8,135 research outputs found
Probing molecular dynamics at the nanoscale via an individual paramagnetic center
Understanding the dynamics of molecules adsorbed to surfaces or confined to
small volumes is a matter of increasing scientific and technological
importance. Here, we demonstrate a pulse protocol using individual paramagnetic
nitrogen vacancy (NV) centers in diamond to observe the time evolution of 1H
spins from organic molecules located a few nanometers from the diamond surface.
The protocol records temporal correlations among the interacting 1H spins, and
thus is sensitive to the local system dynamics via its impact on the nuclear
spin relaxation and interaction with the NV. We are able to gather information
on the nanoscale rotational and translational diffusion dynamics by carefully
analyzing the time dependence of the NMR signal. Applying this technique to
various liquid and solid samples, we find evidence that liquid samples form a
semi-solid layer of 1.5 nm thickness on the surface of diamond, where
translational diffusion is suppressed while rotational diffusion remains
present. Extensions of the present technique could be adapted to highlight the
chemical composition of molecules tethered to the diamond surface or to
investigate thermally or chemically activated dynamical processes such as
molecular folding
Magnetic imaging with an ensemble of Nitrogen Vacancy centers in diamond
The nitrogen-vacancy (NV) color center in diamond is an atom-like system in
the solid-state which specific spin properties can be efficiently used as a
sensitive magnetic sensor. An external magnetic field induces Zeeman shifts of
the NV center levels which can be measured using Optically Detected Magnetic
Resonance (ODMR). In this work, we exploit the ODMR signal of an ensemble of NV
centers in order to quantitatively map the vectorial structure of a magnetic
field produced by a sample close to the surface of a CVD diamond hosting a thin
layer of NV centers. The reconstruction of the magnetic field is based on a
maximum-likelihood technique which exploits the response of the four intrinsic
orientations of the NV center inside the diamond lattice. The sensitivity
associated to a 1 {\mu}m^2 area of the doped layer, equivalent to a sensor
consisting of approximately 10^4 NV centers, is of the order of 2
{\mu}T/sqrt{Hz}. The spatial resolution of the imaging device is 400 nm,
limited by the numerical aperture of the optical microscope which is used to
collect the photoluminescence of the NV layer. The versatility of the sensor is
illustrated by the accurate reconstruction of the magnetic field created by a
DC current inside a copper wire deposited on the diamond sample.Comment: 11 pages, 5 figures, figure 4 added, results unchange
Can Polymer Coils be modeled as "Soft Colloids"?
We map dilute or semi-dilute solutions of non-intersecting polymer chains
onto a fluid of ``soft'' particles interacting via a concentration dependent
effective pair potential, by inverting the pair distribution function of the
centers of mass of the initial polymer chains. A similar inversion is used to
derive an effective wall-polymer potential; these potentials are combined to
successfully reproduce the calculated exact depletion interaction induced by
non-intersecting polymers between two walls. The mapping opens up the
possibility of large-scale simulations of polymer solutions in complex
geometries.Comment: 4 pages, 3 figures ReVTeX[epsfig,multicol,amssymb] references update
Anisotropic and strong negative magneto-resistance in the three-dimensional topological insulator Bi2Se3
We report on high-field angle-dependent magneto-transport measurements on
epitaxial thin films of Bi2Se3, a three-dimensional topological insulator. At
low temperature, we observe quantum oscillations that demonstrate the
simultaneous presence of bulk and surface carriers. The magneto- resistance of
Bi2Se3 is found to be highly anisotropic. In the presence of a parallel
electric and magnetic field, we observe a strong negative longitudinal
magneto-resistance that has been consid- ered as a smoking-gun for the presence
of chiral fermions in a certain class of semi-metals due to the so-called axial
anomaly. Its observation in a three-dimensional topological insulator implies
that the axial anomaly may be in fact a far more generic phenomenon than
originally thought.Comment: 6 pages, 4 figure
Comparison of the Breakdown Strength of N2, CO2 and SF6 using the Extended Up-and-Down Method
Electrical Engineering, Mathematics and Computer Scienc
Forensic investigation of microtraces on an item of Dutch eighteenth century clothing in the Rijksmuseum collection
Most garments in museum collections have belonged to people of high societal status. Clothing of the common people, however, has rarely been preserved. Because of this, the conservation of such rare items is of special importance. The current study focuses on such an object from the Rijksmuseum collection; a pair of eighteenth century breeches that were retrieved from an anonymous grave on Spitsbergen. As these breeches contain several unidentified materials, it is unclear how best to conduct the conservation of the object. The identification of trace material plays a key role within criminal law and therefore, it is hypothesized that a forensic approach could provide a suitable framework within this case of cultural heritage as well. After forensic examination, trace material was analyzed using a microscopy-based approach and was found to be mainly of biological origin. Energy-dispersive X-ray (EDX) and Attenuated Total Reflection Fourier Transform Infrared (ATR-FTIR) spectroscopy indicated the presence of human skin remains. It was concluded that a modern forensic approach can successfully be applied to a historical object within cultural heritage and can assist decision-making regarding possible future conservation of the object. The systematic application of the forensic methodology was found to be appropriate with little to no modification to classify and identify trace materials, but further improvements could be made. The current work should be seen as a starting point that allows for more questions regarding museum objects to be answered in a forensic manner, including aspects such as authenticity, the chain of custody, the context, original use and object conservation
Comparative analysis of radiation dose and low contrast detail detectability using routine paediatric chest radiography protocols
Objectives: To compare low contrast detail (LCD) detectability and radiation dose for routine paediatric chest X-ray (CXR) imaging protocols among various hospitals.
Methods: CDRAD 2.0 phantom and medical grade polymethyl methacrylate (PMMA) slabs were used to simulate the chest region of four different paediatric age groups. Radiographic acquisitions were undertaken on 17 X-ray machines located in eight hospitals using their existing CXR protocols. LCD detectability represented by image quality figure inverse (IQFinv) was measured physically using the CDRAD analyser software. Incident air kerma (IAK) measurements were obtained using a solid-state dosimeter.
Results: The range of IQFinv, between and within the hospitals, was 1.40-4.44 and 1.52-2.18, respectively for neonates; 0.96-4.73 and 2.33-4.73 for a 1-year old; 0.87-1.81 and 0.98-1.46 for a 5-year old and 0.90-2.39 and 1.27-2.39 for a 10-year old.
The range of IAK, between and within the hospitals, was 8.56-52.62 µGy and 21.79-52.62 µGy, respectively for neonates; 5.44-82.82 µGy and 36.78-82.82 µGy for a 1-year old; 10.97-59.22 µGy and 11.75-52.94 µGy for a 5-year old and 13.97-100.77 µGy and 35.72-100.77 µGy for a 10-year old.
Conclusions: Results show considerable variation, between and within hospitals, in the LCD detectability and IAK. Further radiation dose optimisation for the four paediatric age groups, especially in hospitals /X-ray rooms with low LCD detectability and high IAK, are required.
Keywords: Paediatric chest radiography, CDRAD phantom, low contrast detail detectability and radiation dose
Diffraction based Hanbury Brown and Twiss interferometry performed at a hard x-ray free-electron laser
We demonstrate experimentally Hanbury Brown and Twiss (HBT) interferometry at
a hard X-ray Free Electron Laser (XFEL) on a sample diffraction patterns. This
is different from the traditional approach when HBT interferometry requires
direct beam measurements in absence of the sample. HBT analysis was carried out
on the Bragg peaks from the colloidal crystals measured at Linac Coherent Light
Source (LCLS). We observed high degree (80%) spatial coherence of the full beam
and the pulse duration of the monochromatized beam on the order of 11 fs that
is significantly shorter than expected from the electron bunch measurements.Comment: 32 pages, 10 figures, 2 table
Enhanced frequency up-conversion in Rb vapor
We demonstrate highly efficient generation of coherent 420nm light via
up-conversion of near-infrared lasers in a hot rubidium vapor cell. By
optimizing pump polarizations and frequencies we achieve a single-pass
conversion efficiency of 260% per Watt, significantly higher than in previous
experiments. A full exploration of the coherent light generation and
fluorescence as a function of both pump frequencies reveals that coherent blue
light is generated close to 85Rb two-photon resonances, as predicted by theory,
but at high vapor pressure is suppressed in spectral regions that do not
support phase matching or exhibit single-photon Kerr refraction. Favorable
scaling of our current 1mW blue beam power with additional pump power is
predicted.Comment: 6 pages, 4 figures. Modified to include referees' improvement
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