187 research outputs found
Current rectification in a single molecule diode: the role of electrode coupling
We demonstrate large rectification ratios (> 100) in single-molecule
junctions based on a metal-oxide cluster (polyoxometalate), using a scanning
tunneling microscope (STM) both at ambient conditions and at low temperature.
These rectification ratios are the largest ever observed in a single-molecule
junction, and in addition these junctions sustain current densities larger than
10^5 A/cm^2. By following the variation of the I-V characteristics with
tip-molecule separation we demonstrate unambiguously that rectification is due
to asymmetric coupling to the electrodes of a molecule with an asymmetric level
structure. This mechanism can be implemented in other type of molecular
junctions using both organic and inorganic molecules and provides a simple
strategy for the rational design of molecular diodes
Dynamics of quartz tuning fork force sensors used in scanning probe microscopy
We have performed an experimental characterization of the dynamics of
oscillating quartz tuning forks which are being increasingly used in scanning
probe microscopy as force sensors. We show that tuning forks can be described
as a system of coupled oscillators. Nevertheless, this description requires the
knowledge of the elastic coupling constant between the prongs of the tuning
fork, which has not yet been measured. Therefore tuning forks have been usually
described within the single oscillator or the weakly coupled oscillators
approximation that neglects the coupling between the prongs. We propose three
different procedures to measure the elastic coupling constant: an
opto-mechanical method, a variation of the Cleveland method and a thermal noise
based method. We find that the coupling between the quartz tuning fork prongs
has a strong influence on the dynamics and the measured motion is in remarkable
agreement with a simple model of coupled harmonic oscillators. The precise
determination of the elastic coupling between the prongs of a tuning fork
allows to obtain a quantitative relation between the resonance frequency shift
and the force gradient acting at the free end of a tuning fork prong.Comment: 16 pages, 6 figures, 2 Table
Force-gradient-induced mechanical dissipation of quartz tuning fork force sensors used in atomic force microscopy
We have studied the dynamics of quartz tuning fork resonators used in atomic
force microscopy taking into account mechanical energy dissipation through the
attachment of the tuning fork base. We find that the tuning fork resonator
quality factor changes even for the case of a purely elastic sensor-sample
interaction. This is due to the effective mechanical imbalance of the tuning
fork prongs induced by the sensor-sample force gradient which in turn has an
impact on the dissipation through the attachment of the resonator base. This
effect may yield a measured dissipation signal that can be different to the one
exclusively related to the dissipation between the sensor and the sample. We
also find that there is a second order term in addition to the linear
relationship between the sensor-sample force gradient and the resonance
frequency shift of the tuning fork that is significant even for force gradients
usually present in atomic force microscopy which are in the range of tens of
N/m.Comment: 9 pages, 3 figures and supplemental informatio
Observation of a parity oscillation in the conductance of atomic wires
Using a scanning tunnel microscope or mechanically controlled break
junctions, atomic contacts of Au, Pt and Ir are pulled to form chains of atoms.
We have recorded traces of conductance during the pulling process and averaged
these for a large amount of contacts. An oscillatory evolution of conductance
is observed during the formation of the monoatomic chain suggesting a
dependence on even or odd numbers of atoms forming the chain. This behaviour is
not only present in the monovalent metal Au, as it has been previously
predicted, but is also found in the other metals which form chains suggesting
it to be a universal feature of atomic wires
Quantum interference structures in the conductance plateaus of gold nanojunctions
The conductance of breaking metallic nanojunctions shows plateaus alternated
with sudden jumps, corresponding to the stretching of stable atomic
configurations and atomic rearrangements, respectively. We investigate the
structure of the conductance plateaus both by measuring the voltage dependence
of the plateaus' slope on individual junctions and by a detailed statistical
analysis on a large amount of contacts. Though the atomic discreteness of the
junction plays a fundamental role in the evolution of the conductance, we find
that the fine structure of the conductance plateaus is determined by quantum
interference phenomenon to a great extent.Comment: 4 pages, 4 figure
Onset of dissipation in ballistic atomic wires
Electronic transport at finite voltages in free-standing gold atomic chains
of up to 7 atoms in length is studied at low temperatures using a scanning
tunneling microscope (STM). The conductance vs voltage curves show that
transport in these single-mode ballistic atomic wires is non-dissipative up to
a finite voltage threshold of the order of several mV. The onset of dissipation
and resistance within the wire corresponds to the excitation of the atomic
vibrations by the electrons traversing the wire and is very sensitive to
strain.Comment: Revtex4, 4 pages, 3 fig
Calibration of the length of a chain of single gold atoms
Using a scanning tunneling microscope or mechanically controllable break
junctions it has been shown that it is possible to control the formation of a
wire made of single gold atoms. In these experiments an interatomic distance
between atoms in the chain of ~3.6 Angstrom was reported which is not
consistent with recent theoretical calculations. Here, using precise
calibration procedures for both techniques, we measure length of the atomic
chains. Based on the distance between the peaks observed in the chain length
histogram we find the mean value of the inter-atomic distance before chain
rupture to be 2.6 +/- 0.2 A . This value agrees with the theoretical
calculations for the bond length. The discrepancy with the previous
experimental measurements was due to the presence of He gas, that was used to
promote the thermal contact, and which affects the value of the work function
that is commonly used to calibrate distances in scanning tunnelling microscopy
and mechanically controllable break junctions at low temperatures.Comment: 6 pages, 6 figure
Carbon fibre tips for scanning probe microscopy based on quartz tuning fork force sensors
We report the fabrication and the characterization of carbon fibre tips for
their use in combined scanning tunnelling and force microscopy based on
piezoelectric quartz tuning fork force sensors. We find that the use of carbon
fibre tips results in a minimum impact on the dynamics of quartz tuning fork
force sensors yielding a high quality factor and consequently a high force
gradient sensitivity. This high force sensitivity in combination with high
electrical conductivity and oxidation resistance of carbon fibre tips make them
very convenient for combined and simultaneous scanning tunnelling microscopy
and atomic force microscopy measurements. Interestingly, these tips are quite
robust against occasionally occurring tip crashes. An electrochemical
fabrication procedure to etch the tips is presented that produces a sub-100 nm
apex radius in a reproducible way which can yield high resolution images.Comment: 14 pages, 10 figure
Symmetry and Temperature dependence of the Order parameter in MgB2 from point contact measurements
We have performed differential conductance versus voltage measurements of
Au/MgB2 point contacts. We find that the dominant component in the conductance
is due to Andreev reflection. The results are fitted to the theoretical model
of BTK for an s-wave symmetry from which we extract the value of the order
parameter (Delta) and its temperature dependence. From our results we also
obtain a lower experimental bound on the Fermi velocity in MgB2.Comment: 7 pages (Including figure captions) and 4 figure
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