10,596 research outputs found
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The effect of water absorption on the dielectric properties of epoxy nanocomposites
In this research, the influence of water absorption on the dielectric properties of epoxy resin and epoxy micro-composites and nano-composites filled with silica has been studied. Nanocomposites were found to absorb significantly more water than unfilled epoxy. However, the microcomposite absorbed less water than unfilled epoxy: corresponding to reduced proportion of the epoxy in this composite. The glass transition temperatures of all the samples were measured by both differential scanning calorimetry and dielectric spectroscopy. The Tg decreased as the water absorption increased and, in all cases, corresponded to a drop of approximately 20K as the humidity was increased from 0% to 100%. This implied that for all the samples, the amount of water in the resin component of the composites was almost identical. It was concluded that the extra water found in the nanocomposites was located around the surface of the nanoparticles. This was confirmed by measuring the water uptake, and the swelling and density change, as a function of humidity as water was absorbed. The water shell model, originally proposed by Lewis and developed by Tanaka, has been further developed to explain low frequency dielectric spectroscopy results in which percolation of charge carriers through overlapping water shells was shown to occur. This has been discussed in terms of a percolation model. At 100% relative humidity, water is believed to surround the nanoparticles to a depth of approximately 5 monolayers. A second layer of water is proposed that is dispersed by sufficiently concentrated to be conductive; this may extend for approximately 25 nm. If all the water had existed in a single layer surrounding a nanoparticle, this layer would have been approximately 3 to 4 nm thick at 100%. This "characteristic thickness" of water surrounding a given size of nanoparticle appeared to be independent of the concentration of nanoparticles but approximately proportional to water uptake. Filler particles that have surfaces that are functionalized to be hydrophobic considerably reduce the amount of water absorbed in nanocomposites under the same conditions of humidity. Comments are made on the possible effect on electrical aging
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A "water shell" model for the dielectric properties of hydrated silica-filled epoxy nano-composites
The electrical properties of epoxy resin have been studied as a function of hydration. The epoxy was studied in an un-filled state, filled with 40 µm SiO2 particles, and filled with 50 nm SiO2 particles. The relative humidity was controlled by saturated salt solutions at ambient temperatures from 298-353 K. Measurements were made using dielectric spectroscopy over the frequency range 10-3-105 Hz. The hydration isotherm (i.e. the mass uptake of water) was established by measuring the mass as a function of relative humidity (RH). It was found that the nanocomposites absorb up to 60% more water than the unfilled and micro-filled epoxies. Dielectric spectroscopy shows different conduction and quasi-DC behaviours at very low frequencies (<10-2 Hz) with activation energies dependent on the hydration and temperature. These observations have led to the development of a “water shell” model to explain this phenomenon
Spin excitations in layered antiferromagnetic metals and superconductors
The proximity of antiferromagnetic order in high-temperature superconducting
materials is considered a possible clue to the electronic excitations which
form superconducting pairs. Here we study the transverse and longitudinal spin
excitation spectrum in a one-band model in the pure spin density wave (SDW)
state and in the coexistence state of SDW and the superconductivity. We start
from a Stoner insulator and study the evolution of the spectrum with doping,
including distinct situations with only hole pockets, with only electron
pockets and with pockets of both types. In addition to the usual spin-wave
modes, in the partially gapped cases we find significant weight of low-energy
particle-hole excitations. We discuss the implications of our findings for
neutron scattering experiments and for theories of Cooper-pairing in the
metallic SDW state.Comment: (14 pages, 6 figures
Magnetism in meteorites
An overview is presented of magnetism in meteorites. A glossary of magnetism terminology followed by discussion of the various techniques used for magnetism studies in meteorites are included. The generalized results from use of these techniques by workers in the field are described. A brief critical analysis is offered
Thermoelastic analysis of solar cell arrays and their material properties
Announced report discusses experimental test program in which five different solar cell array designs were evaluated by subjecting them to 60 thermal cycles from minus 190 deg to 0.0 deg. Results indicate that solder-coated cells combined with Kovar n-interconnectors and p-interconnectors are more durable under thermal loading than other configurations
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Influence of absorbed water on the dielectric properties and glass-transition temperature of silica-filled epoxy nanocomposites
Work on dielectric spectroscopy of epoxy resin filled with nano-SiO2 at different relative humidities and temperatures is reported. Above the glass-transition temperature (Tg), dc-like imperfect charge transport (QDC or LFD) dominates the low frequency dielectric spectrum. Another mid-frequency relaxation process was found in the non-dried composites. Water also induces glass-transition temperature decreases, which can be measured both by dielectric spectroscopy and DSC. Both theory and experiment demonstrated that a higher water content could exist in nanocomposites than unfilled epoxy suggesting a bigger free volume when nanostructured. In our system, the hydrophilic surface of silica is likely to cause water to surround and lead to delamination of the epoxy from SiO2. This is a potential mechanical and dielectric weakness in the nanocomposites, which may lead to an ageing phenomenon. Hydrophobic surface group may reduce the water adsorption in nanocomposites
Industrial Relations in a Plural Society
In the course of this address I shall be using terms which, though familiar to many of you may noti n fact be known to all of you or umderstood by you in the way I understand them. It is therefore appropriate to begin the evening with some definitions wh1ch I hope will help clarify what I have to sa
Frequency multiplication in high-energy electron beams Semiannual progress report, 1 Apr. - 1 Oct. 1967
High energy electron beam studies dealing with nonlinear analysis of beam-plasma interactions, cyclotron harmonic instabilities, and frequency multiplicatio
Reduction of computer usage costs in predicting unsteady aerodynamic loadings caused by control surface motions: Analysis and results
Results of theoretical and numerical investigations conducted to develop economical computing procedures were applied to an existing computer program that predicts unsteady aerodynamic loadings caused by leading and trailing edge control surface motions in subsonic compressible flow. Large reductions in computing costs were achieved by removing the spanwise singularity of the downwash integrand and evaluating its effect separately in closed form. Additional reductions were obtained by modifying the incremental pressure term that account for downwash singularities at control surface edges. Accuracy of theoretical predictions of unsteady loading at high reduced frequencies was increased by applying new pressure expressions that exactly satisified the high frequency boundary conditions of an oscillating control surface. Comparative computer result indicated that the revised procedures provide more accurate predictions of unsteady loadings as well as providing reduction of 50 to 80 percent in computer usage costs
An exactly solvable model of a superconducting to rotational phase transition
We consider a many-fermion model which exhibits a transition from a
superconducting to a rotational phase with variation of a parameter in its
Hamiltonian. The model has analytical solutions in its two limits due to the
presence of dynamical symmetries. However, the symmetries are basically
incompatible with one another; no simple solution exists in intermediate
situations. Exact (numerical) solutions are possible and enable one to study
the behavior of competing but incompatible symmetries and the phase transitions
that result in a semirealistic situation. The results are remarkably simple and
shed light on the nature of phase transitions.Comment: 11 pages including 1 figur
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