Electrokinetic separation of non-steroidal antiinflamatory drugs by using graphene nanoparticles as pseudostationary phase

III Encuentro sobre Nanociencia y Nanotecnología de Investigadores y Tecnólogos Andaluce

Non-critically squeezed light via spontaneous rotational symmetry breaking

We theoretically address squeezed light generation through the spontaneous breaking of the rotational invariance occuring in a type I degenerate optical parametric oscillator (DOPO) pumped above threshold. We show that a DOPO with spherical mirrors, in which the signal and idler fields correspond to first order Laguerre-Gauss modes, produces a perfectly squeezed vacuum with the shape of a Hermite-Gauss mode, within the linearized theory. This occurs at any pumping level above threshold, hence the phenomenon is non-critical. Imperfections of the rotational symmetry, due e.g. to cavity anisotropy, are shown to have a small impact, hence the result is not singular.Comment: 4 pages, 1 figure, replaced with resubmitted versio

Análisis directo de aceite de oliva

The practical impact of “direct analysis” is undeniable as it strong contributes to enhance the so-called productive analytical features such as expeditiousness, reduction of costs and minimisation of risks for the analysts and environment. The main objective is to establish a reliable bypass to the conventional preliminary operations of the analytical process. This paper offers a systematic approach in this context and emphasises the great field of action of direct methodologies in the routine analysis of olive oil. Two main types of methodologies are considered. On the one hand, the direct determination of volatile components is systematically considered. On the other hand, simple procedures to automatically implement the preliminary operations of the oil analysis using simple devices in which the sample is directly introduced with/without a simple dilution are present and discussed.El impacto práctico del análisis directo es tan innegable como que el contribuye decisivamente a mejorar las denominadas características analíticas relacionadas con la productividad como la rapidez, la reducción de costes y la minimización de riesgos para los analistas y el ambiente. El principal objetivo es establecer un adecuado "bypass" a las operaciones convencionales preliminares del proceso analítico. Este artículo ofrece una propuesta sistemática en este contexto y resalta el gran campo de acción de las metodologías directas en los análisis de rutina del aceite de oliva. Se analizan los dos tipos principales de metodologías. Por una lado, se analiza la determinación directa de los compuestos volátiles. Por el otro, se presentan y discuten los procedimientos simples para implementar automáticamente las operaciones preliminares del análisis del aceite usando sistemas simples en los que la muestra se introduce directamente con/sin un dilución simple

Flow injection analysis of water. Part 2: Integrated system for automatic multideterrnination

This paper describes an integrated flow injection (FI) system for the determination of ammonia, sulphate and Fe(II)/Fe(III) which can work unattended for long periods. The system was designed for the determination of individual analytes in long series of samples. Each batch of samples requires manual selection of parameters and units, such as wavelength for monitoring, preconcentration column, loops and switching of three valves to select the carrier, reagents and eluent. The system then works automatically

Espectroscopia. fundamento de la resonancia magnética nuclear

Presentamos una introducción al fenómeno de la espectroscopia, su significado y los principios físicos básicos involucrados en el proceso de absorción y emisión de  radiación que posee una capacidad suficiente para perturbar las condiciones de equilibrio de un átomo. Explicamos  el principio de operación de un espectrómetro sencillo y  analizamos la espectroscopia de resonancia magnética nuclear (RMN) una de las herramientas más poderosas con que cuenta la Medicina moderna para detectar ciertos desequilibrios en la estructura y configuración molecular.AbstractWe present an introduction to the phenomenon of spectroscopy.Its meaning and the basic physical principles involve the process of absorption and emission of radiation that possess enough capacity to perturb the conditions of equilibrium of an atom. We explain the principle of operation of a simple spectrometer and analyze the spectroscopy of nuclear magnetic resonance (NMR). It is one of the most powerful tools available to modern medicine to detect certain imbalances in the structure and molecular configuration

Cycloidal Domains in the Magnetization Reversal Process of Ni80Fe20/Nd16Co84/Gd12Co88 Trilayers

The magnetization reversal of each individual layer in magnetic trilayers ( permalloy / Nd Co / Gd Co ) is investigated in detail with x-ray microscopy and micromagnetic calculations. Two sequential inversion mechanisms are identified. First, magnetic vortex-antivortex pairs move along the field direction while inverting the magnetization of magnetic stripes until they are pinned by defects. The vortex-antivortex displacements are reversible within a field interval which allows their controlled motion. Second, as the reversed magnetic field increases, cycloidal domains appear in the permalloy layer as a consequence of the dissociation of vortex-antivortex pairs due to pinning. The field range where magnetic vortices and antivortices are effectively guided by the stripe pattern is of the order of tens of mT for the Ni Fe layer, as estimated from the stability of cycloid domains in the sample

Theory of quantum fluctuations of optical dissipative structures and its application to the squeezing properties of bright cavity solitons

We present a method for the study of quantum fluctuations of dissipative structures forming in nonlinear optical cavities, which we illustrate in the case of a degenerate, type I optical parametric oscillator. The method consists in (i) taking into account explicitly, through a collective variable description, the drift of the dissipative structure caused by the quantum noise, and (ii) expanding the remaining -internal- fluctuations in the biorthonormal basis associated to the linear operator governing the evolution of fluctuations in the linearized Langevin equations. We obtain general expressions for the squeezing and intensity fluctuations spectra. Then we theoretically study the squeezing properties of a special dissipative structure, namely, the bright cavity soliton. After reviewing our previous result that in the linear approximation there is a perfectly squeezed mode irrespectively of the values of the system parameters, we consider squeezing at the bifurcation points, and the squeezing detection with a plane--wave local oscillator field, taking also into account the effect of the detector size on the level of detectable squeezing.Comment: 10 figure