25 research outputs found
Understanding Nanopore Window Distortions in the Reversible Molecular Valve Zeolite RHO
Molecular valves are becoming popular for potential biomedical applications.
However, little is known concerning their performance in energy and
environmental areas. Zeolite RHO shows unique pore deformations upon changes in
hydration, cation siting, cation type, or temperature-pressure conditions. By
varying the level of distortion of double eight-rings, it is possible to
control the adsorption properties, which confer a molecular valve behavior to
this material. We have employed interatomic potentials-based simulations to
obtain a detailed atomistic view of the structural distortion mechanisms of
zeolite RHO, in contrast with the averaged and space group restricted
information provided by diffraction studies. We have modeled four
aluminosilicate structures, containing Li, Na, K, Ca, and
Sr cations. The distortions of the three different zeolite rings are
coupled, and the six- and eight-membered rings are largely flexible. A large
dependence on the polarizing power of the extra-framework cations and with the
loading of water has been found for the minimum aperture of the eight-membered
rings that control the nanovalve effect. The calculated energy barriers for
moving the cations across the eight-membered rings are very high, which
explains the experimentally observed slow kinetics of the phase transition as
well as the appearance of metastable phases
Enhancement of the intrinsic fluorescence of ZIF-8 via post-synthetic cation exchange with Cd2+ and its incorporation into PDMS films for selective sulfide optical sensing
In this study, ZIF-8 MOF nanocrystals were synthesized and post-synthetically modified by applying different cation exchange strategies. Addition of cadmium nitrate in either methanol or DMF followed by either magnetic stirring or gentle heating led to the incorporation of a small amount of Cd (II) ions into the crystal structure in most cases, as clearly demonstrated by several characterization techniques including PXRD, SEM-EDS and FT-IR. This novel doped material exhibits a high fluorescence with the maximum emission wavelength at 444 nm upon excitation at 380 nm, which allows its use as an effective optical sensor. The sensing capability of the Cd-doped ZIF-8 material was demonstrated by its exposure to sulfide ions in aqueous solution. The fluorescence of the doped material was gradually quenched as the concentration of S2− was increased. Sensing devices based on mixed-matrix membranes (MMMs) were fabricated by using poly (dimethyl siloxane) (PDMS) as a hosting matrix for the Cd-doped ZIF-8 crystals, giving rise to fluorescent sensing films with fast and selective responses against a broad number of potential interferents
Selective sulfur dioxide adsorption on crystal defect sites on an isoreticular metal organic framework series
The widespread emissions of toxic gases from fossil fuel combustion represent major welfare risks. Here we report the improvement of the selective sulfur dioxide capture from flue gas emissions of isoreticular nickel pyrazolate metal organic frameworks through the sequential introduction of missing-linker defects and extra-framework barium cations. The results and feasibility of the defect pore engineering carried out are quantified through a combination of dynamic adsorption experiments, X-ray diffraction, electron microscopy and density functional theory calculations. The increased sulfur dioxide adsorption capacities and energies as well as the sulfur dioxide/carbon dioxide partition coefficients values of defective materials compared to original non-defective ones are related to the missing linkers enhanced pore accessibility and to the specificity of sulfur dioxide interactions with crystal defect sites. The selective sulfur dioxide adsorption on defects indicates the potential of fine-tuning the functional properties of metal organic frameworks through the deliberate creation of defects.We thank generous funding from the European Research Council through an ERC Starting Grant (ERC2011-StG-279520-RASPA), the Spanish Ministry of Economy (CTQ2013-48396-P, CTQ2014-53486-R, CTQ2015-70135-REDT) and FEDER and Marie Curie IIF-625939 (LMRA) funding from European Union and Andalucía Region (FQM-1851)
Modified natural zeolites for water disinfection using heterogeneous photo-Fenton at near neutral pH.
According to the World Health Organisation (WHO) [1], microbiologically contaminated water for for human consumption can transmit diarrheal diseases or acute respiratory infections, among others, causing 485,000 deaths from diarrhea each year. Therefore, water contaminated with pathogenic organisms (bacteria resistant to antibiotics, viruses, etc.) must be adequately treated for its safe use.Currently there are several types of treatments for water disinfection, and in recent years the interest of the scientific community in Advanced Oxidation Processes (POAs) has increased significantly [2]. Among all types of POAs, the heterogeneous photo-Fenton process has been used for the degradation of a large number of contaminants in water. Likewise, there are studies that demonstrate its efficacy for the inactivation of pathogens. Its effectiveness lies in the generation of hydroxyl radicals through the oxidation-reduction reactions that occur on the surface of a photocatalyst due to the action of UV-Vis light and the presence of an oxidising agent (hydrogen peroxide) capable of producing profound changes in the chemical structure of contaminants and irreversible damage to microorganisms.In this work, modified natural zeolites (NZ) were used as an efficient photocatalytic and low-cost support [3] for the inactivation of a model microorganism (E. coli). To do this, first, natural zeolite clinoptilolite from the Tasajeras site (Villa Clara) was was subjected to ion exchange with Fe2+, following an usual procedure [4]. Once the material was obtained, it was characterised by DRX, SEM and IR, to ensure that the synthesis had been carried out properly. Next, its efficiency was evaluated in an 850 mL jacketed glass reactor with constant agitation and illuminated with UV or visible light at a constant temperature of 25ºC and initial pH of 6.5. The tests were performed with an initial concentration of E. coli of 106 CFU/mL and adding H2O2 (10 mM) and modified zeolite2(0.85 gr) at the beginning. The reduction of bacterial concentration was then evaluated every 30 minutes through serial dilutions. Likewise, in addition to the photo-Fenton process, to understand the isolated effect of the different parameters of the process, radiation disinfection; radiation - H2O2; H2O2; modified zeolite; modified radiation-zeolite; H2O2 - modified zeolite (Fenton) and the viability of the cells and their recreation were evaluated. Finally, the ability of the used catalyst to be recovered and cyclically reused without losing its photocatalytic activity was evaluated
Chemical Engineering of Photoactivity in Heterometallic Titanium-Organic Frameworks by Metal Doping
[EN] We report a new family of titanium-organic frameworks that enlarges the limited number of crystalline, porous materials available for this metal. They are chemically robust and can be prepared as single crystals at multi-gram scale from multiple precursors. Their heterometallic structure enables engineering of their photoactivity by metal doping rather than by linker functionalization. Compared to other methodologies based on the post-synthetic metallation of MOFs, our approach is well-fitted for controlling the positioning of dopants at an atomic level to gain more precise control over the band-gap and electronic properties of the porous solid. Changes in the band-gap are also rationalized with computational modelling and experimentally confirmed by photocatalytic H-2 production.This work was supported by the EU (ERC Stg Chem-fs-MOF 714122) and Spanish MINECO (MDM-2015-0538, MAT2016-75586-C4-4-P & CTQ2017-83486-P). C.M.-G. and J.C.-G. thank the Spanish MINECO for a Ramon y Cajal Fellowship and FPI Scholarship (CTQ2014-59209-P), respectively. N.M.P. thanks the Junta de Andalucia for post-doctoral fellowship (P10-FQM-6050). BSC-RES and UG-Alhambra are acknowledged for the computational resources and F. Lloret for helpful discussions.Castells-Gil, J.; Padial, NM.; Almora-Barrios, N.; Albero-Sancho, J.; Ruiz-Salvador, AR.; Gonzalez-Platas, J.; García Gómez, H.... (2018). Chemical Engineering of Photoactivity in Heterometallic Titanium-Organic Frameworks by Metal Doping. Angewandte Chemie International Edition. 57(28):8453-8457. https://doi.org/10.1002/anie.201802089S845384575728Furukawa, H., Cordova, K. E., O’Keeffe, M., & Yaghi, O. M. (2013). The Chemistry and Applications of Metal-Organic Frameworks. Science, 341(6149), 1230444-1230444. doi:10.1126/science.1230444Adil, K., Belmabkhout, Y., Pillai, R. S., Cadiau, A., Bhatt, P. M., Assen, A. H., … Eddaoudi, M. (2017). Gas/vapour separation using ultra-microporous metal–organic frameworks: insights into the structure/separation relationship. Chemical Society Reviews, 46(11), 3402-3430. doi:10.1039/c7cs00153cHowarth, A. J., Liu, Y., Li, P., Li, Z., Wang, T. C., Hupp, J. T., & Farha, O. K. (2016). Chemical, thermal and mechanical stabilities of metal–organic frameworks. Nature Reviews Materials, 1(3). doi:10.1038/natrevmats.2015.18Colombo, V., Galli, S., Choi, H. J., Han, G. D., Maspero, A., Palmisano, G., … Long, J. R. (2011). High thermal and chemical stability in pyrazolate-bridged metal–organic frameworks with exposed metal sites. Chemical Science, 2(7), 1311. doi:10.1039/c1sc00136aPark, K. S., Ni, Z., Cote, A. P., Choi, J. Y., Huang, R., Uribe-Romo, F. J., … Yaghi, O. M. (2006). Exceptional chemical and thermal stability of zeolitic imidazolate frameworks. Proceedings of the National Academy of Sciences, 103(27), 10186-10191. doi:10.1073/pnas.0602439103Cavka, J. H., Jakobsen, S., Olsbye, U., Guillou, N., Lamberti, C., Bordiga, S., & Lillerud, K. P. (2008). A New Zirconium Inorganic Building Brick Forming Metal Organic Frameworks with Exceptional Stability. Journal of the American Chemical Society, 130(42), 13850-13851. doi:10.1021/ja8057953Devic, T., & Serre, C. (2014). High valence 3p and transition metal based MOFs. Chem. Soc. Rev., 43(16), 6097-6115. doi:10.1039/c4cs00081aBai, Y., Dou, Y., Xie, L.-H., Rutledge, W., Li, J.-R., & Zhou, H.-C. (2016). Zr-based metal–organic frameworks: design, synthesis, structure, and applications. Chemical Society Reviews, 45(8), 2327-2367. doi:10.1039/c5cs00837aAssi, H., Mouchaham, G., Steunou, N., Devic, T., & Serre, C. (2017). Titanium coordination compounds: from discrete metal complexes to metal–organic frameworks. Chemical Society Reviews, 46(11), 3431-3452. doi:10.1039/c7cs00001dDan-Hardi, M., Serre, C., Frot, T., Rozes, L., Maurin, G., Sanchez, C., & Férey, G. (2009). A New Photoactive Crystalline Highly Porous Titanium(IV) Dicarboxylate. Journal of the American Chemical Society, 131(31), 10857-10859. doi:10.1021/ja903726mGao, J., Miao, J., Li, P.-Z., Teng, W. Y., Yang, L., Zhao, Y., … Zhang, Q. (2014). A p-type Ti(iv)-based metal–organic framework with visible-light photo-response. Chem. Commun., 50(29), 3786-3788. doi:10.1039/c3cc49440cBueken, B., Vermoortele, F., Vanpoucke, D. E. P., Reinsch, H., Tsou, C.-C., Valvekens, P., … De Vos, D. (2015). A Flexible Photoactive Titanium Metal-Organic Framework Based on a [TiIV3(μ3-O)(O)2(COO)6] Cluster. Angewandte Chemie International Edition, 54(47), 13912-13917. doi:10.1002/anie.201505512Bueken, B., Vermoortele, F., Vanpoucke, D. E. P., Reinsch, H., Tsou, C.-C., Valvekens, P., … De Vos, D. (2015). A Flexible Photoactive Titanium Metal-Organic Framework Based on a [TiIV3(μ3-O)(O)2(COO)6] Cluster. Angewandte Chemie, 127(47), 14118-14123. doi:10.1002/ange.201505512Yuan, S., Liu, T.-F., Feng, D., Tian, J., Wang, K., Qin, J., … Zhou, H.-C. (2015). A single crystalline porphyrinic titanium metal–organic framework. Chemical Science, 6(7), 3926-3930. doi:10.1039/c5sc00916bYuan, S., Qin, J.-S., Xu, H.-Q., Su, J., Rossi, D., Chen, Y., … Zhou, H.-C. (2017). [Ti8Zr2O12(COO)16] Cluster: An Ideal Inorganic Building Unit for Photoactive Metal–Organic Frameworks. ACS Central Science, 4(1), 105-111. doi:10.1021/acscentsci.7b00497Dhakshinamoorthy, A., Asiri, A. M., & García, H. (2016). Metal-Organic Framework (MOF) Compounds: Photocatalysts for Redox Reactions and Solar Fuel Production. Angewandte Chemie International Edition, 55(18), 5414-5445. doi:10.1002/anie.201505581Dhakshinamoorthy, A., Asiri, A. M., & Garcia, H. (2016). Metall-organische Gerüstverbindungen: Photokatalysatoren für Redoxreaktion und die Produktion von Solarbrennstoffen. Angewandte Chemie, 128(18), 5504-5535. doi:10.1002/ange.201505581Deng, X., Li, Z., & García, H. (2017). Visible Light Induced Organic Transformations Using Metal-Organic-Frameworks (MOFs). Chemistry - A European Journal, 23(47), 11189-11209. doi:10.1002/chem.201701460Horiuchi, Y., Toyao, T., Saito, M., Mochizuki, K., Iwata, M., Higashimura, H., … Matsuoka, M. (2012). Visible-Light-Promoted Photocatalytic Hydrogen Production by Using an Amino-Functionalized Ti(IV) Metal–Organic Framework. The Journal of Physical Chemistry C, 116(39), 20848-20853. doi:10.1021/jp3046005Hendon, C. H., Tiana, D., Fontecave, M., Sanchez, C., D’arras, L., Sassoye, C., … Walsh, A. (2013). Engineering the Optical Response of the Titanium-MIL-125 Metal–Organic Framework through Ligand Functionalization. Journal of the American Chemical Society, 135(30), 10942-10945. doi:10.1021/ja405350uChambers, M. B., Wang, X., Ellezam, L., Ersen, O., Fontecave, M., Sanchez, C., … Mellot-Draznieks, C. (2017). Maximizing the Photocatalytic Activity of Metal–Organic Frameworks with Aminated-Functionalized Linkers: Substoichiometric Effects in MIL-125-NH2. Journal of the American Chemical Society, 139(24), 8222-8228. doi:10.1021/jacs.7b02186Blatov, V. A., Shevchenko, A. P., & Proserpio, D. M. (2014). Applied Topological Analysis of Crystal Structures with the Program Package ToposPro. Crystal Growth & Design, 14(7), 3576-3586. doi:10.1021/cg500498kDelgado-Friedrichs, O., & O’Keeffe, M. (2003). Identification of and symmetry computation for crystal nets. Acta Crystallographica Section A Foundations of Crystallography, 59(4), 351-360. doi:10.1107/s0108767303012017Dincă, M., Han, W. S., Liu, Y., Dailly, A., Brown, C. M., & Long, J. R. (2007). Observation of Cu2+–H2 Interactions in a Fully Desolvated Sodalite-Type Metal–Organic Framework. Angewandte Chemie International Edition, 46(9), 1419-1422. doi:10.1002/anie.200604362Dincă, M., Han, W. S., Liu, Y., Dailly, A., Brown, C. M., & Long, J. R. (2007). Observation of Cu2+–H2 Interactions in a Fully Desolvated Sodalite-Type Metal–Organic Framework. Angewandte Chemie, 119(9), 1441-1444. doi:10.1002/ange.200604362Liu, T.-F., Vermeulen, N. A., Howarth, A. J., Li, P., Sarjeant, A. A., Hupp, J. T., & Farha, O. K. (2016). Adding to the Arsenal of Zirconium-Based Metal-Organic Frameworks: the
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Thermochemistry of strontium incorporation in aragonite from atomistic simulations
We have investigated the thermodynamics of mixing between aragonite (orthorhombic CaCO3) and strontianite (SrCO3). In agreement with experiment, our simulations predict that there is a miscibility gap between the two solids at ambient conditions. All SrxCa1−xCO3 solids with compositions 0.12 < x < 0.87 are metastable with respect to separation into a Ca-rich and a Sr-rich phase. The concentration of Sr in coral aragonites (x ∼ 0.01) lies in the miscibility region of the phase diagram, and therefore formation of separated Sr-rich phases in coral aragonites is not thermodynamically favorable. The miscibility gap disappears at around 380 K. The enthalpy of mixing, which is positive and nearly symmetric with respect to x = 0.5, is the dominant contribution to the excess free energy, while the vibrational and configurational entropic contributions are small and of opposite sign. We provide a detailed comparison of our simulation results with available experimental data
Unravelling the key factors in the chlorine-promoted epoxidation of ethylene over a silver-copper oxide nanocatalyst
Ethylene oxide is one of the most important raw materials in the chemical industry, with an annual production close to 35 million metric tons. Despite its importance, to date, no metal has been found that can compete with the original silver bulk material catalyst discovered in 1931. Recently, a few copper and copper–silver based nanostructures have demonstrated remarkable selectivity and activity, especially when coupled with an industrial chlorine promoter. The present work evaluates the mechanistic role of chlorine as an active promoter of the selective oxidation of ethylene to ethylene oxide in the presence of a silver–copper oxide hybrid nanocatalyst (AgCuO). Experimental kinetic studies combined with density functional theory (DFT) calculations provide insight into the influence that Ag/CuO-supported chlorine atoms have over the ethylene epoxidation reaction. Remarkably, the typically described indirect route via the formation of an oxametallacycle (OMC) is also accompanied by a direct route. Furthermore, the presence of chlorine seems to facilitate a more favorable adsorption energy for ethylene oxide (EO) than for acetaldehyde (AA), the main reaction by-product. As a result, complete oxidation of EO can be further prevented in the presence of this AgCuO hybrid heteronanostructure.We acknowledge financial support from the European Research Council ERC-Advanced Grant HECTOR (project number 267626) is gratefully acknowledged. The computations were performed on resources provided by the supercomputer “Caesaraugusta” (node of the Spanish Supercomputer Network) provided by BIFI (Universidad de Zaragoza). The TEM studies were conducted at the Laboratorio de Microscopias Avanzadas, Instituto de Nanociencia de Aragon, Universidad de Zaragoza, Spain. S.H. acknowledges funding from the Agencia Estatal de Investigación and the Ministerio de Ciencia, Innovación y Universidades, of Spain (PID2019-110430G B-C22), and from the EU FEDER Framework 2014-2020 and Consejería de Conocimiento, Investigación y Universidad of the Andalusian Government (FEDER-UPO-1265695).Peer reviewe
Importance of Blocking Inaccessible Voids on Modeling Zeolite Adsorption: Revisited
We have carried out a geometry-based
analysis of the need of artificial blocking in a collection of zeolites,
for various gases of industrial and environmental relevance (carbon
dioxide, methane, nitrogen, oxygen, and argon), and we have studied
its influence on the heats of adsorption and saturation uptakes, which
are key properties for gas separation and storage, respectively. Our
results highlight the importance of blocking some of the pores of
the zeolites in order to avoid the spurious inclusion of guest molecules
in inaccessible regions during Monte Carlo simulations. We can thus
avoid the overestimation of adsorption and also identify nonadsorbent
zeolites for these gases by introducing pore blockings. We discuss
the limitations of the current approaches to perform automatic blocking,
and we check the reliability of the results obtained with our blocking
method, by comparing with self-diffusion coefficient values calculated
using molecular dynamics simulations