Compensation in epitaxial cubic SiC films

Hall measurements on four n-type cubic SiC films epitaxially grown by chemical vapor deposition on SiC substrates are reported. The temperature dependent carrier concentrations indicate that the samples are highly compensated. Donor ionization energies, E sub D, are less than one half the values previously reported. The values for E sub D and the donor concentration N sub D, combined with results for small bulk platelets with nitrogen donors, suggest the relation E sub D (N sub D) = E sub D(O) - alpha N sub N sup 1/3 for cubic SiC. A curve fit gives alpha is approx 2.6x10/5 meV cm and E sub D (O) approx 48 meV, which is the generally accepted value of E sub D(O) for nitrogen donors in cubic SiC

A study of 60 Gigahertz intersatellite link applications

Applications of intersatellite links operating at 60 GHz are reviewed. Likely scenarios, ranging from transmission of moderate and high data rates over long distances to low data rates over short distances are examined. A limited parametric tradeoff is performed with system variables such as radiofrequency power, receiver noise temperature, link distance, data rate, and antenna size. Present status is discussed and projections are given for both electron tube and solid state transmitter technologies. Monolithic transmit and receive module technology, already under development at 20 to 30 GHz, is reviewed and its extension to 60 GHz, and possible applicability is discussed

Explainable deep learning for arm classification during deep brain stimulation - towards digital biomarkers for closed-loop stimulation

Deep brain stimulation (DBS) is an effective technique for treating motor symptoms in neurological conditions like Parkinson’s disease and dystonic and essential tremor (DT and ET). The DBS delivery could be improved if reliable biomarkers could be found. We propose a deep learning (DL) framework based on EEGNet to search for digital biomarkers in EEG recordings for discriminating neural response from changes in DBS parameters. Here we present a proof-of-concept by distinguishing left and right arm movement in raw EEG recorded during a DBS programming session of a DT patient. Based on the classification of 1s segments from six-channel EEG, we achieve an average accuracy of up to 93.8%. In addition, we propose a simple, yet effective model-agnostic filtering strategy for explaining the network’s performance, showing which frequency band features it mostly uses to classify the EEG

Coupled cluster cavity Born-Oppenheimer approximation for electronic strong coupling

Chemical and photochemical reactivity, as well as supramolecular organization and several other molecular properties, can be modified by strong interactions between light and matter. Theoretical studies of these phenomena require the separation of the Schr\"odinger equation into different degrees of freedom as in the Born-Oppenheimer approximation. In this paper, we analyze the electron-photon Hamiltonian within the cavity Born-Oppenheimer approximation (CBOA), where the electronic problem is solved for fixed nuclear positions and photonic parameters. Specifically, we focus on intermolecular interactions in representative dimer complexes. The CBOA potential energy surfaces are compared with those obtained using a polaritonic approach, where the photonic and electronic degrees of freedom are treated at the same level. This allows us to assess the role of electron-photon correlation and the accuracy of CBOA.Comment: 9 pages, 8 figure

Estimate of the Rigidity of Eclogite in the Lower Mantle From Waveform Modeling of Broadband S‐to‐P Wave Conversions

Broadband USArray recordings of the 21 July 2007 western Brazil earthquake (Mw=6.0; depth = 633 km) include high‐amplitude signals about 40 s, 75 s, and 100 s after the P wave arrival. They are consistent with S wave to P wave conversions in the mantle beneath northwestern South America. The signal at 100 s, denoted as S1750P, has the highest amplitude and is formed at 1,750 km depth based on slant‐stacking and semblance analysis. Waveform modeling using axisymmetric, finite difference synthetics indicates that S1750P is generated by a 10 km thick heterogeneity, presumably a fragment of subducted mid‐ocean ridge basalt in the lower mantle. The negative polarity of S1750P is a robust observation and constrains the shear velocity anomaly δVS of the heterogeneity to be negative. The amplitude of S1750P indicates that δVS is in the range from −1.6% to −12.4%. The large uncertainty in δVS is due to the large variability in the recorded S1750P amplitude and simplifications in the modeling of S1750P waveforms. The lower end of our estimate for δVS is consistent with ab initio calculations by Tsuchiya (2011), who estimated that δVS of eclogite at lower mantle pressure is between 0 and −2% due to shear softening from the poststishovite phase transition.Key PointsBroadband recordings of S‐P conversions allow for constraining compositional properties of deep Earth materialsStishovite is present in subducted eclogite and contributes to shear velocity softeningFragments of subducted oceanic crust are entrained in mantle flow and can be preserved at depths approaching 2,000 kmPeer Reviewedhttps://deepblue.lib.umich.edu/bitstream/2027.42/141104/1/grl56669_am.pdfhttps://deepblue.lib.umich.edu/bitstream/2027.42/141104/2/grl56642-sup-0002-supplementary.pdfhttps://deepblue.lib.umich.edu/bitstream/2027.42/141104/3/grl56642-sup-0001-supplementary.pdfhttps://deepblue.lib.umich.edu/bitstream/2027.42/141104/4/grl56669.pd

Intermolecular interactions in optical cavities: an ab initio QED study

Intermolecular bonds are weak compared to covalent bonds, but they are strong enough to influence the properties of large molecular systems. In this work, we investigate how strong light-matter coupling inside an optical cavity can modify these intermolecular forces. We perform a detailed comparison between currently available ab initio electron-photon methodologies. The electromagnetic field inside the cavity can modulate the ground state properties of weakly bound complexes. Controlling the field polarization, the interactions can be stabilized or destabilized, and electron densities, dipole moments, and polarizabilities can be altered. We demonstrate that electron-photon correlation is fundamental to describe intermolecular interactions in strong light-matter coupling. This work proposes optical cavities as a novel tool to manipulate and control ground state properties, solvent effects, and intermolecular interactions for molecules and materials.Comment: 11 pages and 9 figure

Two Carrier Analysis of Persistent Photoconductivity in Modulation-Doped Structures

A simultaneous fit of Hall and conductivity data gives quantitative results on the carrier concentration and mobility in both the quantum well and the parallel conduction channel. In this study this method was applied to reveal several new findings on the effect of persistent photoconductivity (PPC) on free-carrier concentrations and mobilities. The increase in the two-dimensional electron-gas (2DEG) concentration is significantly smaller than the apparent one derived from single carrier analysis of the Hall coefficient. In the two types of structures investigated, delta doped and continuously doped barrier, the apparent concentration almost doubles following illumination, while analysis reveals an increase of about 20% in the 2DEG. The effect of PPC on mobility depends on the structure. For the sample with a continuously doped barrier the mobility in the quantum well more than doubles. This increase is attributed to the effective screening of the ionized donors by the large electron concentration in the barrier. In the delta doped barrier sample the mobility is reduced by almost a factor of 2. This decrease is probably caused by strong coupling between the two wells, as is demonstrated by self-consistent analysis

Mixed Carrier Conduction in Modulation-doped Field Effect Transistors

The contribution of more than one carrier to the conductivity in modulation-doped field effect transistors (MODFET) affects the resultant mobility and complicates the characterization of these devices. Mixed conduction arises from the population of several subbands in the two-dimensional electron gas (2DEG), as well as the presence of a parallel path outside the 2DEG. We characterized GaAs/AlGaAs MODFET structures with both delta and continuous doping in the barrier. Based on simultaneous Hall and conductivity analysis we conclude that the parallel conduction is taking place in the AlGaAs barrier, as indicated by the carrier freezeout and activation energy. Thus, simple Hall analysis of these structures may lead to erroneous conclusions, particularly for real-life device structures. The distribution of the 2D electrons between the various confined subbands depends on the doping profile. While for a continuously doped barrier the Shubnikov-de Haas analysis shows superposition of two frequencies for concentrations below 10(exp 12) cm(exp -2), for a delta doped structure the superposition is absent even at 50% larger concentrations. This result is confirmed by self-consistent analysis, which indicates that the concentration of the second subband hardly increases

Coupled Cluster Theory for Molecular Polaritons: Changing Ground and Excited States

We present an ab initio correlated approach to study molecules that interact strongly with quantum fields in an optical cavity. Quantum electrodynamics coupled cluster theory provides a non-perturbative description of cavity-induced effects in ground and excited states. Using this theory, we show how quantum fields can be used to manipulate charge transfer and photochemical properties of molecules. We propose a strategy to lift electronic degeneracies and induce modifications in the ground state potential energy surface close to a conical intersection.Comment: 18 pages, 12 figure