Theoretical Reflectance Spectra of Earth-Like Planets through Their Evolutions: Impact of Clouds on the Detectability of Oxygen, Water, and Methane with Future Direct Imaging Missions

In the near-future, atmospheric characterization of Earth-like planets in the habitable zone will become possible via reflectance spectroscopy with future telescopes such as the proposed LUVOIR and HabEx missions. While previous studies have considered the effect of clouds on the reflectance spectra of Earth-like planets, the molecular detectability considering a wide range of cloud properties has not been previously explored in detail. In this study, we explore the effect of cloud altitude and coverage on the reflectance spectra of Earth-like planets at different geological epochs and examine the detectability of $\mathrm{O_2}$, $\mathrm{H_2O}$, and $\mathrm{CH_4}$ with test parameters for the future mission concept, LUVOIR, using a coronagraph noise simulator previously designed for WFIRST-AFTA. Considering an Earth-like planet located at 5 pc away, we have found that for the proposed LUVOIR telescope, the detection of the $\mathrm{O_2}$ A-band feature (0.76 $\mathrm{\mu}$m) will take approximately 100, 30, and 10 hours for the majority of the cloud parameter space modeled for the atmospheres with 10\%, 50\%, and 100\% of modern Earth O$_2$ abundances, respectively. Especially, for {the case of $\gtrsim 50$\%} of modern Earth O$_2$ abundance, the feature will be detectable with integration time $\lesssim 10$ hours as long as there are lower altitude ($\lesssim 8$ km) clouds with a global coverage of $\gtrsim 20\%$. For the 1\% of modern Earth $\mathrm{O_2}$ abundance case, however, it will take more than 100 hours for all the cloud parameters we modeled.Comment: 16 pages, 10 figures, accepted for publication in A

Hues of Habitability: Characterizing Pale Blue Dots Around Other Stars

A wide range of potentially rocky transiting planets in the habitable zone (HZ) have been detected by Kepler as well as ground-based searches. The spectral type of the host star will influence our ability to detect atmospheric features with future space and ground based missions like JWST, GMT and E-ELT. For my thesis, I present a complete suit of stellar models with a stellar effective temperature ranging from Teff = 2300K to Teff = 7000K, sampling the entire FGKM stellar type range, for modeling extrasolar planets. I also have a grid of model atmospheres for an Earth-analogue planet orbiting stars and derive remotely detectable spectral atmospheric features. The UV emission from a planet's host star dominates the photochemistry and thus the resultant observable spectral features. Using the latest UV spectra obtained by Hubble as well as IUE, I model Earth-like planets for a wide range of host stars. I detail the results of activity on the primary detectable atmospheric features that indicate habitability on Earth, namely: H2O, O3, CH4, N2O and CH3Cl. I model the emergent spectra of Earth-analogue planets orbiting our grid of FGKM stars in the VIS/NIR (0.4 - 4 microns) and the IR (5 - 20 microns) range in accordance with future mission design concepts like JWST and direct detection missions like HDST/LUVOIR in the more distant horizon. We also model the amount of UV flux reaching the surface of Earth-like planets at various geological epochs ranging from a pre-biotic world through the rise of oxygen and for Earth-like planets orbiting FGKM stars at equivalent stages of evolution.Astronom

Photochemical modelling of atmospheric oxygen levels confirms two stable states

This work was supported by the European Research Council (ERC) under the European Union's Horizon 2020 Research and Innovation programme (grant no. 678812 awarded to M.W.C).Various proxies and numerical models have been used to constrain O2 levels over geological time, but considerable uncertainty remains. Previous investigations using 1-D photochemical models have predicted how O3 concentrations vary with assumed ground-level O2 concentrations, and indicate how the ozone layer might have developed over Earth history. These classic models have utilised the numerical simplification of fixed mixing ratio boundary conditions. Critically, this modelling assumption requires verification that predicted fluxes of biogenic and volcanic gases are realistic, but also that the resulting steady states are in fact stable equilibrium solutions against trivial changes in flux. Here, we use a 1-D photochemical model with fixed flux boundary conditions to simulate the effects on O3 and O2 concentrations as O2 (and CH4) fluxes are systematically varied. Our results suggest that stable equilibrium solutions exist for trace- and high-O2/O3 cases, separated by a region of instability. In particular, the model produces few stable solutions with ground O2 mixing ratios between 6×10-7 and 2×10-3 (3×10-6 and 1% of present atmospheric levels). A fully UV-shielding ozone layer only exists in the high-O2 states. Our atmospheric modelling supports prior work suggesting a rapid bimodal transition between reducing and oxidising conditions, and proposes Proterozoic oxygen levels higher than some recent proxies suggest. We show that the boundary conditions of photochemical models matter, and should be chosen and explained with care.Publisher PDFPeer reviewe

Prebiosignature Molecules Can Be Detected in Temperate Exoplanet Atmospheres with JWST

The search for biosignatures on exoplanets connects the fields of biology and biochemistry to astronomical observation, with the hope that we might detect evidence of active biological processes on worlds outside the solar system. Here we focus on a complementary aspect of exoplanet characterisation connecting astronomy to prebiotic chemistry: the search for molecules associated with the origin of life, prebiosignatures. Prebiosignature surveys in planetary atmospheres offer the potential to both constrain the ubiquity of life in the galaxy and provide important tests of current prebiotic syntheses outside of the laboratory setting. Here, we quantify the minimum abundance of identified prebiosignature molecules that would be required for detection by transmission spectroscopy using JWST. We consider prebiosignatures on five classes of terrestrial planet: an ocean planet, a volcanic planet, a post-impact planet, a super-Earth, and an early Earth analogue. Using a novel modelling and detection test pipeline, with simulated JWST noise, we find the detection thresholds of hydrogen cyanide (HCN), hydrogen sulfide (H2S), cyanoacetylene (HC3N), ammonia (NH3), methane (CH4), acetylene (C2H2), sulfur dioxide (SO2), nitric oxide (NO), formaldehyde (CH2O), and carbon monoxide (CO) in a variety of low mean molecular weight (<5) atmospheres. We test the dependence of these detection thresholds on M dwarf target star and the number of observed transits, finding that a modest number of transits (1-10) are required to detect prebiosignatures in numerous candidate planets, including TRAPPIST-1e with a high mean molecular weight atmosphere. We find that the NIRSpec G395M/H instrument is best suited for detecting most prebiosignatures.Comment: 28 pages, 12 figures, accepted for publication in A

The effect of Lyman α\alpha radiation on mini-Neptune atmospheres around M stars: application to GJ 436b

Mini-Neptunes orbiting M stars are a growing population of known exoplanets. Some of them are located very close to their host star, receiving large amounts of UV radiation. Many M stars emit strong chromospheric emission in the H I Lyman $\alpha$ line (Ly$\alpha$) at 1215.67 \AA, the brightest far-UV emission line. We show that the effect of incoming Ly$\alpha$ flux can significantly change the photochemistry of mini-Neptunes' atmospheres. We use GJ 436b as an example, considering different metallicities for its atmospheric composition. For solar composition, H$_2$O-mixing ratios show the largest change because of Ly$\alpha$ radiation. H$_2$O absorbs most of this radiation, thereby shielding CH$_4$, whose dissociation is driven mainly by radiation at other far-UV wavelengths ($\sim1300$ \AA). H$_2$O photolysis also affects other species in the atmosphere, including H, H$_2$, CO$_2$, CO, OH and O. For an atmosphere with high metallicity, H$_2$O- and CO$_2$-mixing ratios show the biggest change, thereby shielding CH$_4$. Direct measurements of the UV flux of the host stars are important for understanding the photochemistry in exoplanets' atmospheres. This is crucial, especially in the region between 1 and 10$^{-6}$ bars, which is the part of the atmosphere that generates most of the observable spectral features.Comment: 10 pages, Accepted for publication in MNRA

Characterizing Atmospheres of Transiting Earth-like Exoplanets Orbiting M Dwarfs with James Webb Space Telescope

A number of transiting, potentially habitable Earth-sized exoplanets have recently been detected around several nearby M dwarf stars. These worlds represent important targets for atmospheric characterization for the upcoming NASA James Webb Space Telescope. Given that available time for exoplanet characterization will be limited, it is critically important to first understand the capabilities and limitations of JWST when attempting to detect atmospheric constituents for potentially Earth-like worlds orbiting cool stars. Here, we explore coupled climate-chemistry atmospheric models for Earth-like planets orbiting a grid of M dwarf hosts. Using a newly-developed and validated JWST instrument model - the JWST Exoplanet Transit Simulator (JETS) - we investigate the detectability of key biosignature and habitability indicator gaseous species for a variety of relevant instruments and observing modes. Spectrally-resolved detection scenarios as well as cases where the spectral impact of a given species is integrated across the entire range of an instrument/mode are considered and serve to highlight the importance of considering information gained over an entire observable spectral range. When considering the entire spectral coverage of an instrument/mode, detections of methane, carbon dioxide, oxygen and water at signal-to-noise ratio 5 could be achieved with observations of several tens of transits (or less) for cloud-free Earth-like worlds orbiting mid- to late-type M dwarfs at system distances of up to 10-15 pc. When compared to previous results, requisite exposure times for gas species detection depend on approaches to quantifying the spectral impact of the species as well as underlying photochemical model assumptions. Thus, constraints on atmospheric abundances, even if just upper limits, by JWST have the potential to further our understanding of terrestrial atmospheric chemistry.Comment: Accepted to PASP; 14 pages (with references), 8 figure

The MUSCLES Treasury Survey. V. FUV Flares on Active and Inactive M Dwarfs

M dwarf stars are known for their vigorous flaring. This flaring could impact the climate of orbiting planets, making it important to characterize M dwarf flares at the short wavelengths that drive atmospheric chemistry and escape. We conducted a far-ultraviolet flare survey of 6 M dwarfs from the recent MUSCLES (Measurements of the Ultraviolet Spectral Characteristics of Low-mass Exoplanetary Systems) observations, as well as 4 highly-active M dwarfs with archival data. When comparing absolute flare energies, we found the active-M-star flares to be about 10$\times$ more energetic than inactive-M-star flares. However, when flare energies were normalized by the star's quiescent flux, the active and inactive samples exhibited identical flare distributions, with a power-law index of -$0.76^{+0.1}_{-0.09}$ (cumulative distribution). The rate and distribution of flares are such that they could dominate the FUV energy budget of M dwarfs, assuming the same distribution holds to flares as energetic as those cataloged by Kepler and ground-based surveys. We used the observed events to create an idealized model flare with realistic spectral and temporal energy budgets to be used in photochemical simulations of exoplanet atmospheres. Applied to our own simulation of direct photolysis by photons alone (no particles), we find the most energetic observed flares have little effect on an Earth-like atmosphere, photolyzing $\sim$0.01% of the total O$_3$ column. The observations were too limited temporally (73 h cumulative exposure) to catch rare, highly energetic flares. Those that the power-law fit predicts occur monthly would photolyze $\sim$1% of the O$_3$ column and those it predicts occur yearly would photolyze the full O$_3$ column. Whether such energetic flares occur at the rate predicted is an open question.Comment: Accepted to ApJ. v2 fixed some transposed errors, added PDF To

Mission to planet Earth : the first two billion years

Solar radiation and geological processes over the first few million years of Earth’s history, followed soon thereafter by the origin of life, steered our planet towards an evolutionary trajectory of long-lived habitability that ultimately enabled the emergence of complex life. We review the most important conditions and feedbacks over the first 2 billion years of this trajectory, which perhaps represent the best analogue for other habitable worlds in the galaxy. Crucial aspects included: (1) the redox state and volatile content of Earth’s building blocks, which determined the longevity of the magma ocean and its ability to degas H2O and other greenhouse gases, in particular CO2, allowing the condensation of a water ocean; (2) the chemical properties of the resulting degassed mantle, including oxygen fugacity, which would have not only affected its physical properties and thus its ability to recycle volatiles and nutrients via plate tectonics, but also contributed to the timescale of atmospheric oxygenation; (3) the emergence of life, in particular the origin of autotrophy, biological N2 fixation, and oxygenic photosynthesis, which accelerated sluggish abiotic processes of transferring some volatiles back into the lithosphere; (4) strong stellar UV radiation on the early Earth, which may have eroded significant amounts of atmospheric volatiles, depending on atmospheric CO2/N2 ratios and thus impacted the redox state of the mantle as well as the timing of life’s origin; and (5) evidence of strong photochemical effects on Earth’s sulfur cycle, preserved in the form of mass-independent sulfur isotope fractionation, and potentially linked to fractionation in organic carbon isotopes. The early Earth presents itself as an exoplanet analogue that can be explored through the existing rock record, allowing us to identify atmospheric signatures diagnostic of biological metabolisms that may be detectable on other inhabited planets with next-generation telescopes. We conclude that investigating the development of habitable conditions on terrestrial planets, an inherently complex problem, requires multi-disciplinary collaboration and creative solutions.Publisher PDFPeer reviewe

Large Interferometer For Exoplanets (LIFE): V. Diagnostic potential of a mid-infrared space-interferometer for studying Earth analogs

An important future goal in exoplanetology is to detect and characterize potentially habitable planets. Using nulling interferometry, LIFE will allow us to constrain the radius and effective temperature of (terrestrial) exoplanets, as well as provide unique information about their atmospheric structure and composition. We explore the potential of LIFE in characterizing emission spectra of Earth at various stages of its evolution. We perform Bayesian retrievals on simulated spectra of 8 different scenarios, which correspond to cloud-free and cloudy spectra of four different epochs of the evolution of the Earth. Assuming a distance of 10 pc and a Sun-like host star, we simulate observations obtained with LIFE using its simulator LIFEsim, considering all major astrophysical noise sources. With the nominal spectral resolution (R=50) and signal-to-noise ratio (assumed to be S/N=10 at 11.2 $\mu$m), we can identify the main spectral features of all the analyzed scenarios (most notably CO$_2$, H$_2$O, O$_3$, CH$_4$). This allows us to distinguish between inhabited and lifeless scenarios. Results suggest that particularly O$_3$ and CH$_4$ yield an improved abundance estimate by doubling the S/N from 10 to 20. We conclude that the baseline requirements for R and S/N are sufficient for LIFE to detect O$_3$ and CH$_4$ in the atmosphere of an Earth-like planet with an abundance of O$_2$ of around 2% in volume mixing ratio. This information is relevant in terms of the LIFE mission planning. We also conclude that cloud-free retrievals of cloudy planets can be used to characterize the atmospheric composition of terrestrial habitable planets, but not the thermal structure of the atmosphere. From the inter-model comparison performed, we deduce that differences in the opacity tables (caused by e.g. a different line wing treatment) may be an important source of systematic errors.Comment: 18 pages (main text, incl. 11 figures) + appendix; submitted to A&A; comments are very welcome! Fifth paper of LIFE telescope series. First: arXiv:2101.07500v4, Second: arXiv:2203.00471, Third: arXiv:2112.02054, Sixth: arXiv:2201.0489

A comparison of simulated JWST observations derived from equilibrium and non-equilibrium chemistry models of giant exoplanets

SDB thanks NASA GSFC and UMBC for support of this work, and the University of Exeter for support through a Ph.D. studentship.We aim to see if the difference between equilibrium and disequilibrium chemistry is observable in the atmospheres of transiting planets by the James Webb Space Telescope (JWST). We perform a case study comparing the dayside emission spectra of three planets like HD 189733b, WASP-80b, and GJ436b, in and out of chemical equilibrium at two metallicities each. These three planets were chosen because they span a large range of planetary masses and equilibrium temperatures, from hot and Jupiter-sized to warm and Neptune-sized. We link the one-dimensional disequilibrium chemistry model from Venot et al. (2012) in which thermochemical kinetics, vertical transport, and photochemistry are taken into account, to the one-dimensional, pseudo line-by-line radiative transfer model, Pyrat Bay, developed especially for hot Jupiters, and then simulate JWST spectra using PandExo for comparing the effects of temperature, metallicity, and radius. We find the most significant differences from 4 to 5 μm due to disequilibrium from CO and CO2 abundances, and also H2O for select cases. Our case study shows a certain "sweet spot" of planetary mass, temperature, and metallicity where the difference between equilibrium and disequilibrium is observable. For a planet similar to WASP-80b, JWST's NIRSpec G395M can detect differences due to disequilibrium chemistry with one eclipse event. For a planet similar to GJ 436b, the observability of differences due to disequilibrium chemistry is possible at low metallicity given five eclipse events, but not possible at the higher metallicity.PostprintPeer reviewe