Granate con alto contenido de tierras raras pesadas (HREE) y elevada relación Sm/Nd, en pegmatitas de la Sierra de Valle Fértil (Sierras Pampeanas, Argentina).

2 p.El trabajo se realizó en el marco de lso proyectos PB97-1246 (MEC) y BTE2001-1486 (MCYT) y PICT98-4189 (Argentina

Cordieritite and Leucogranite Formation during Emplacement of Highly Peraluminous Magma: the El Pilón Granite Complex (Sierras Pampeanas, Argentina)

Cordieritites and highly peraluminous granites within the El Pilon granite complex, Sierras Pampeanas, Argentina, were emplaced during a medium-P, high-T metamorphic event during the initial decompression of a Cambrian orogen along the southwestern margin of Gondwana. Very fresh orbicular and massive cordieritite bodies with up to 90% cordieritite are genetically associated with a cordierite monzogranite pluton and a larger body of porphyritic granodiorite. The petrogenesis of this association has been studied using petrographical, mineralogical, thermobarometric, geochemical, geochronological and isotope methods. The granitic magmas were formed by anatexis of mid-crustal metamorphic rocks formed earlier in the Pampean orogeny. The cordieritites appear at the top of feeder conduits that connected the source region located at ∼6 kbar with the pluton emplacement level at 3·7 ± 0·3 kbar. A fall in the liquidus temperature of the melt during emplacement was produced by a marked increase in fluid activity owing to rapid decompression and assimilation of surrounding hydrous metapelitic schists, followed by isobaric crystallization. High-Mg cordierite crystallized early on biotite–sillimanite restitic mineral assemblages of the assimilated schists or at the wall of the feeder conduits. Strong convection in the small magma chamber caused flow segregation of cumulate cordierite and restite, developing leucogranites and highly evolved pegmatoids that are in isotopic equilibrium. Rapid ascent of highly peraluminous magmas might explain why emplacement of these granites was simultaneous with the metamorphic peak registered in neighbouring high-grade migmatite and granulite terranes.Facultad de Ciencias Naturales y MuseoCentro de Investigaciones Geológica

Theoretical study of the conformational energy hypersurface of cyclotrisarcosyl

The multidimensional Conformational Potential Energy Hypersurface (PEHS) of cyclotrisarcosyl was comprehensively investigated at the DFT (B3LYP/6-31G(d), B3LYP/6-31G(d,p) and B3LYP/6-311++G(d,p)), levels of theory. The equilibrium structures, their relative stability, and the Transition State (TS) structures involved in the conformational interconversion pathways were analyzed. Aug-cc-pVTZ//B3LYP/6-311++G(d,p) and MP2/6-31G(d)//B3LYP/6-311++G(d,p) single point calculations predict a symmetric cis-cis-cis crown conformation as the energetically preferred form for this compound, which is in agreement with the experimental data. The conformational interconversion between the global minimum and the twist form requires 20.88 kcal mol-1 at the MP2/6-31G(d)//B3LYP/6- 311++G(d,p) level of theory. Our results allow us to form a concise idea about the internal intricacies of the PEHSs of this cyclic tripeptide, describing the conformations as well as the conformational interconversion processes in this hypersurface. In addition, a comparative analysis between the conformational behaviors of cyclotrisarcosyl with that previously reported for cyclotriglycine was carried out.Fil: Alvarez, Maria de Los Angeles. Universidad Nacional de San Luis. Facultad de Química, Bioquímica y Farmacia. Departamento de Química; ArgentinaFil: Saavedra, Edgardo J.. Universidad Nacional de la Patagonia "San Juan Bosco"; ArgentinaFil: Olivella, Mónica Susana. Universidad Nacional de San Luis. Facultad de Química, Bioquímica y Farmacia. Departamento de Química; ArgentinaFil: Suvire, Fernando Daniel. Universidad Nacional de San Luis. Facultad de Química, Bioquímica y Farmacia. Departamento de Química; ArgentinaFil: Zamora, Miguel Angel. Universidad Nacional de San Luis. Facultad de Química, Bioquímica y Farmacia. Departamento de Química; ArgentinaFil: Enriz, Ricardo Daniel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis. Instituto Multidisciplinario de Investigaciones Biológicas de San Luis. Universidad Nacional de San Luis. Facultad de Ciencias Físico Matemáticas y Naturales. Instituto Multidisciplinario de Investigaciones Biológicas de San Luis; Argentina. Universidad Nacional de San Luis. Facultad de Química, Bioquímica y Farmacia. Departamento de Química; Argentin

New SHRIMP U-Pb data from the Famatina Complex : Constraining Early-Mid Ordovician Famatinian magmatism in the Sierras Pampeanas, Argentina

New SHRIMP U-Pb zircon ages are reported for igneous and sedimentary rocks of the Famatina Complex, constraining the age of the magmatism and the ensialic basins. Together with whole-rock and isotope geochemistry for the igneous rocks from the complex, these ages indicate that the voluminous parental magmas of metaluminous composition were derived by partial melting of an older lithosphere without significant asthenospheric contribution. This magmatism was initiated in the Early Ordovician (481 Ma). During the Mid-Late Ordovician, the magmatism ceased (463 Ma), resulting in a short-lived (no more than ~20 Ma) and relatively narrow (~100–150 km) magmatic belt, in contrast to the long-lived cordilleran magmatism of the Andes. The exhumation rate of the Famatina Complex was considerably high and the erosional stripping and deposition of Ordovician sediments occurred soon after of the emplacement of the igneous source rocks during the Early to mid-Ordovician. During the upper Mid Ordovician the clastic contribution was mainly derived from plutonic rocks. Magmatism was completely extinguished in the Mid Ordovician and the sedimentary basins closed in the early Late Ordovician.Centro de Investigaciones Geológica

New SHRIMP U-Pb data from the Famatina Complex : Constraining Early-Mid Ordovician Famatinian magmatism in the Sierras Pampeanas, Argentina

New SHRIMP U-Pb zircon ages are reported for igneous and sedimentary rocks of the Famatina Complex, constraining the age of the magmatism and the ensialic basins. Together with whole-rock and isotope geochemistry for the igneous rocks from the complex, these ages indicate that the voluminous parental magmas of metaluminous composition were derived by partial melting of an older lithosphere without significant asthenospheric contribution. This magmatism was initiated in the Early Ordovician (481 Ma). During the Mid-Late Ordovician, the magmatism ceased (463 Ma), resulting in a short-lived (no more than ~20 Ma) and relatively narrow (~100–150 km) magmatic belt, in contrast to the long-lived cordilleran magmatism of the Andes. The exhumation rate of the Famatina Complex was considerably high and the erosional stripping and deposition of Ordovician sediments occurred soon after of the emplacement of the igneous source rocks during the Early to mid-Ordovician. During the upper Mid Ordovician the clastic contribution was mainly derived from plutonic rocks. Magmatism was completely extinguished in the Mid Ordovician and the sedimentary basins closed in the early Late Ordovician.Centro de Investigaciones Geológica

Age, Sr and Nd-Isotope Systematics, and Origin of Two Fluorite Lodes, Sierras Pampeanas, Argentina

Fluorite mineralization at the La Nueva and Bubu mines yields Sm-Nd ages of 131 ± 22 and 117 ± 26 Ma, respectively. Thus, the mineralization most probably is related to a late Gondwanian (Lower Cretaceous) extensional and magmatic event that affected the Sierras Pampeanas basement during the opening of the Atlantic Ocean. Hydrothermal fluids involved in the formation of the fluorite probably were of meteoric origin, their isotopic composition (Sr and Nd) resulting largely from the incongruent dissolution of feldspars in the host porphyritic granites.Facultad de Ciencias Naturales y Muse

Involvement of the Argentine Precordillera terrane in the Famatinian mobile belt: U-Pb SHRIMP and metamorphic evidence from the Sierra de Pie de Palo

New data suggest that the eastern margin of the Argentine Precordillera terrane comprises Grenvillian basement and a sedimentary cover derived from it that were together affected by Middle Ordovician deformation and metamorphism during accretion to the Gondwana margin. The basement first underwent low pressure/temperature (P/T) type metamorphism, reaching high-grade migmatitic conditions in places (686 ± 40 MPa, 790 ± 17 °C), comparable to the Grenvillian M2 metamorphism of the supposed Laurentian counterpart of the terrane. The second metamorphism, recognized in the cover sequence, is of Famatinian age and took place under higher P/T conditions, following a clockwise P-T path (baric peak: 1300 ± 100 Mpa, 600 ± 50 °C). Low-U zircon overgrew detrital Grenvillian cores as pressure fell from its peak, and yields U-Pb SHRIMP ages of ca. 460 Ma. This is interpreted as the age of ductile thrusting coincident with early uplift; initial accretion to Gondwana must have occurred before this. The absence of late Neoproterozoic detrital zircons is consistent with a Laurentian origin of the Argentine Precordillera terrane.Centro de Investigaciones Geológica

Grenvillian massif-type anorthosites in the Sierras Pampeanas

We report the discovery of massif-type anorthosites in the Andean basement of the Western Sierras Pampeanas of Argentina. U–Pb zircon dating (by sensitive high-resolution ion microprobe) of a cogenetic gabbronorite dyke yields ages of 1070 ± 41 Ma for igneous emplacement and 431 ± 40 Ma for metamorphism. These anorthosites are petrologically and geochemically comparable with those of the Grenville province of Laurentia. Palaeogeographical reconstructions of Rodinia at 1.0–1.1 Ga suggest that the Sierras Pampeanas anorthosites were part of a large anorthosite province in the late Mesoproterozoic.Centro de Investigaciones Geológica

BVRI Light Curves for 29 Type Ia Supernovae

BVRI light curves are presented for 27 Type Ia supernovae discovered during the course of the Calan/Tololo Survey and for two other SNe Ia observed during the same period. Estimates of the maximum light magnitudes in the B, V, and I bands and the initial decline rate parameter m15(B) are also given.Comment: 17 pages, figures and tables are not included (contact first author if needed), to appear in the Astronomical Journa