Comparing soil boundaries delineated by digital analysis of multispectral scanner data from high and low spatial resolution systems

The author has identified the following significant results. Computer-aided analysis techniques used with aircraft MSS data showed that the spatial resolution was sufficient to recognize each soil mapping unit of the test site. Some difficulties occurred where different soil series were intricately mixed, and this mixture showed as a separate spectral mapping unit, or where the difference between two soils depended on the depth of silty surface material. Analysis of LANDSAT data with computer-aided techniques showed that it was not possible to find spectrally homogeneous soil features of the seven soil series on the 40 ha test site on the digital display or on a picture print map. Cluster techniques could be used on an extended test area to group spectrally similar data points into cluster classes

Plio-Pleistocene time-averaged field in southern Patagonia recorded in lava flows

Paleomagnetic directions were obtained from stepwise alternating-field or thermal demagnetization of 53 lava flows from southern Patagonia (latitudes 49.5°-52.1 °S) that include the Pali-Aike volcanic field and the Meseta Viscachas plateau lavas. In addition to previous Miocene-late Quaternary ages of these flows, 40Ar/39Ar dates spanning from 0.1 to 15.4 Ma were obtained for 17 of the sites. All except one of the magnetic polarities coincide with the expected polarities of the magnetic polarity timescale [Cande and Kent, 1995] for the obtained 40Ar/39Ar ages. The mean direction from 33 sites (eliminating sites <4 Ma) that pass a selection criteria of α95 ≤5° is Dec = 358.7°,Inc = - 68.2°, α95 = 3.5°, a value that coincides within the statistical uncertainty with the direction of the geocentric axial dipole for that area (Inc = - 68.1°). Likewise, the mean virtual geomagnetic pole (VGP) coincides within the statistical uncertainty with the geographic North Pole. The secular variation described by the VGP angular standard deviation for these sites is 17.1°, a value expected for that latitude according to Model G of paleosecular variation [McFadden et al., 1988]. The characteristics of the data presented are optimum for time-averaged field (TAF) studies because of the good age control and good quality of the paleomagnetic data: (1) primary components of magnetization were obtained using principal component analysis [Kirschvink, 1980] from at least five points and maximum angular deviation ≤5°, (2) site means were calculated with Fisher statistics using at least three samples, and (c) 38 of the 53 flows had α95 ≤ 5°. No results (five sites) or high α95 values (≤5°) were obtained primarily from sites affected by lightning.Fil: Mejia, V.. University of Florida; Estados UnidosFil: Opdyke, N. D.. University of Florida; Estados UnidosFil: Vilas, Juan Francisco A.. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Departamento de Geología; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Geociencias Básicas, Aplicadas y Ambientales de Buenos Aires. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Instituto de Geociencias Básicas, Aplicadas y Ambientales de Buenos Aires; ArgentinaFil: Singer, B. S.. University of Wisconsin; Estados UnidosFil: Stoner, J. S.. State University of Colorado at Boulder; Estados Unido

Chemicals having estrogenic activity can be released from some bisphenol a-free, hard and clear, thermoplastic resins

Background: Chemicals that have estrogenic activity (EA) can potentially cause adverse health effects in mammals including humans, sometimes at low doses in fetal through juvenile stages with effects detected in adults. Polycarbonate (PC) thermoplastic resins made from bisphenol A (BPA), a chemical that has EA, are now often avoided in products used by babies. Other BPA-free thermoplastic resins, some hypothesized or advertised to be EA-free, are replacing PC resins used to make reusable hard and clear thermoplastic products such as baby bottles. Methods: We used two very sensitive and accurate in vitro assays (MCF-7 and BG1Luc human cell lines) to quantify the EA of chemicals leached into ethanol or water/saline extracts of fourteen unstressed or stressed (autoclaving, microwaving, UV radiation) thermoplastic resins. Estrogen receptor (ER)-dependent agonist responses were confirmed by their inhibition with the ER antagonist ICI 182,780. Results: Our data showed that some (4/14) unstressed and stressed BPA-free thermoplastic resins leached chemicals having significant levels of EA, including one polystyrene (PS), and three Tritan™ resins, the latter reportedly EA-free. Exposure to UV radiation in natural sunlight resulted in an increased release of EA from Tritan™ resins. Triphenyl-phosphate (TPP), an additive used to manufacture some thermoplastic resins such as Tritan™, exhibited EA in both MCF-7 and BG1Luc assays. Ten unstressed or stressed glycol-modified polyethylene terephthalate (PETG), cyclic olefin polymer (COP) or copolymer (COC) thermoplastic resins did not release chemicals with detectable EA under any test condition. Conclusions: This hazard survey study assessed the release of chemicals exhibiting EA as detected by two sensitive, widely used and accepted, human cell line in vitro assays. Four PC replacement resins (Tritan™ and PS) released chemicals having EA. However, ten other PC-replacement resins did not leach chemicals having EA (EA-free-resins). These results indicate that PC-replacement plastic products could be made from EA-free resins (if appropriate EA-free additives are chosen) that maintain advantages of re-usable plastic items (price, weight, shatter resistance) without releasing chemicals having EA that potentially produce adverse health effects on current or future generations.This work was supported by the following NIH/NIEHS grants: R44 ES011469, 01–03 (CZY); 1R43/44 ES014806, 01–03 (CZY); subcontract (CZY, PI) on an NIH Grant 01–03 43/44ES018083-01. This work was also supported by NIH grants to MSD (P42 ES004699), and DJK and SIY (1R43ES018083-01-03, NIEHS 1R44ES019442-01-03 and NIEHS 2R44ES016964-01-03).Neuroscienc

A randomized trial evaluating an mHealth system to monitor and enhance adherence to pharmacotherapy for alcohol use disorders

BACKGROUND: Nonadherence to prescribed medication regimens is a substantial barrier to the pharmacological management of alcohol use disorders. The availability of low-cost, sustainable interventions that maximize medication adherence would likely lead to improved treatment outcomes. Mobile health (mHealth) technologies are increasingly being adopted as a method of delivering behavioral health interventions and represent a promising tool for adherence interventions. We are evaluating a cell-phone–based intervention called AGATE that seeks to enhance adherence with regular text-messaging. METHODS/DESIGN: A randomized controlled effectiveness trial in the context of an eight-week open label naltrexone efficacy trial delivered in a naturalistic clinical setting. Treatment-seeking heavy drinkers (N = 105) are currently being recruited and randomly assigned to the AGATE intervention or a control condition. Daily measures of alcohol use and medication side effects are being recorded via cell phone in both conditions. Additionally, participants randomized to the AGATE condition receive medication reminders via SMS text message according to a schedule that adjusts according to their level of adherence. DISCUSSION: Results from this trial will provide initial information about the feasibility and efficacy of mHealth interventions for improving adherence to alcohol pharmacotherapies. TRIAL REGISTRATION: NCT01349985

Ferromagnetic transition of a two-component Fermi gas of Hard Spheres

We use microscopic many-body theory to analyze the problem of itinerant ferromagnetism in a repulsive atomic Fermi gas of Hard Spheres. Using simple arguments, we show that the available theoretical predictions for the onset of the ferromagnetic transition predict a transition point at a density ($k_F a \sim 1$) that is too large to be compatible with the universal low-density expansion of the energy. We present new variational calculations for the hard-sphere Fermi gas, in the framework of Fermi hypperneted chain theory, that shift the transition to higher densities ($k_F a \sim 1.8$). Backflow correlations, which are mainly active in the unpolarized system, are essential for this shift

Accounting students' IT applicaton skills over a 10-year period

This paper reports on the changing nature of a range of information technology (IT) application skills that students declare on entering an accounting degree over the period from 1996 to 2006. Accounting educators need to be aware of the IT skills students bring with them to university because of the implications this has for learning and teaching within the discipline and the importance of both general and specific IT skills within the practice and craft of accounting. Additionally, IT skills constitute a significant element within the portfolio of employability skills that are increasingly demanded by employers and emphasized within the overall Higher Education (HE) agenda. The analysis of students' reported IT application skills on entry to university, across a range of the most relevant areas of IT use in accounting, suggest that their skills have continued to improve over time. However, there are significant differential patterns of change through the years and within cohorts. The paper addresses the generalizability of these findings and discusses the implications of these factors for accounting educators, including the importance of recognising the differences that are potentially masked by the general increase in skills; the need for further research into the changing nature, and implications, of the gender gap in entrants' IT application skills; and the low levels of entrants' spreadsheet and database skills that are a cause for concern

Landau-Zener-Stueckelberg effect in a model of interacting tunneling systems

The Landau-Zener-Stueckelberg (LZS) effect in a model system of interacting tunneling particles is studied numerically and analytically. Each of N tunneling particles interacts with each of the others with the same coupling J. This problem maps onto that of the LZS effect for a large spin S=N/2. The mean-field limit N=>\infty corresponds to the classical limit S=>\infty for the effective spin. It is shown that the ferromagnetic coupling J>0 tends to suppress the LZS transitions. For N=>\infty there is a critical value of J above which the staying probability P does not go to zero in the slow sweep limit, unlike the standard LZS effect. In the same limit for J>0 LZS transitions are boosted and P=0 for a set of finite values of the sweep rate. Various limiting cases such as strong and weak interaction, slow and fast sweep are considered analytically. It is shown that the mean-field approach works well for arbitrary N if the interaction J is weak.Comment: 13 PR pages, 15 Fig

How well does ramped thermal oxidation quantify the age distribution of soil carbon? Assessing thermal stability of physically and chemically fractionated soil organic matter

Carbon (C) in soils persists on a range of timescales depending on physical, chemical, and biological processes that interact with soil organic matter (SOM) and affect its rate of decomposition. Together these processes determine the age distribution of soil C. Most attempts to measure this age distribution have relied on operationally defined fractions using properties like density, aggregate stability, solubility, or chemical reactivity. Recently, thermal fractionation, which relies on the activation energy needed to combust SOM, has shown promise for separating young from old C by applying increasing heat to decompose SOM. Here, we investigated radiocarbon (C-14) and C-13 of C released during thermal fractionation to link activation energy to the age distribution of C in bulk soil and components previously separated by density and chemical properties. While physically and chemically isolated fractions had very distinct mean C-14 values, they contributed C across the full temperature range during thermal analysis. Thus, each thermal fraction collected during combustion of bulk soil integrates contributions from younger and older C derived from components having different physical and chemical properties but the same activation energy. Bulk soil and all density and chemical fractions released progressively older and more C-13-enriched C with increasing activation energy, indicating that each operationally defined fraction itself was not homogeneous but contained a mix of C with different ages and degrees of microbial processing. Overall, we found that defining the full age distribution of C in bulk soil is best quantified by first separating particulate C prior to thermal fractionation of mineral-associated SOM. For the Podzol analyzed here, thermal fractions confirmed that similar to 95 % of the mineral-associated organic matter (MOM) had a relatively narrow C-14 distribution, while 5 % was very low in C-14 and likely reflected C from the < 2 mm parent shale material in the soil matrix. After first removing particulate C using density or size separation, thermal fractionation can provide a rapid technique to study the age structure of MOM and how it is influenced by different OM-mineral interactions