding. Two false assumptions inform much of the existing scholarship on wartime insect control: one is that without DDT the Allies had no protection from malaria and typhus; the other is that DDT was significantly more toxic than any alternative insecticide available. This paper tells a very different story of wartime insecticides. We recontextualise DDT in the wider wartime technological landscape and in so doing show the enduring significance of the natural insecticide, pyrethrum. DDT was never solely responsible for protecting troops and civilians from malaria and typhus and its deployment did not render all existing insecticides obsolete. Claims about the significance of DDT often work by writing out the existence of alternative methods of controlling vectors or by downplaying the efficacy of existing materials and practices

P3-[2-(4-hydroxyphenyl)-2-oxo]ethyl ATP for the Rapid Activation of the Na+,K+-ATPase

This is the published version, also available here: http://dx.doi.org/10.1016/S0006-3495(00)76387-9.P3-[2-(4-hydroxyphenyl)-2-oxo]ethyl ATP (pHP-caged ATP) has been investigated for its application as a phototrigger for the rapid activation of electrogenic ion pumps. The yield of ATP after irradiation with a XeCl excimer laser (λ = 308 nm) was determined at pH 6.0–7.5. For comparison, the photolytic yields of P3-[1-(2-nitrophenyl)]ethyl ATP (NPE-caged ATP) and P3-[1,2-diphenyl-2-oxo]ethyl ATP (desyl-caged ATP) were also measured. It was shown that at λ = 308 nm pHP-caged ATP is superior to the other caged ATP derivatives investigated in terms of yield of ATP after irradiation. Using time-resolved single-wavelength IR spectroscopy, we determined a lower limit of 106 s−1 for the rate constant of release of ATP from pHP-caged ATP at pH 7.0. Like NPE-caged ATP, pHP-caged ATP and desyl-caged ATP bind to the Na+,K+-ATPase and act as competitive inhibitors of ATPase function. Using pHP-caged ATP, we investigated the charge translocation kinetics of the Na+,K+-ATPase at pH 6.2–7.4. The kinetic parameters obtained from the electrical measurements are compared to those obtained with a technique that does not require caged ATP, namely parallel stopped-flow experiments using the voltage-sensitive dye RH421. It is shown that the two techniques yield identical results, provided the inhibitory properties of the caged compound are taken into account. Our results demonstrate that under physiological (pH 7.0) and slightly basic (pH 7.5) or acidic (pH 6.0) conditions, pHP-caged ATP is a rapid, effective, and biocompatible phototrigger for ATP-driven biological systems

Petrophysical zoning elements of Chertovo Koryto gold-ore deposit (Patom Upland, Eastern Siberia)

The paper considers magnetic susceptibility (chi) and electrode potentials (EP) of rocks in the Chertovo Koryto deposit. Carbon-bearing substance is found in all the studied samples, but in some cases, this substance supplies EP (-150 ± -400 mV). In these samples [chi] rarely exceeds 40·10{-5} SI units, while, in other samples [chi] is 8-10 (up to 30) times higher. Less intensive EP (-20 ± -240 mV) is furnished due to the sulfides in this deposit. Rocks with polarized carbon-bearing substance do not contain magnetic pyrrhotine and are negative linear EP anomalies. Rocks in which carbon-bearing substance is associated with pyrrhotine are revealed as magnetic anomalies. The adjacent rocks determine petrophysical zoning of the Chertovo Koryto deposit. The combination of negative linear EP anomalies and magnetic anomalies is a potential indicator and can define the multi-stage formation of the deposit itself

Was Adam Smith an individualist?

Smith is generally regarded as an individualist without qualification. This article argues that his predominantly individualist policy prescription is rooted in a more complex philosophy. He sees nature, including human nature, as a vast machine supervised by God and designed to maximize human happiness. Human weaknesses, as well as strengths, display the wisdom of God and play their part in this scheme. While Smith pays lip-service to justice, it is really social order that preoccupies him, and, within that, the defence of property. Individuals are valued as bearers of property. As persons, individuals are deceived by nature into acting in a socially beneficial way. In different ways Smith systematically denies the autonomy of the individual with respect to the whole of which he or she is part. For Smith, individual liberty is not the end, but the means, of sustaining social order and property

Deconvolution of the relaxations associated with local and segmental motions in poly(methacrylate)s containing dichlorinated benzyl moieties in the ester residue

9 pages, 15 figures, 1 scheme.The relaxation behavior of poly(2,3-dichlorobenzyl methacrylate) is studied by broadband dielectric spectroscopy in the frequency range of 10–1–109 Hz and temperature interval of 303–423 K. The isotherms representing the dielectric loss of the glassy polymer in the frequency domain present a single absorption, called B process. At temperatures close to Tg, the dynamical (alfa) relaxation already overlaps with the (beta) process, the degree of overlapping increasing with temperature. The deconvolution of the (alfa) and (beta) relaxations is facilitated using the retardation spectra calculated from the isotherms utilizing linear programming regularization parameter techniques. The temperature dependence of the (beta) relaxation presents a crossover associated with a change in activation energy of the local processes. The distance between the (alfa) and (beta) peaks, expressed as log(fmax;/fmax;) where fmax is the frequency at the peak maximum, follows Arrhenius behavior in the temperature range of 310–384 K. Above 384 K, the distance between the peaks remains nearly constant and, as a result, the (alfa) onset temperature exhibited for many polymers is not reached in this system. The fraction of relaxation carried out through the (alfa) process, without (beta) assistance, is larger than 60% in the temperature range of 310–384 K where the so-called Williams ansatz holds.This work was financially suported by the DGCYT and CAM through Grant Nos. MAT2002-04042-C02 and GR/ MAT/0723/2004. Two of the authors (L.G. and D.R.) thank the FONDECYT for partial financial support through Grant Nos. 21050956 and 1050962, respectively.Peer reviewe