HNBR and its MWCNT reinforced nanocomposites : Crystalline morphology and electrical response

Morphology and electrical response of hydrogenated acrylonitrile butadiene rubber (HNBR) and its multiwall carbon nanotube (MWCNT) reinforced nanocomposites were studied by means of x-ray diffraction and broadband dielectric spectroscopy. HNBR systems were found to be semi-crystalline, with their crystallinity to increase with the addition of MWCNTs. In their dielectric spectra, four relaxation processes were detected. Ascending in relaxation time, these were attributed to: (i) interfacial polarization at the interface of crystalline and amorphous regions of HNBR and at the interface between HNBR and MWCNTs, (ii) glass to rubber transition of the amorphous part of HNBR, (iii) rearrangement of polar side groups, such as –CN, and (iv) local motions of small segments of the main elastomer chain. Electrical conductivity increases with MWCNT content and frequency increasing. The effect of temperature, on the electrical response, is more pronounced at low frequencies. The temperature dependence of the electrical conductivity strongly deviates from a pure Arrhenius behavior, signifying that the occurring conductance mechanisms do not correspond to a single thermally activated process. Relaxation dynamics imply that crystalline regions exert motion restrictions to large segments of the macromolecules in the amorphous phase and to polar parts of the systems

Prototyping the BOPTEST framework for simulation-based testing of advanced control strategies in buildings

Advanced control strategies are becoming increasingly necessary in buildings in order to meet and balance requirements for energy efficiency, demand flexibility, and occupant comfort. Additional development and widespread adoption of emerging control strategies, however, ultimately require low implementation costs to reduce payback period and verified performance to gain control vendor, building owner, and operator trust. This is difficult in an already first-cost driven and risk-averse industry. Recent innovations in building simulation can significantly aid in meeting these requirements and spurring innovation at early stages of development by evaluating performance, comparing state-of-the-art to new strategies, providing installation experience, and testing controller implementations. This paper presents the development of a simulation framework consisting of test cases and software platform for the testing of advanced control strategies (BOPTEST - Building Optimization Performance Test). The objectives and requirements of the framework, components of a test case, and proposed software platform architecture are described, and the framework is demonstrated with a prototype implementation and example test case

Public Narratives and the Construction of Memory Among European Muslims

This chapter draws on group and individual interviews with 735 European Muslims in 5 European countries and explores some key aspects of the politics of memory that form an inextricable component of European Muslim self-definitions, discourses and narratives deployed in the attempt to negotiate their inclusion in European societies

Molecular dynamics pre-simulations for nanoscale computational fluid dynamics

We present a procedure for using molecular dynamics (MD) simulations to provide essential fluid and interface properties for subsequent use in computational fluid dynamics (CFD) calculations of nanoscale fluid flows. The MD pre-simulations enable us to obtain an equation of state, constitutive relations, and boundary conditions for any given fluid/solid combination, in a form that can be conveniently implemented within an otherwise conventional Navier–Stokes solver. Our results demonstrate that these enhanced CFD simulations are then capable of providing good flow field results in a range of complex geometries at the nanoscale. Comparison for validation is with full-scale MD simulations here, but the computational cost of the enhanced CFD is negligible in comparison with the MD. Importantly, accurate predictions can be obtained in geometries that are more complex than the planar MD pre-simulation geometry that provides the nanoscale fluid properties. The robustness of the enhanced CFD is tested by application to water flow along a (15,15) carbon nanotube, and it is found that useful flow information can be obtained

Impact of dietary organic acids and botanicals on intestinal integrity and inflammation in weaned pigs

BACKGROUND: Organic acids, such as citric and sorbic acid, and pure plant-derived constituents, like monoterpens and aldehydes, have a long history of use in pig feeding as alternatives to antibiotic growth promoters. However, their effects on the intestinal barrier function and inflammation have never been investigated. Therefore, aim of this study was to assess the impact of a microencapsulated mixture of citric acid and sorbic acid (OA) and pure botanicals, namely thymol and vanillin, (PB) on the intestinal integrity and functionality of weaned pigs and in vitro on Caco-2 cells. In the first study 20 piglets were divided in 2 groups and received either a basal diet or the basal diet supplemented with OA + PB (5 g/kg) for 2 weeks post-weaning at the end of which ileum and jejunum samples were collected for Ussing chambers analysis of trans-epithelial electrical resistance (TER), intermittent short-circuit current (I(SC)), and dextran flux. Scrapings of ileum mucosa were also collected for cytokine analysis (n = 6). In the second study we measured the effect of these compounds directly on TER and permeability of Caco-2 monolayers treated with either 0.2 or 1 g/l of OA + PB. RESULTS: Pigs fed with OA + PB tended to have reduced I(SC) in the ileum (P = 0.07) and the ileal gene expression of IL-12, TGF-β, and IL-6 was down regulated. In the in vitro study on Caco-2 cells, TER was increased by the supplementation of 0.2 g/l at 4, 6, and 14 days of the experiment, whereas 1 g/l increased TER at 10 and 12 days of treatment (P < 0.05). Dextran flux was not significantly affected though a decrease was observed at 7 and 14 days (P = 0.10 and P = 0.09, respectively). CONCLUSIONS: Overall, considering the results from both experiments, OA + PB improved the maturation of the intestinal mucosa by modulating the local and systemic inflammatory pressure ultimately resulting in a less permeable intestine, and eventually improving the growth of piglets prematurely weaned