Production of hybrid granitic magma at the advancing front of basaltic underplating: Inferences from the Sesia Magmatic System (south-western Alps, Italy)

The Permian Sesia Magmatic System of the southwestern Alps displays the plumbing system beneath a Permian caldera, including a deep crustal gabbroic complex, upper crustal granite plutons and a bimodal volcanic field dominated by rhyolitic tuff filling the caldera. Isotopic compositions of the deep crustal gabbro overlap those of coeval andesitic basalts, whereas granites define a distinct, more radiogenic cluster (Sri 480.708 and 0.710, respectively). AFC computations starting from the best mafic candidate for a starting melt show that Nd and Sr isotopic compositions and trace elements of andesitic basalts may be modeled by reactive bulk assimilation of 4830% of partially depleted crust and 4815%\u201330% gabbro fractionation. Trace elements of the deep crustal gabbro cumulates require a further 4860% fractionation of the andesitic basalt and loss of 4840% of silica-rich residual melt. The composition of the granite plutons is consistent with a mixture of relatively constant proportions of residual melt delivered from the gabbro and anatectic melt. Chemical and field evidence leads to a conceptual modelwhich links the production of the two granitic components to the evolution of theMafic Complex. During the growth of the Mafic Complex, progressive incorporation of packages of crustal rocks resulted in a roughly steady state rate of assimilation. Anatectic granite originates in the hot zone of melting crust located above the advancing mafic intrusion. Upward segregation of anatectic melts facilitates the assimilation of the partially depleted restite by stoping. At each cycle of mafic intrusion and incorporation, residual and anatectic melts are produced in roughly constant proportions, because the amount of anatectic melt produced at the roof is a function of volume and latent heat of crystallization of the underplated mafic melt which in turn produces proportional amounts of hybrid gabbro cumulates and residualmelt. Such a process can explain the restricted range in isotopic compositions of most rhyolitic and granitic rocks of the Permo-Carboniferous province of Europe and elsewhere

U-Pb zircon SHRIMP data from the Cana Brava layered complex: new constraints for the mafic-ultramafic intrusions of Northern Goiás, Brazil

The Cana Brava Complex is the northernmost and less-known layered intrusion of a discontinuous belt of mafic-ultramafic massifs within the Brasilia Belt, which also comprises the Niquelândia and Barro Alto complexes. Available geochronological determination by means of different systematics (K/Ar, Ar/Ar, Rb/Sr, Sm/Nd and U/Pb) provide a range of possible ages (time span from 3.9 Ga to 450 Ma), hence a precise and statistically reliable age for the Cana Brava Complex is still lacking. Also, preliminary isotopic and geochemical data of the Cana Brava Complex suggest a significant crustal contamination, which could have affected bulk-rock Sr and Nd systematics resulting in meaningless age determinations. In this paper, we present new U-Pb SHRIMP zircon analyses from four samples of different units of the Cana Brava Complex which suggest that the intrusion occurred during the Neoproterozoic, between 800 and 780 Ma, i.e. at the same age of Niquelândia. Discordant older 206Pb/238U ages are provided by inherited zircons, and match the age of the metamorphism of the encasing Palmeirópolis Sequence

Comparing the Cana Brava and Niquelândia complexes: large mafic-ultramafic intrusions in the lower crust and contamination processes

Mafic-ultramafic complexes offer a unique opportunity to study how intrusions of mantlederived melts growth into the deep crust and interact with the country rocks. The Cana Brava and Niquelândia complexes are two mafic-ultramafic bodies which outcrop within the Brasilia Belt (Goias, central Brazil) and that intruded the metavolcanicmetasedimentary sequences of Palmeiropolis and Indaianopolis during a Neoproterozoic continental rifting. The two complexes are parts, together with the Barro Alto complex, of a ~350 km NNE-trend belt of layered bodies which were exhumed during the Gondwana formation. New field, geochemical and isotopic data give new constraints on the model of growth of these complexes and the interactions between parent melts and the lower crust. Field evidences suggest that the complexes grow via multiple-melt intrusions under hyper- to subsolidus shear conditions. During the complex growth, the upper metavolcanic-metasedimentary sequence was delaminated and xenoliths were incorporated and deformed within the crystal mush. The increase of the 87Sr/86Sr(790) along the complex stratigraphy, coupled with a decrease of the εNd(790), provides evidences of strong crustal contamination by the embedded xenoliths. The enrichment in most incompatible elements (e.g. K, Ba and LREE) and hydrous phases (biotite and amphibole) in rocks containing more xenoliths supports also the crustal contamination. The almost linear trend of isotopic contamination suggests that this process involved all the magma colum, similarly to AFC. However, the increase abundance of incompatible elements and H2O contents toward xenoliths-rich bands provide for a local effect of contamination

Zircon ages in granulite facies rocks: decoupling from geochemistry above 850 °C?

Granulite facies rocks frequently show a large spread in their zircon ages, the interpretation of which raises questions: Has the isotopic system been disturbed? By what process(es) and conditions did the alteration occur? Can the dates be regarded as real ages, reflecting several growth episodes? Furthermore, under some circumstances of (ultra-)high-temperature metamorphism, decoupling of zircon U–Pb dates from their trace element geochemistry has been reported. Understanding these processes is crucial to help interpret such dates in the context of the P–T history. Our study presents evidence for decoupling in zircon from the highest grade metapelites (> 850 °C) taken along a continuous high-temperature metamorphic field gradient in the Ivrea Zone (NW Italy). These rocks represent a well-characterised segment of Permian lower continental crust with a protracted high-temperature history. Cathodoluminescence images reveal that zircons in the mid-amphibolite facies preserve mainly detrital cores with narrow overgrowths. In the upper amphibolite and granulite facies, preserved detrital cores decrease and metamorphic zircon increases in quantity. Across all samples we document a sequence of four rim generations based on textures. U–Pb dates, Th/U ratios and Ti-in-zircon concentrations show an essentially continuous evolution with increasing metamorphic grade, except in the samples from the granulite facies, which display significant scatter in age and chemistry. We associate the observed decoupling of zircon systematics in high-grade non-metamict zircon with disturbance processes related to differences in behaviour of non-formula elements (i.e. Pb, Th, U, Ti) at high-temperature conditions, notably differences in compatibility within the crystal structure

PRELIMINARY U-Pb LA-ICPMS ZIRCON ANALYSES FROM THE GOIAS COMPLEXES: SHRIMP COMPARISON AND INTRUSION AGE

Cana Brava, Niquelàndia and Barro Alto are three mafic-ultramafic layered intrusions (from N to S) which form a - 350 km, NNE-trend belt within the Brasilia Belt (Goiés state, Brazil). Presently, their intrusion ages and geologica! evolution are stili debated. The Niquelàndia and Barro Alto complexes are forrned by two main sequences: the upper sequence and the lower one. Some authors suggest that the two sequences represent two separate intrusions: the upper sequence would be a Mesoproterozoic intrusion at - 1.3 Ga, whereas the lower sequence a Neoproterozic one at - 790 Ma. According to this interpretation, the two sequences were re-crystallized by Neoproterozoic metamorphism and exhumed and juxtaposed during the Brazilian event of formation of the Gondwana continent. Another model suggests that the two sequences are part of the same intrusion, which occurred during the Neoproterozoic and was exhumed during the Brazilian event. New U-Pb SHRIMP-II zircon analyses were perforrned at the Universidade de Sào Paulo from samples from Cana Brava and Barro Alto, the two least-known complexes in order to clarify the sequence of events that led to their forrnation. Analyses were then replicated at the CIGS of the Università di Modena e Reggio Emilia using a X Series" quadrupole ICP-MS coupled with a New Wave UP-213 Nd:YAG laser ablation system. Zircons were sampled through a 40 micron spot (static mode), using a He flux of 0.6 l/min, with an energy density of - 6 J/cm2. Daily instrument calibration was perforrned with the NIST 610 standard, monitoring also the oxide production rate {232Th160/232Th << 0.01 %). Laser-induced elemental fractionation was corrected by repeated analyses of the standard zircon TEMORA2 (Black et al., 2004). A secondary reference materia! (zircon CZ3) was used to check the precision and accuracy of the corrections. Our LA-ICP-MS data are preliminary, but very promising being the accuracy of the measured ratio within the SHRIMP variability. We are currently working to improve the precision of our methodology, which however is now comparable with literature LA-ICP-MS data (propagated 2SE - 2-6%; Horstwood et al., 2008). Overall, the isotopic data of Cana Brava and Barro Alto complexes previde for a coeval Neoproterozoic intrusion age at - 790 Ma. These ages are consistent with those reported in literature for Niquelàndia. Mesoproterozoic ages, consistent with the forrnation age of the metavolcanic-metasedimentary sequence in magmatic contaci with the complexes, were found in inherited zircon cores. Our data clearly show that the Goiàs complexes are formed by single bodies intruded during the Neoproterozoic at -790 Ma and that the hypothesis of two separate intrusions juxtaposed by tectonic must be discarded

Permian high-temperature metamorphism in the Western Alps (NW Italy)

During the late Palaeozoic, lithospheric thinning in part of the Alpine realm caused high-temperature low-to-medium pressure metamorphism and partial melting in the lower crust. Permian metamorphism and magmatism has extensively been recorded and dated in the Central, Eastern, and Southern Alps. However, Permian metamorphic ages in the Western Alps so far are constrained by very few and sparsely distributed data. The present study fills this gap. We present U/Pb ages of metamorphic zircon from several Adria-derived continental units now situated in the Western Alps, defining a range between 286 and 266 Ma. Trace element thermometry yields temperatures of 580-890°C from Ti-in-zircon and 630-850°C from Zr-in-rutile for Permian metamorphic rims. These temperature estimates, together with preserved mineral assemblages (garnet-prismatic sillimanite-biotite-plagioclase-quartz-K-feldspar-rutile), define pervasive upper-amphibolite to granulite facies conditions for Permian metamorphism. U/Pb ages from this study are similar to Permian ages reported for the Ivrea Zone in the Southern Alps and Austroalpine units in the Central and Eastern Alps. Regional comparison across the former Adriatic and European margin reveals a complex pattern of ages reported from late Palaeozoic magmatic and metamorphic rocks (and relics thereof): two late Variscan age groups (~330 and ~300 Ma) are followed seamlessly by a broad range of Permian ages (300-250 Ma). The former are associated with late-orogenic collapse; in samples from this study these are weakly represented. Clearly, dominant is the Permian group, which is related to crustal thinning, hinting to a possible initiation of continental rifting along a passive margin

Zircon U‐Pb Dating of a Lower Crustal Shear Zone: A Case Study From the Northern Sector of the Ivrea‐Verbano Zone (Val Cannobina, Italy)

A geochronological study was performed on zircon grains from a middle‐lower crustal shear zone exposed in the northern sector of the Ivrea‐Verbano Zone (Southern Alps, Italy) for the first time. The shear zone developed at the boundary between mafic rocks of the External Gabbro unit and ultramafic rocks of the Amphibole Peridotite unit. It is ~10–20 m wide, can be followed along a NE strike for several kilometers, and consists of an anastomosing network of mylonites and ultramylonites. Zircon grains were studied in thin sections and as separates from three representative outcrops along the shear zone. Zircon grains are more abundant in the shear zone compared to wall rocks and are generally equant, rounded to subrounded with dimensions up to 500 μm. U‐Pb data are mainly discordant, and the apparent ²⁰⁶Pb/²³⁸U dates show a large variation from Permian to Jurassic. Isotopic data, combined with microstructural, morphological, and internal features of zircon, reveal an inherited age component and suggest partial zircon recrystallization under high‐temperature conditions during Late Triassic to Early Jurassic. High‐temperature deformation in the shear zone, at lower crustal levels, was coeval with amphibolite to greenschist facies mylonitic deformation at upper crustal levels and is inferred to be related to Mesozoic rifting processes at the Adriatic margin

Structure and petrography of the Valle Mosso pluton, Sesia Magmatic System, Southern Alps

5noThe Valle Mosso pluton (VMP) is a Permian granitic body intruded at intermediate to upper crustal levels in the rocks of the pre-Alpine basement of the Ivrea-Verbano Zone and Serie dei Laghi shortly after the end of Variscan orogeny. As a consequence of Triassic to Jurassic rifting and Alpine orogeny, the VMP and surrounding host rocks have been tilted more than 60° from their original Permian polarity. Thus at present day, the VMP offers the rare opportunity to study a roof-to-floor exposure of a granitic pluton, providing insights into pristine geometry of the magma chamber and its relations to the country rocks. This work presents a new drift and solid map of the VMP and its surrounding host rocks at 1:15.000 scale.open accessopenopenTavazzani, Lorenzo; Peres, Stefano; Sinigoi, Silvano; Demarchi, Gabriella; Musumeci, GiovanniTavazzani, Lorenzo; Peres, Stefano; Sinigoi, Silvano; Demarchi, Gabriella; Musumeci, Giovann

L’evoluzione del sistema magmatico dell’isola d’Ischia, Italia meridionale, negli ultimi 10ka

Tutor di MARIA CHIARA ANDRIA - Scopo principale del presente lavoro è fornire un contributo significativo alle indagini vulcanologiche e petrologiche sul sistema magmatico dell'isola d'Ischia. In particolare, è stato eseguito uno studio petrografico, geochimico e geochimico-isotopico di dettaglio focalizzato su prodotti vulcanici degli ultimi 10ka, la fase più recente dell'attività vulcanica dell'isola. In quest'arco di tempo si sono succedute 46 eruzioni vulcaniche, sia di tipo esplosivo che di tipo effusivo, concentrate in particolare nel settore orientale dell'isola. L'interesse sorge soprattutto dal fatto che il sistema magmatico di Ischia è ancora attivo, come testimoniato dall'attività vulcanica che si è verificata fino a tempi storici (l'ultima eruzione risale al 1302 A.D.), e dall'odierna attività sismica e fumarolica. Inoltre, essendo un'isola densamente abitata, soprattutto per l'intensa attività turistica, i rischi connessi ai fenomeni vulcanici sono estremamente alti. Dalle analisi eseguite e dalla loro interpretazione si delinea che le variazioni geochimiche osservate nei prodotti degli ultimi 10ka possono essere spiegate dall'interazione di due processi principali, cristallizzazione frazionata dai termini shoshonitico-latitici ai termini trachitico-fonolitici e mixing/mingling. Lo studio geochimico di dettaglio su olivine e clinopirosseni presenti all'interno delle rocce delle unità piroclastiche di Molara, Vateliero e Cava Nocelle ha fornito ulteriori evidenze di fenomeni di disequilibrio presenti nel sistema magmatico di Ischia e ha permesso di individuare quali possano essere i due end-member che si mescolano l'uno all'altro. Le olivine e i clinopirosseni magnesiaci ritrovati all'interno di queste unità sono in sostanziale equilibrio chimico con un magma K-basaltico simile a quello rappresentato dai litici lavici presenti nella formazione di Solchiaro a Procida, che quindi è presente anche nel sistema magmatico dell'isola d'Ischia e risale in superficie attraverso la faglia di direzione NW-SE, di importanza regionale, su cui sono impostati i centri eruttivi di Molara, Vateliero e Cava Nocelle. Tale faglia ha la sua prosecuzione in terraferma nei Campi Flegrei e mette direttamente in relazione questi tre centri eruttivi di Ischia con altri dei Campi Flegrei, Minopoli 2 e Pigna San Nicola, che pure hanno dato origine a prodotti meno evoluti. Quindi il primo end-member è di tipo K-basaltico; il secondo è un end-member trachitico, rappresentato dai prodotti delle Piroclastiti di Cretaio, che si è comportato da sistema chiuso fino al mixing-mingling. Gli isotopi di Sr e Nd forniscono altrettante evidenze di un meccanismo complesso che opera all'interno del sistema magmatico, perché coesistono prodotti a diverso contenuto di 87Sr/86Sr nel corso di tutto il periodo di attività e in particolare circa 3ka b.p. vengono eruttati i prodotti più radiogenici, che risultano essere anche quelli meno evoluti. Nel sistema quindi dev'essere arrivato un nuovo magma più ricco di Sr radiogenico rispetto a quello residente, che corrisponde al termine K-basaltico. Inoltre le analisi isotopiche hanno evidenziato una correlazione negativa presente tra i rapporti 87Sr/86Sr e 143Nd/144Nd per i termini meno evoluti, rappresentati dai clinopirosseni diopsidici delle Piroclastiti di Molara e Cava Nocelle, che hanno anche il maggior contenuto di Sr radiogenico. Dallo studio integrato degli isotopi di Sr con il d18O si è potuto verificare che i dati ottenuti suggeriscono la presenza di una sorgente contaminata, ricca in Sr radiogenico, ma non radiogenica per il Nd. Tale ipotesi è in accordo con quanto suggerito da altri autori che ritengono che ci sia stato una contaminazione della sorgente astenosferica da parte di fluidi e fusi derivanti da una slab in subduzione