68 research outputs found
Revisiting Vacuum Energy in Compact Spacetimes
We revisit the calculation of vacuum energy density in compact space times.
By explicitly computing the effective action through the heat kernel method, we
compute vacuum energy density for the general case of compact spatial
dimensions in dimensional Minkowski space time. Additionally, we use this
formalism to calculate the Casimir force on a piston placed in such space
times, and note the deviations from previously reported results in the
literature.Comment: 21 Pages, 4 Figure
On Aspects of Spontaneous Symmetry Breaking in Rindler and Anti-de Sitter spacetimes for the Linear Sigma Model
We investigate aspects of spontaneous breakdown of symmetry for
symmetric linear sigma model in the background of Rindler and Anti-de Sitter
spacetimes respectively. In the large limit, by computing the one-loop
effective action, we report that in three dimensional Rindler space, there is a
phase transition from the disordered phase to an ordered phase past a certain
critical Rindler acceleration parameter `'. Connections with finite
temperature field theory results are established, thereby further reinforcing
the idea that Rindler space can indeed be a proxy for Minkowski spacetime with
finite temperature. We extend our calculations to Anti-de Sitter space in
various dimensions and observe that symmetry is broken in three dimensions, but
not in four dimensions. We discuss the implications of our results.Comment: 7 Pages, 1 figure, Template changed, Additional citations added and
corrected some typo
On the Observer Dependence of the Quantum Effective Potential
In this short paper, we investigate the consequences of observer dependence
of the quantum effective potential for an interacting field theory.
Specializing to dimensional Euclidean Rindler space, we develop the
formalism to calculate the effective potential. While the free energy diverges
due to the presence of the Rindler horizon, the effective potential, which is a
local function of space, is finite after the necessary renormalization
procedure. We apply the results of our formalism to understand the restoration
of spontaneously broken symmetry in three and four dimensions.Comment: 7 pages, 2 Figures, Included additional citations, corrected some
typos and changed the templat
Extraction of Scandium (III) from acidic solutions using organo-phosphoric acid reagents: A comparative study
Comparative and synergistic solvent extraction of Sc(III) using two phosphoric acidic reagents such as di-(2-ethyhexyl) phosphoric acid and 2,4,4,tri-methyl,pentyl-phosphinic acid was investigated. Slope analysis method suggests a cation exchange reaction of Sc(III) with both extractants at a molar ratio of extractant: Sc(III) = 2.5:1 at equilibrium pH< 1.5. The plot of log D vs. log [Extractant] yield the slope (n) value as low as 1.2-1.3 and as high as n=7 at low and high extrcatant concentration level, respectively. Extraction isotherm study predicted the need of 2 stages at A: O=1:4 and A: O=1:3 using 0.1 M D2EHPA and 0.1 M Cyanex 272, respectively. Stripping of Sc (III) was carried out at varied NaOH concentration to ascertain the optimum stripping condition for effective enrichment of metal. The predicted stripping condition (2)-stages with A: O=1:3 and 1:4 for D2EHPA and Cyanex 272, respectively) obtained from Mc-Cabe Thiele plot was further validated by 6-cycles CCS study. An actual leach solution of Mg-Sc alloy bearing 1.0 g/L of Sc (III), 2.5 g/L of Mg and 0.2 M HCl was subjected for selective separation of Sc at the optimum condition. The counter current simulation (CCS) study for both extraction and stripping of actual solution resulted quantitative separation of Sc with ∼12 fold enrichment. The organic phase before and after loading of Sc (III) along with the diluents was characterized by FTIR to ascertain the phase transportation of Sc (III)
Nanoarchitectonics of low process parameter synthesized porous carbon on enhanced performance with synergistic interaction of redox-active electrolyte for supercapacitor application
To develop materials of lower embodied energy and materials footprint for energy storage industry, the present work reports synthesis of porous carbon from a waste wetland weed (wild sugarcane) using low process parametric conditions (temperature and impregnation ratio) and their electrochemical capacitive (synonymously known as supercapacitors) charge storage performance in aqueous and redox active electrolytes. The phase, surface chemistry, physical surface, and morphology of the porous carbon thus developed are studied in detail using X-ray diffraction, gas adsorption measurements, Fourier-transform infrared spectroscopy, X-ray photoelectron spectroscopy, scanning and transmission electron microscopy techniques. Porous carbon synthesized at 500 °C, with the activator ZnCl2, resulted in a combination of micro and meso pores and a specific surface area ∼1294 m2 g−1. The optimized electrodes show outstanding energy storage performance, viz. specific capacitance of ∼414 F g−1 (three-electrode system) and ∼197 F g−1 (two-electrode system) at 1 A g−1 current density in aqueous 1 M H2SO4 electrolyte. The porous activated carbon showed high performance in terms of electrochemical stability of 96 % in half cell configuration for 10,000 cycles, while the symmetric device showed 80 % cyclic stability for 5000 cycles in full cell configuration. Addition of redox active 0.01 M hydroquinone in the 1 M H2SO4 significantly improved the storage capacity to 540 C g−1 at current density of 3 A g−1 in two-electrode configuration and maintained 72 % of capacity for 5000 cycles. The redox-active symmetric supercapacitors show an energy density ∼26.9 W h kg−1 and power density ∼5527 W kg−1 and other related electrochemical properties
Unified model for quasar absorption line systems
We propose a three component model consisting of minihalos and galactic halos
with embedded thin discs for absorbers producing all the observed classes of
intervening quasar absorption line systems. We show that this model, based on
CDM cosmology, can explain most of the observed statistical distributions of
various types of absorption systems. Use of the Schechter luminosity function
for absorbers, on the other hand, is consistent with the observations only if
the number of galaxies was larger in the past and reduced with time due to
mergers. A strong chemical evolution in the halos of galaxies is indicated by
the observed properties of CIV lines. We discuss our results in the light of
the recent observations of the absorption line systems.Comment: 8 pages and 7 figures. Accepted for publication in Astronomy and
Astrophysic
Overlay databank unlocks data-driven analyses of biomolecules for all
Tools based on artificial intelligence (AI) are currently revolutionising many fields, yet their applications are often limited by the lack of suitable training data in programmatically accessible format. Here we propose an effective solution to make data scattered in various locations and formats accessible for data-driven and machine learning applications using the overlay databank format. To demonstrate the practical relevance of such approach, we present the NMRlipids Databank—a community-driven, open-for-all database featuring programmatic access to quality-evaluated atom-resolution molecular dynamics simulations of cellular membranes. Cellular membrane lipid composition is implicated in diseases and controls major biological functions, but membranes are difficult to study experimentally due to their intrinsic disorder and complex phase behaviour. While MD simulations have been useful in understanding membrane systems, they require significant computational resources and often suffer from inaccuracies in model parameters. Here, we demonstrate how programmable interface for flexible implementation of data-driven and machine learning applications, and rapid access to simulation data through a graphical user interface, unlock possibilities beyond current MD simulation and experimental studies to understand cellular membranes. The proposed overlay databank concept can be further applied to other biomolecules, as well as in other fields where similar barriers hinder the AI revolution
Hydrochemical diversity of semi-natural water system on the background of environmental conditions
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