406 research outputs found

    3D CAMERAS ACQUISITIONS FOR THE DOCUMENTATION OF CULTURAL HERITAGE

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    Abstract. Photography has always been considered as a valid tool to acquire information about reality. Nowadays, its versatility, together with the development of new techniques and technologies, allows to use it in different fields of application. Particularly, in the digitization of built heritage, photography not only enables to understand and document historical and architectural artifacts but also to acquire morphological and geometrical data about them with automated digital photogrammetry. Nowadays, photogrammetry enables many tools to give virtual casts of reality by showing it in the way of point cloud. Although they can have metric reliability and visual quality, traditional instruments &amp;ndash; such as monoscopic cameras &amp;ndash; involve a careful planning of the campaign phase and a long acquisition and processing time. On the contrary, the most recent ones, based on the integration of different sensors and cameras, try to reduce the gap between time and results. The latter include some systems of indoor mapping who, thanks to 360&amp;deg; acquisitions and SLAM technology, reconstruct the original scene in real time in great detail and with a photorealistic rendering. This study is aimed at reporting a research evaluating metric reliability and the level of survey detail with a Matterport Pro2 3D motorized rotating camera, equipped with SLAM technology, whose results have been compared with point clouds obtained by image-based and range-based processes.</p

    Application of Nanoparticles with the Structure of the Metal Nucleus - Carbon Enclosure in Biology and Medicine

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    The study was carried out with the financial support of the Russian Foundation for Basic Research in the framework of the research project No. 18-33-00785

    Dimerization and low-dimensional magnetism in nanocrystalline TiO2 semiconductors doped by Fe and Co

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    The report is devoted to an analysis of the structural and magnetic state of the nanocrystalline diluted magnetic semiconductors based on TiO2 doped with Fe and Co atoms. Structural and magnetic characterization of samples was carried out using X-ray diffraction (XRD) analysis, transmission electron microscopy (TEM), X-ray absorption spectroscopy (XAS), electron paramagnetic resonance (EPR) spectroscopy, SQUID magnetometry, and the density functional theory (DFT) calculations. Analysis of the experimental data suggests the presence of non-interacting paramagnetic Fe3+ and Co2+ ions in the high-spin state and negative exchange interactions between them. The important conclusions is that the distribution of dopants in the TiO2 matrix, even at low concentrations of 3d-metal dopant (less than one percent), is not random, but the 3d ions localization and dimerization is observed both on the surface and in the nanoparticles core. Thus, in the paper the quantum mechanical model for describing the magnetic properties of TiO2:(Fe, Co) was suggested. The model operates only with two parameters: paramagnetic contribution of non-interacting 3d-ions and dimers having different exchange interactions between 3d magnetic carriers. © Published under licence by IOP Publishing Ltd

    Unconventional magnetism of non-uniform distribution of Co in TiO2 nanoparticles

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    High-resolution transmission electron microscopy (HRTEM), X-ray diffraction (XRD) analysis, electron paramagnetic resonance (EPR), X-ray absorption spectroscopy (XAS), magnetic methods, and density-functional theory (DFT) calculations were applied for the investigations of Co-doped anatase TiO2 nanoparticles (∼20 nm). It was found that high-spin Co2+ ions prefer to occupy the interstitial positions in the TiO2 lattice which are the most energetically favourable in compare to the substitutional those. A quantum mechanical model which operates mainly on two types of Co2+ – Co2+ dimers with different negative exchange interactions and the non-interacting paramagnetic Co2+ ions provides a satisfactorily description of magnetic properties for the TiO2:Co system. © 2020 Elsevier B.V.Russian Foundation for Basic Research. Ministry of Science and Higher Education of the Russian Federatio

    Spectral and kinetic features of thermoluminescence in hexagonal boron nitride powder after UV-irradiation

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    Thermally stimulated luminescence (TL) from UV-irradiated h-BN powder synthesized using carbamide technique was studied. Three TL peaks at T max = 380, 500 and 600 K during linear heating with 2 K/s rate in RT - 773 K temperature range were observed. It was found that the 2.90 and 3.25 eV emission bands, which were related with recombination centers on the basis of VN and BO--complexes, dominate in TL spectra of h-BN. Experimental TL glow curves were analyzed in terms of general order kinetics and energy parameters of responsible capture levels were estimated. It was shown, considering the independent data on the luminescent properties of hexagonal boron nitride in different structural states, that TL peaks at 380 K and 600 K were due to traps based on the one-boron and the three-boron centers with thermal depth EA = 0.7 and 1.0 eV, respectively. The possible origin of the trap with EA = 1.6 eV, responsible for the TL peak at 500 K, is discussed. © 2013 Elsevier B.V. All rights reserved

    Magnetic properties and structure of TiO2-Mn (0.73 %) nanopowders: The effects of electron irradiation and vacuum annealing

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    Nanopowder TiO2-0.73 % Mn was synthesized by the sol-gel method. Thermal treatment of the samples was carried out in vacuum at a temperature of 500°C. Magnetic properties were studied in the temperature range from 2 to 850 K. The effects of electron irradiation and vacuum annealing on the EPR spectra and magnetic properties of TiO2-Mn powder are discussed. It was established that a part of manganese ions in the anatase crystal lattice interacts antiferromagnetically, which causes a decrease in magnetization as compared to the result of the calculation for non-interacting ions. Vacuum annealing leads to the formation of oxygen vacancies and, at the same time, to a noticeable increase in the ferromagnetic contribution to magnetization, especially, after preliminary electron irradiation. We assume that the ferromagnetic contribution to the magnetization appears either due to incomplete compensation of antiferromagnetically directed moments of manganese ions, or due to positive exchange interactions of Mn ions via defects in the TiO2 lattice. It is shown that the temperature of magnetic disordering in samples with a spontaneous magnetic moment exceeds 600°C. © 2019, Institute for Metals Superplasticity Problems of Russian Academy of Sciences. All rights reserved

    Complex 99mTc-PDA-DTPA for myocardial imaging

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    The 123I-labeled fatty acids such as 123I-Iodophenylpentadecanoic acid and 123I-Beta-methyliodophenylpentadecanoic acid are the agents used clinically for myocardial imaging. Fatty acids are the major source of energy for the normal myocardium. However, under ischemic conditions the myocardial cells switch to glucose metabolism for their energy needs. Fatty acids undergo prolonged metabolic stunning in patients with reversible ischemia, thereby helping in early diagnosis of coronary artery disease in highrisk patients. High cost andlimited availability of cyclotron-produced 123I, makes 99mTc-labeled fatty acids more desirable for the purpose. In diagnosis the dominant radionuclide is 99mTc. It is estimated that it is involved in about 85% of all imaging procedures in nuclear medicine. The method for preparation of new 99mTc-fatty chemical systems based on modified diethylene triamine pentaacetic acid (DTPA) molecule has been elaborated in this work . The main advantage using DTPA as chelate agent for radioactive label, is the molecule or it's derivative ability to form sufficiently stable complexes with different radioactive metals including technetium-99. Moiety of pentadecanoic acid addition gave the ability to prepare modified complex of DTPA. In a labeling procedure, freshly eluted Na99mTcO4 (20mCi) was added to a mixture of cysteine, stannous chloride, PDK-DTPA and ethanol in a vial. On keeping the reaction mixture at 90 0C for 30 min, [99mTc-PDK-DTPA] radiopharmaceutical was formed. Thereafter, the reaction mixture was cooled over ice and characterized by HPLC. The result of dynamic scintigraphic research showed, that after being injected, the substance is actively acumulated into myocardium. Eventually one can say that modified DTPA-moleculs are functionally suitable for myocardial imaging

    Bispyrenylalkane Chemosensor for the Naked-eye Detection of Nitro-explosives

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    Pyrene-based compounds have a great potential as fluorescent chemosensors for various analytes including common nitro-explosives, such as 2,4,6-trinitrotoluene (TNT). Compounds having two pyrene units in one molecule, such as bispyrenylalkanes, are able to form stable, bright emissive in a visual wavelength region excimers both in non-polar and polar environments. In this work we wish to report that in non-polar solvents the excimer has poor chemosensing properties while in aqueous solutions it provides significant “turn-off” fluorescence response to TNT in the sub-nanomolar concentrations

    Bayesian modeling of recombination events in bacterial populations

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    Background: We consider the discovery of recombinant segments jointly with their origins within multilocus DNA sequences from bacteria representing heterogeneous populations of fairly closely related species. The currently available methods for recombination detection capable of probabilistic characterization of uncertainty have a limited applicability in practice as the number of strains in a data set increases. Results: We introduce a Bayesian spatial structural model representing the continuum of origins over sites within the observed sequences, including a probabilistic characterization of uncertainty related to the origin of any particular site. To enable a statistically accurate and practically feasible approach to the analysis of large-scale data sets representing a single genus, we have developed a novel software tool (BRAT, Bayesian Recombination Tracker) implementing the model and the corresponding learning algorithm, which is capable of identifying the posterior optimal structure and to estimate the marginal posterior probabilities of putative origins over the sites. Conclusion: A multitude of challenging simulation scenarios and an analysis of real data from seven housekeeping genes of 120 strains of genus Burkholderia are used to illustrate the possibilities offered by our approach. The software is freely available for download at URL http://web.abo.fi/fak/ mnf//mate/jc/software/brat.html
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