Substrate Dependant Microbial Synthesis of Silver Nanoparticle and its Application as Antimicrobial Agent

Microbial synthesis of nanoparticles is a green chemistry approach that interconnects nanotechnology and microbial biotechnology. In this present study, synthesis of silver nanoparticles (AgNPs) has been demonstrated using a metabolically versatile actinobacteria Rhodococcus sp. by reducing aqueous silver nitrate. The AgNPs were characterized by Ultraviolet–Visible (UV – vis) Spectrometer, Scanning Electron Microscopy (SEM), Energy Dispersive X-ray Analysis (EDAX), Dynamic Light Scattering (DLS), Selected Area Diffraction Pattern (SAED) and Transmission Electron Microscopy (TEM). The TEM showed spherical particles with an average size of 10 nm. The SAED pattern showed the characteristic Bragg peaks of (111), (200), (220) and (311) facets of the face centered cubic (fcc) silver nanoparticles and confirmed that these nanoparticles are crystalline in nature. When you are citing the document, use the following link http://essuir.sumdu.edu.ua/handle/123456789/3482

Impact of source of infection and vancomycin AUC0–24/MICBMD targets on treatment failure in patients with methicillin-resistant Staphylococcus aureus bacteraemia

AbstractDespite recent controversies about toxicity and reduced efficacy, vancomycin remains the current treatment of choice for methicillin-resistant Staphylococcus aureus (MRSA) bacteraemia. The parameter associated with treatment success is the vancomycin 24-h area under concentration-time curve to MIC ratio (AUC0–24/MIC). We aimed to determine the utility of calculated AUCs and explore the optimal AUC0–24/MIC targets associated with treatment success. In this single-centre retrospective observational cohort study of 127 patients with MRSA bacteraemia, forty-five (35.4%) did not respond to vancomycin treatment. Patient characteristics were essentially the same between those who did not respond to vancomycin treatment and those with treatment success, with independent predictors of treatment failure being source of bacteraemia (odds ratio (OR), 4.29; 95% confidence interval (CI), 1.50–12.26; p 0.007) and not achieving an AUC0–24/MICBMD (using broth microdilution) target of ≥398 (OR, 11.4; 95% CI, 4.57–28.46; p< 0.001). Bacteraemic source-specific thresholds were observed with a higher AUC0–24/MICBMD target of 440 required for high-risk sources (e.g. infective endocarditis) compared with 330 for low-risk sources (line related bacteraemia). Overall treatment success in patients with MRSA bacteraemia was associated with a vancomycin AUC0–24/MICBMD target of ≥398, with source-specific targets observed. Future vancomycin practice guidelines will need to take into account MIC methodology, source of bacteraemia and patient populations prior to setting targets and monitoring recommendations

On the gauge and BRST invariance of the chiral QED with Faddeevian anomaly

Chiral Schwinger model with the Faddeevian anomaly is considered. It is found that imposing a chiral constraint this model can be expressed in terms of chiral boson. The model when expressed in terms of chiral boson remains anomalous and the Gauss law of which gives anomalous Poisson brackets between itself. In spite of that a systematic BRST quantization is possible. The Wess-Zumino term corresponding to this theory appears automatically during the process of quantization. A gauge invariant reformulation of this model is also constructed. Unlike the former one gauge invariance is done here without any extension of phase space. This gauge invariant version maps onto the vector Schwinger model.The gauge invariant version of the chiral Schwinger model for $a=2$ has a massive field with identical mass however gauge invariant version obtained here does not map on to that.Comment: 11 pages latex, no figures, A little change in Title and abstrac

Shadowing in photo-production : role of in-medium hadrons

We study the effects of in-medium hadronic properties on shadowing in photon-nucleus interactions in Glauber model as well as in the multiple scattering approach. A reasonable agreement with the experimental data is obtained in a scenario of downward spectral shift of the hadrons. Shadowing is found to be insensitive to the broadening of the spectral functions. An impact parameter dependent analysis of shadowing might shed more light on the role of in-medium properties of hadrons.Comment: Title modified; version to appear in PRC, Rapid Communication

A Green's function approach to transmission of massless Dirac fermions in graphene through an array of random scatterers

We consider the transmission of massless Dirac fermions through an array of short range scatterers which are modeled as randomly positioned $\delta$- function like potentials along the x-axis. We particularly discuss the interplay between disorder-induced localization that is the hallmark of a non-relativistic system and two important properties of such massless Dirac fermions, namely, complete transmission at normal incidence and periodic dependence of transmission coefficient on the strength of the barrier that leads to a periodic resonant transmission. This leads to two different types of conductance behavior as a function of the system size at the resonant and the off-resonance strengths of the delta function potential. We explain this behavior of the conductance in terms of the transmission through a pair of such barriers using a Green's function based approach. The method helps to understand such disordered transport in terms of well known optical phenomena such as Fabry Perot resonances.Comment: 22 double spaced single column pages. 15 .eps figure

Theory of excited state absorptions in phenylene-based π\pi-conjugated polymers

Within a rigid-band correlated electron model for oligomers of poly-(paraphenylene) (PPP) and poly-(paraphenylenevinylene) (PPV), we show that there exist two fundamentally different classes of two-photon A$_g$ states in these systems to which photoinduced absorption (PA) can occur. At relatively lower energies there occur A$_g$ states which are superpositions of one electron - one hole (1e--1h) and two electron -- two hole (2e--2h) excitations, that are both comprised of the highest delocalized valence band and the lowest delocalized conduction band states only. The dominant PA is to one specific member of this class of states (the mA$_g$). In addition to the above class of A$_g$ states, PA can also occur to a higher energy kA$_g$ state whose 2e--2h component is {\em different} and has significant contributions from excitations involving both delocalized and localized bands. Our calculated scaled energies of the mA$_g$ and the kA$_g$ agree reasonably well to the experimentally observed low and high energy PAs in PPV. The calculated relative intensities of the two PAs are also in qualitative agreement with experiment. In the case of ladder-type PPP and its oligomers, we predict from our theoretical work a new intense PA at an energy considerably lower than the region where PA have been observed currently. Based on earlier work that showed that efficient charge--carrier generation occurs upon excitation to odd--parity states that involve both delocalized and localized bands, we speculate that it is the characteristic electronic nature of the kA$_g$ that leads to charge generation subsequent to excitation to this state, as found experimentally.Comment: Revtex4 style, 2 figures inserted in the text, three tables, 10 page

Phenomenology of Λ\Lambda-CDM model: a possibility of accelerating Universe with positive pressure

Among various phenomenological $\Lambda$ models, a time-dependent model $\dot \Lambda\sim H^3$ is selected here to investigate the $\Lambda$-CDM cosmology. Using this model the expressions for the time-dependent equation of state parameter $\omega$ and other physical parameters are derived. It is shown that in $H^3$ model accelerated expansion of the Universe takes place at negative energy density, but with a positive pressure. It has also been possible to obtain the change of sign of the deceleration parameter $q$ during cosmic evolution.Comment: 16 Latex pages, 11 figures, Considerable modifications in the text; Accepted in IJT

Weak Localization Effect in Superconductors by Radiation Damage

Large reductions of the superconducting transition temperature $T_{c}$ and the accompanying loss of the thermal electrical resistivity (electron-phonon interaction) due to radiation damage have been observed for several A15 compounds, Chevrel phase and Ternary superconductors, and $\rm{NbSe_{2}}$ in the high fluence regime. We examine these behaviors based on the recent theory of weak localization effect in superconductors. We find a good fitting to the experimental data. In particular, weak localization correction to the phonon-mediated interaction is derived from the density correlation function. It is shown that weak localization has a strong influence on both the phonon-mediated interaction and the electron-phonon interaction, which leads to the universal correlation of $T_{c}$ and resistance ratio.Comment: 16 pages plus 3 figures, revtex, 76 references, For more information, Plesse see http://www.fen.bilkent.edu.tr/~yjki