Electrochemical properties and electrochemical impedance spectroscopy of polypyrrole-coated platinum electrodes

Polypyrrole (PPy) films of different thickness were characterized by electrochemical impedance spectroscopy (EIS) measurements in acetonitrile and aqueous solutions, containing 0.1 M NaClO4 or sodium dodecylsulfate as the dopant. The PPy films were electrochemically deposited on Pt, and their electrochemical properties studied by cyclic voltammetry. Impedance spectra were obtained at potentials ranging from 0 to 0.8 V/SCE. The EIS data were fitted using two different equivalent electrical circuits (depending on the nature of the dopant). They involve a diffusive capacitance, which increased with the passing charge during electrosynthesis (i.e. film thickness) for ClO4--doped PPy, but was practically unaffected by the film thickness in the case of SDS-doped PPy. Also, a double-layer capacitance was found only in the circuit of ClO4--doped PPy. It increased with the film thickness, and showed a minimum near the open-circuit potential. Finally the charge-transfer resistance (Rct) obtained with SDS is nearly 200-fold higher than that obtained with ClO4- in the same solvent (H2O). With the same dopant (ClO4-), Rct is about five times higher in acetonitrile relative to water. All these EIS results of the different types of PPy suggest a relation with the wettability of the polymer.KEY WORDS: Conducting polymers, Polypyrrole, Electrochemical impedance spectroscopy, Equivalent-electrical circuit, Micellar mediaBull. Chem. Soc. Ethiop. 2006, 20(2), 279-293

Endobronchial ultrasound application for diagnosis of tracheobronchial tree invasion by esophageal cancer

INTRODUCTION: Esophageal cancer staging has been performed through bronchoscopy, computerized tomography (CT), positron emission tomography (PET), and endoscopic ultrasound (EUS). Whereas CT and PET scan provide assessments of distant metastasis, bronchoscopy importantly diagnoses tracheobronchial involvement, complementing chest CT findings. EUS is the most accurate examination for T and N staging but is technically limited when tumoral stenoses cannot be traversed. Endobronchial ultrasound (EBUS) appears to present greater accuracy than EUS, CT, and bronchoscopy for assessing tracheobronchial wall involvement. EBUS has been recently associated with EUS for esophageal cancer staging in our unit. OBJECTIVE: To compare EBUS findings in esophageal cancer patients without evident signs of tracheobronchial invasion on conventional bronchoscopy with EUS and CT. METHODS: Fourteen patients with esophageal cancer underwent CT, conventional bronchoscopy, EUS, and EBUS for preoperative staging. All patients underwent EBUS and EUS with an Olympus® MH-908 echoendoscope at 7.5 MHz. Seven patients were eligible for the study according to the inclusion criteria. RESULTS: The echoendoscope could not traverse tumoral esophageal stenosis to perform EUS in two patients, and invasion was effectively diagnosed by EBUS. In 4 (57%) of 7 patients EBUS revealed additional information to staging. In the remaining 3 cases the invasion findings were the same under both EUS and EBUS. CONCLUSION: EBUS showed signs of tracheobronchial invasion not observed by conventional bronchoscopy, adding information to staging in most of the cases when compared with CT and EUS

Spectrum of confining strings in SU(N) gauge theories

We study the spectrum of the confining strings in four-dimensional SU(N) gauge theories. We compute, for the SU(4) and SU(6) gauge theories formulated on a lattice, the string tensions sigma_k related to sources with Z_N charge k, using Monte Carlo simulations. Our results are consistent with the sine formula sigma_k/sigma = sin k pi/N / sin pi/N for the ratio between sigma_k and the standard string tension sigma. For the SU(4) and SU(6) cases the accuracy is approximately 1% and 2%, respectively. The sine formula is known to emerge in various realizations of supersymmetric SU(N) gauge theories. On the other hand, our results show deviations from Casimir scaling. We also discuss an analogous behavior exhibited by two-dimensional SU(N) x SU(N) chiral models.Comment: Latex, 34 pages, 10 figures. Results of new SU(4) simulations added. The new data are included in the analysis, leading to improved final estimates for SU(4). Conclusions unchange

Three-dimensional stability of Burgers vortices

Burgers vortices are explicit stationary solutions of the Navier-Stokes equations which are often used to describe the vortex tubes observed in numerical simulations of three-dimensional turbulence. In this model, the velocity field is a two-dimensional perturbation of a linear straining flow with axial symmetry. The only free parameter is the Reynolds number $Re = \Gamma/\nu$, where $\Gamma$ is the total circulation of the vortex and $\nu$ is the kinematic viscosity. The purpose of this paper is to show that Burgers vortex is asymptotically stable with respect to general three-dimensional perturbations, for all values of the Reynolds number. This definitive result subsumes earlier studies by various authors, which were either restricted to small Reynolds numbers or to two-dimensional perturbations. Our proof relies on the crucial observation that the linearized operator at Burgers vortex has a simple and very specific dependence upon the axial variable. This allows to reduce the full linearized equations to a vectorial two-dimensional problem, which can be treated using an extension of the techniques developped in earlier works. Although Burgers vortices are found to be stable for all Reynolds numbers, the proof indicates that perturbations may undergo an important transient amplification if $Re$ is large, a phenomenon that was indeed observed in numerical simulations.Comment: 31 pages, no figur

SU(2) Calorons and Magnetic Monopoles

We investigate the self-dual Yang-Mills gauge configurations on $R^3\times S^1$ when the gauge symmetry SU(2) is broken to U(1) by the Wilson loop. We construct the explicit field configuration for a single instanton by the Nahm method and show that an instanton is composed of two self-dual monopoles of opposite magnetic charge. We normalize the moduli space metric of an instanton and study various limits of the field configuration and its moduli space metric.Comment: 17 pages, RevTex, 1 Figur

nanostructured bitumen with nanocarbon

Physical and chemical indicators of bitumen quality of grade BND 70/100 with the added carbon nanopowder 2% by weight have been studied by laboratory test methods and analysis. High reaction ability of nanopowder particles and concentration of excess surface and internal energy in them have been determined, which provide the increase of low-temperature resistance, aggregate strength, and improvement of rheological properties of nanostructured bitumen. Essential structure variation has been proved: the increase of asphaltenes and oils content for 9% and 7.2% respectively due to the decrease of resins for 16.2% by weight. Methods have been discussed for preparing a liquid nanocarbon mix, adding of the mix into bitumen and homogenization of the bitumen. Some economic indicators have been represented which influence essentially the reduction for the cost value of the nanostructure bitumen

Comparison of Strangeness Production between A+A and p+p Reactions from 2 to 160 AGeV

The measured K$^+/\pi^+$ ratios from heavy-ion reactions are compared with the K$^+/\pi^+$ ratios from p+p reactions over the energy range 2-160 AGeV. The K/$\pi$ enhancement in heavy-ion reactions is largest at the lower energies, consistent with strangeness production in secondary scattering becoming relatively more important than initial collisions near the kaon production threshold. The enhancement decreases steadily from 4 to 160 AGeV, suggesting that the same enhancement mechanism of hadronic rescattering and decay of strings may be applicable over this full energy range. Based on existing data, the mid-rapidity K$^+/\pi^+$ ratio is predicted to be $0.27\pm0.05$ for the forthcoming Pb+Pb reactions at 40 AGeV/c.Comment: 14 pages, 4 figures, submitted to Phys. Rev.

Rotating Strings with Two Unequal Spins in Lunin-Maldacena Background

We study a string motion in the Lunin-Maldacena background, that is, the \beta-deformed AdS_5 \times \tilde{S}^5 background dual to a \beta-deformation of \mathcal{N} = 4 super Yang-Mills theory. For real \beta we construct a rotating and wound string solution which has two unequal spins in \tilde{S}^5. The string energy is expressed in terms of the spins, the winding numbers and the deformation parameter. In the expansion of \lambda/J^2 with the total spin J and the string tension \sqrt{\lambda} we present ``one-loop" and ``two-loop" energy corrections. The ``one-loop" one agrees with the one-loop anomalous dimension of the corresponding gauge-theory scalar operators obtained in hep-th/0503192 from the \beta-deformed Bethe equation as well as the anisotropic Landau-Lifshitz equation.Comment: 13 pages, LaTeX, no figure

Stability of Spatial Optical Solitons

We present a brief overview of the basic concepts of the soliton stability theory and discuss some characteristic examples of the instability-induced soliton dynamics, in application to spatial optical solitons described by the NLS-type nonlinear models and their generalizations. In particular, we demonstrate that the soliton internal modes are responsible for the appearance of the soliton instability, and outline an analytical approach based on a multi-scale asymptotic technique that allows to analyze the soliton dynamics near the marginal stability point. We also discuss some results of the rigorous linear stability analysis of fundamental solitary waves and nonlinear impurity modes. Finally, we demonstrate that multi-hump vector solitary waves may become stable in some nonlinear models, and discuss the examples of stable (1+1)-dimensional composite solitons and (2+1)-dimensional dipole-mode solitons in a model of two incoherently interacting optical beams.Comment: 34 pages, 9 figures; to be published in: "Spatial Optical Solitons", Eds. W. Torruellas and S. Trillo (Springer, New York