Theoretical study of the charge transport through C60-based single-molecule junctions

We present a theoretical study of the conductance and thermopower of single-molecule junctions based on C60 and C60-terminated molecules. We first analyze the transport properties of gold-C60-gold junctions and show that these junctions can be highly conductive (with conductances above 0.1G0, where G0 is the quantum of conductance). Moreover, we find that the thermopower in these junctions is negative due to the fact that the LUMO dominates the charge transport, and its magnitude can reach several tens of micro-V/K, depending on the contact geometry. On the other hand, we study the suitability of C60 as an anchoring group in single-molecule junctions. For this purpose, we analyze the transport through several dumbbell derivatives using C60 as anchors, and we compare the results with those obtained with thiol and amine groups. Our results show that the conductance of C60-terminated molecules is rather sensitive to the binding geometry. Moreover, the conductance of the molecules is typically reduced by the presence of the C60 anchors, which in turn makes the junctions more sensitive to the functionalization of the molecular core with appropriate side groups.Comment: 9 pages, 7 figure

Field enhancement in subnanometer metallic gaps

Motivated by recent experiments [Ward et al., Nature Nanotech. 5, 732 (2010)], we present here a theoretical analysis of the optical response of sharp gold electrodes separated by a subnanometer gap. In particular, we have used classical finite difference time domain simulations to investigate the electric field distribution in these nanojunctions upon illumination. Our results show a strong confinement of the field within the gap region, resulting in a large enhancement compared to the incident field. Enhancement factors exceeding 1000 are found for interelectrode distances on the order of a few angstroms, which are fully compatible with the experimental findings. Such huge enhancements originate from the coupling of the incident light to the evanescent field of hybrid plasmons involving charge density oscillations in both electrodes.Comment: 4 pages, 3 figures, to appear in Physical Review

Stability of non-time-reversible phonobreathers

Non-time reversible phonobreathers are non-linear waves that can transport energy in coupled oscillator chains by means of a phase-torsion mechanism. In this paper, the stability properties of these structures have been considered. It has been performed an analytical study for low-coupling solutions based upon the so called {\em multibreather stability theorem} previously developed by some of the authors [Physica D {\bf 180} 235]. A numerical analysis confirms the analytical predictions and gives a detailed picture of the existence and stability properties for arbitrary frequency and coupling.Comment: J. Phys. A.:Math. and Theor. In Press (2010

Breather Statics and Dynamics in Klein--Gordon Chains with a Bend

In this communication, we examine a nonlinear model with an impurity emulating a bend. We justify the geometric interpretation of the model and connect it with earlier work on models including geometric effects. We focus on both the bifurcation and stability analysis of the modes that emerge as a function of the strength of the bend angle, but we also examine dynamical effects including the scattering of mobile localized modes (discrete breathers) off of such a geometric structure. The potential outcomes of such numerical experiments (including transmission, trapping within the bend as well as reflection) are highlighted and qualitatively explained. Such models are of interest both theoretically in understanding the interplay of breathers with curvature, but also practically in simple models of photonic crystals or of bent chains of DNA.Comment: 14 pages, 16 figure

Effect of the Introduction of Impurities on the Stability Properties of Multibreathers at Low Coupling

sing a theorem dubbed the {\em Multibreather Stabiliy Theorem} [Physica D 180 (2003) 235-255] we have obtained the stability properties of multibreathers in systems of coupled oscillators with on-site potentials, with an inhomogeneity. Analytical results are obtained for 2-site, 3-site breathers, multibreathers, phonobreathers and dark breathers. The inhomogeneity is considered both at the on-site potential and at the coupling terms. All the results have been checked numerically with excellent agreement. The main conclusion is that the introduction of a impurity does not alter the stability properties.Comment: 20 pages, 9 figure

Subharmonic gap structure in short ballistic graphene junctions

We present a theoretical analysis of the current-voltage characteristics of a ballistic superconductor-normal-superconductor (SNS) junction, in which a strip of graphene is coupled to two superconducting electrodes. We focus in the short-junction regime, where the length of the strip is much smaller than superconducting coherence length. We show that the differential conductance exhibits a very rich subharmonic gap structure which can be modulated by means of a gate voltage. On approaching the Dirac point the conductance normalized by the normal-state conductance is identical to that of a short diffusive SNS junction.Comment: revtex4, 4 pages, 4 figure

Application of multiple-wireless to a visual localisation system for emergency services

Abstract—In this paper we discuss the application of multiplewireless technology to a practical context-enhanced service system called ViewNet. ViewNet develops technologies to support enhanced coordination and cooperation between operation teams in the emergency services and the police. Distributed localisation of users and mapping of environments implemented over a secure wireless network enables teams of operatives to search and map an incident area rapidly and in full coordination with each other and with a control centre. Sensing is based on fusing absolute positioning systems (UWB and GPS) with relative localisation and mapping from on-body or handheld vision and inertial sensors. This paper focuses on the case for multiple-wireless capabilities in such a system and the benefits it can provide. We describe our work of developing a software API to support both WLAN and TETRA in ViewNet. It also provides a basis for incorporating future wireless technologies into ViewNet. I

Subharmonic Gap Structure in Superconductor/Ferromagnet/Superconductor Junctions

The behavior of dc subgap current in magnetic quantum point contact is discussed for the case of low-transparency junction with different tunnel probabilities for spin-up ($D_\uparrow$) and spin-down ($D_\downarrow$) electrons. Due to the presence of Andreev bound states $\pm \epsilon_0$ in the system the positions of subgap electric current steps $eV_n = (\Delta \pm \epsilon_0)/n$ are split at temperature $T \neq 0$ with respect to the nonmagnetic result $eV_n=2\Delta/n$. It is found that under the condition $D_\uparrow \neq D_\downarrow$ the spin current also manifests subgap structure, but only for odd values of $n$. The split steps corresponding to $n=1,2$ in subgap electric and spin currents are analytically calculated and the following steps are described qualitatively.Comment: 4 pages, 1 figure, minor stylistic changes, journal-ref adde

Dynamical Coulomb blockade of multiple Andreev reflections

We analyze the dynamical Coulomb blockade of multiple Andreev reflections (MAR) in a superconducting quantum point contact coupled to a macroscopic impedance. We find that at very low transmission the blockade scales as $n^2$ with $n = {Int}(2\Delta/eV)$, where $V$ is the bias voltage and $\Delta$ is the superconducting gap, as it would correspond to the occurrence of "shots" of charge $ne$. For higher transmission the blockade is reduced both due to Pauli principle and to elastic renormalization of the MAR probability, and for certain voltage regions it may even become an "antiblockade", i.e. the current is enhanced due to the coupling with the electromagnetic environment.Comment: 5 pages, 4 figures, submitted to Phys. Rev. Let