Bio- and chronostratigraphy of the Middle Triassic Reifling Formation of the westernmost Northern Calcareous Alps

New finds of fossils including bivalves, ammonoids, brachiopods and palynomorphs from the Middle Triassic Reifling Formation significantly improve the age assignment for this unit in Liechtenstein and Vorarlberg. The lower part of the Reifling Formation is tentatively referred to the Late Anisian Paraceratites trinodosus Zone and somewhat older levels, whereas the uppermost part reaches the Ladinian Protrachyceras archelaus Zone (ammonoid zonation). The Middle Triassic successions of the study area are correlated with the coeval South Alpine reference section at Bagolino (Brescian Prealps), which also bears the Ladinian GSSP. The comparison shows that the Reifling Formation in the study area is age-equivalent with the South Alpine Prezzo Limestone and the Buchenstein Formation. A volcanoclastic layer in the upper part of the Reifling Formation at Flexenpass yields a U-Pb zircon age of 239.3 +/- 0.2 Ma. This value is slightly older than previously published minimum ages from equivalent horizons in the Southern Alps; the difference is thought to be mainly due to improved pre-treatment of zircons (annealing/chemical abrasion), which significantly reduces the effects of Pb loss. The new radio-isotope age further constrains the stratigraphical age of the Reifling Formation and supports the proposed biostratigraphy-based correlation of Middle Triassic successions in the Eastern and Southern Alp

Geometry and chronology of growth and drowning of Middle Triassic carbonate platforms (Cernera and Bivera/Clapsavon) in the Southern Alps (northern Italy)

Abstract.: The depositional architecture and the geometric relationships between platform-slope deposits and basinal sediments along with paleontological evidence indicate the time interval of the younger Anisian Reitziites reitzi ammonoid zone to largely represent the main stage of platform aggradation at the Cernera and Bivera/Clapsavon carbonate platforms. Published and new U-Pb age data of zircons from volcaniclastic layers bracketing the stratigraphic interval of platform growth constrain the duration of platform evolution to a time span shorter than 1.8±0.7m.y., probably in the order of 0.5-1m.y., reflecting fast rates of vertical platform aggradation exceeding 500 m/m.y. In the range of growth potentials for shallow-water carbonate systems estimated in relation to the time span of observation, this high rate is in agreement with values for short intervals of 105-106yrs (e.g., Schlager 1999). After drowning, the platforms at Cernera and Bivera/Clapsavon were blanketed by thin pelagic carbonates. On the former platform flanks the draping sediments in places comprise red nodular pelagic limestones (Clapsavon Limestone) similar in facies to the Han Bulog Limestones occurring elsewhere in Middle Triassic successions of the Mediterranean Tethys. The drowning of vast areas of former carbonate platforms possibly triggered the onset of bottom-water circulation in adjacent basins as suggested by the abrupt transition from laminated to bioturbated pelagic nodular limestones in the Buchenstein Formation which occurred close to the time of initial platform submergence. During the Late Ladinian the topographic features of the drowned platforms were onlapped by rapidly deposited, predominantly clastic successions including coarse breccias and volcanic rocks sealing and preserving the peculiar stratigraphic settin

Numerical approximation of statistical solutions of scalar conservation laws

We propose efficient numerical algorithms for approximating statistical solutions of scalar conservation laws. The proposed algorithms combine finite volume spatio-temporal approximations with Monte Carlo and multi-level Monte Carlo discretizations of the probability space. Both sets of methods are proved to converge to the entropy statistical solution. We also prove that there is a considerable gain in efficiency resulting from the multi-level Monte Carlo method over the standard Monte Carlo method. Numerical experiments illustrating the ability of both methods to accurately compute multi-point statistical quantities of interest are also presented

Empirical evidence for stability of the 405-kiloyear Jupiter-Venus eccentricity cycle over hundreds of millions of years

The Newark–Hartford astrochronostratigraphic polarity timescale (APTS) was developed using a theoretically constant 405-kiloyear eccentricity cycle linked to gravitational interactions with Jupiter–Venus as a tuning target and provides a major timing calibration for about 30 million years of Late Triassic and earliest Jurassic time. While the 405-ky cycle is both unimodal and the most metronomic of the major orbital cycles thought to pace Earth’s climate in numerical solutions, there has been little empirical confirmation of that behavior, especially back before the limits of orbital solutions at about 50 million years before present. Moreover, the APTS is anchored only at its younger end by U–Pb zircon dates at 201.6 million years before present and could even be missing a number of 405-ky cycles. To test the validity of the dangling APTS and orbital periodicities, we recovered a diagnostic magnetic polarity sequence in the volcaniclastic-bearing Chinle Formation in a scientific drill core from Petrified Forest National Park (Arizona) that provides an unambiguous correlation to the APTS. New high precision U–Pb detrital zircon dates from the core are indistinguishable from ages predicted by the APTS back to 215 million years before present. The agreement shows that the APTS is continuous and supports a stable 405-kiloyear cycle well beyond theoretical solutions. The validated Newark–Hartford APTS can be used as a robust framework to help differentiate provinciality from global temporal patterns in the ecological rise of early dinosaurs in the Late Triassic, amongst other problems

Origin of two types of rhyolites in the Tarim Large Igneous Province: Consequences of incubation and melting of a mantle plume

The Early Permian Tarim Large Igneous Province (LIP) in northwestern China contains a large area of silicic volcanics (similar to 48,000 km(2)) which are spatially and temporally associated with mafic-ultramafic rocks. In order to understand the behavior of crust above a mantle plume, selected rhyolitic samples are investigated in terms of U-Pb zircon dating, geochemical and isotopic analyses. The Tarim rhyolites have high A/CNK ratios (= molar Al2O3/CaO + Na2O + K2O), Fe#, Ga/Al ratios, concentrations of high field strength elements (HFSEs) such as Zr and Nb, and rare earth elements (REEs), along with high zircon saturation temperatures (872-940 degrees C), typical of aluminous A-type granitoids. Two contrasting rock types have been recognized. The low Nb-Ta type rhyolites are mainly associated with the first phase of the Tarim flood basalt magmatism at similar to 290 Ma. They are characterized by negative Nb-Ta anomalies, low epsilon(Nd)(t) and epsilon(Hf)(t) values, and high Sr-87/Sr-88(t) and delta(18) O-zircon values, consistent with a derivation from continental crustal source. The high Nb-Ta type rhyolites and their plutonic equivalents are associated with the second episode of Tarim magmatism (283-272 Ma). They are characterized by small negative to positive Nb-Ta anomalies, oceanic island basalt (0113)-like trace element ratios, low Sr-87/Sr-88(t) and high epsilon(Nd)(t) and epsilon(Hf)(t) values. These high Nb-Ta rhyolites are best interpreted as hybrid products of crystal fractionation of mafic magmas, coupled with crustal assimilation. The temporal and compositional evolution of the Tarim rhyolites reflects various extents of thermal and mass exchange between mantle-derived basaltic magma and crustal material above a mantle plume. When the plume head rises to the base of the Tarim craton, it first melts enriched components in the lithospheric mantle (similar to 290 Ma), part of which may have ponded near the crust-mantle boundary and induced crustal anatexis leading to the formation of the low Nb-Ta type rhyolites. At similar to 280 Ma, large magma chambers and plumbing systems were formed due to increasing magma supply rate during decompression melting of the mantle plume. This led to the formation of a mafic-ultramafic and felsic association of which the high Nb-Ta type rhyolites are a part. (C) 2014 Elsevier B.V. All right reservedGeochemistry & GeophysicsMineralogySCI(E)[email protected],SI59-7220

Magnetochronology of the Entire Chinle Formation (Norian Age) in a Scientific Drill Core From Petrified Forest National Park (Arizona, USA) and Implications for Regional and Global Correlations in the Late Triassic

Building on an earlier study that confirmed the stability of the 405‐kyr eccentricity climate cycle and the timing of the Newark‐Hartford astrochronostratigraphic polarity time scale back to 215 Ma, we extend the magnetochronology of the Late Triassic Chinle Formation to its basal unconformity in scientific drill core PFNP‐1A from Petrified Forest National Park (Arizona, USA). The 335‐m‐thick Chinle section is imprinted with paleomagnetic polarity zones PF1r to PF10n, which we correlate to chrons E17r to E9n (~209 to 224 Ma) of the Newark‐Hartford astrochronostratigraphic polarity time scale. A sediment accumulation rate of ~34 m/Myr can be extended down to ~270 m, close to the base of the Sonsela Member and the base of magnetozone PF5n, which we correlate to chron E14n that onsets at 216.16 Ma. Magnetozones PF5r to PF10n in the underlying 65‐m‐thick section of the mudstone‐dominated Blue Mesa and Mesa Redondo members plausibly correlate to chrons E13r to E9n, indicating a sediment accumulation rate of only ~10 m/Myr. Published high‐precision U‐Pb detrital zircon dates from the lower Chinle tend to be several million years older than the magnetochronological age model. The source of this discrepancy is unclear but may be due to sporadic introduction of juvenile zircons that get recycled. The new magnetochronological constraint on the base of the Sonsela Member brings the apparent timing of the included Adamanian‐ Revueltian land vertebrate faunal zone boundary and the Zone II to Zone III palynofloral transition closer to the temporal range of the ~215 Ma Manicouagan impact structure in Canada

LA-ICPMS U-Pb geochronology of detrital zircon grains from the Coconino, Moenkopi, and Chinle Formations in the Petrified Forest National Park (Arizona)

Uranium–lead (U–Pb) geochronology was conducted by laser ablation – inductively coupled plasma mass spectrometry (LA-ICPMS) on 7175 detrital zircon grains from 29 samples from the Coconino Sandstone, Moenkopi Formation, and Chinle Formation. These samples were recovered from ∼ 520 m of drill core that was acquired during the Colorado Plateau Coring Project (CPCP), located in Petrified Forest National Park (Arizona). A sample from the lower Permian Coconino Sandstone yields a broad distribution of Proterozoic and Paleozoic ages that are consistent with derivation from the Appalachian and Ouachita orogens, with little input from local basement or Ancestral Rocky Mountain sources. Four samples from the Holbrook Member of the Moenkopi Formation yield a different set of Precambrian and Paleozoic age groups, indicating derivation from the Ouachita orogen, the East Mexico arc, and the Permo-Triassic arc built along the Cordilleran margin. A total of 23 samples from the Chinle Formation contain variable proportions of Proterozoic and Paleozoic zircon grains but are dominated by Late Triassic grains. LA-ICPMS ages of these grains belong to five main groups that correspond to the Mesa Redondo Member, Blue Mesa Member and lower part of the Sonsela Member, upper part of the Sonsela Member, middle part of the Petrified Forest Member, and upper part of the Petrified Forest Member. The ages of pre-Triassic grains also correspond to these chronostratigraphic units and are interpreted to reflect varying contributions from the Appalachian orogen to the east, Ouachita orogen to the southeast, Precambrian basement exposed in the ancestral Mogollon Highlands to the south, East Mexico arc, and Permian–Triassic arc built along the southern Cordilleran margin. Triassic grains in each chronostratigraphic unit also have distinct U and thorium (Th) concentrations, which are interpreted to reflect temporal changes in the chemistry of arc magmatism. Comparison of our LA-ICPMS ages with available chemical abrasion thermal ionization mass spectrometry (CA-TIMS) ages and new magnetostratigraphic data provides new insights into the depositional history of the Chinle Formation, as well as methods utilized to determine depositional ages of fluvial strata. For parts of the Chinle Formation that are dominated by fine-grained clastic strata (e.g., mudstone and siltstone), such as the Blue Mesa Member and Petrified Forest Member, all three chronometers agree (to within ∼ 1 Myr), and robust depositional chronologies have been determined. In contrast, for stratigraphic intervals dominated by coarse-grained clastic strata (e.g., sandstone), such as most of the Sonsela Member, the three chronologic records disagree due to recycling of older zircon grains and variable dilution of syn-depositional-age grains. This results in LA-ICPMS ages that significantly predate deposition and CA-TIMS ages that range between the other two chronometers. These complications challenge attempts to establish a well-defined chronostratigraphic age model for the Chinle Formation

U-Pb zircon geochronology and depositional age models for the Upper Triassic Chinle Formation (Petrified Forest National Park, Arizona, USA): implications for Late Triassic paleoecological and paleoenvironmental change

The Upper Triassic Chinle Formation is a critical non-marine archive of low-paleolatitude biotic and environmental change in southwestern North America. The well-studied and highly fossiliferous Chinle strata at Petrified Forest National Park (PFNP), Arizona, preserve a biotic turnover event recorded by vertebrate and palynomorph fossils, which has been alternatively hypothesized to coincide with tectonically driven climate change or with the Manicouagan impact event at ca. 215.5 Ma. Previous outcrop-based geochronologic age constraints are difficult to put in an accurate stratigraphic framework because lateral facies changes and discontinuous outcrops allow for multiple interpretations. A major goal of the Colorado Plateau Coring Project (CPCP) was to retrieve a continuous record in unambiguous superposition designed to remedy this situation. We sampled the 520-m-long core 1A of the CPCP to develop an accurate age model in unquestionable superposition by combining U-Pb zircon ages and magnetostratigraphy. From 13 horizons of volcanic detritus-rich siltstone and sandstone, we screened up to ∼300 zircon crystals per sample using laser ablation−inductively coupled plasma−mass spectrometry and subsequently analyzed up to 19 crystals of the youngest age population using the chemical abrasion−isotope dilution−thermal ionization mass (CA-ID-TIMS) spectrometry method. These data provide new maximum depositional ages for the top of the Moenkopi Formation (ca. 241 Ma), the lower Blue Mesa Member (ca. 222 Ma), and the lower (ca. 218 to 217 Ma) and upper (ca. 213.5 Ma) Sonsela Member. The maximum depositional ages obtained for the upper Chinle Formation fall well within previously proposed age constraints, whereas the maximum depositional ages for the lower Chinle Formation are relatively younger than previously proposed ages from outcrop; however, core to outcrop stratigraphic correlations remain uncertain. By correlating our new ages with the magnetostratigraphy of the core, two feasible age model solutions can be proposed. Model 1 assumes that the youngest, coherent U-Pb age clusters of each sample are representative of the maximum depositional ages and are close to (227 Ma) in age, and hence the biotic turnover event cannot be correlated to the Carnian−Norian boundary but is rather a mid-Norian event. Our age models demonstrate the powers, but also the challenges, of integrating detrital CA-ID-TIMS ages with magnetostratigraphic data to properly interpret complex sedimentary sequences

Earliest Palaeocene purgatoriids and the initial radiation of stem primates

Plesiadapiform mammals, as stem primates, are key to understanding the evolutionary and ecological origins of Pan-Primates and Euarchonta. The Purgatoriidae, as the geologically oldest and most primitive known plesiadapiforms and one of the oldest known placental groups, are also central to the evolutionary radiation of placentals and the Cretaceous-Palaeogene biotic recovery on land. Here, we report new dental fossils of Purgatorius from early Palaeocene (early Puercan) age deposits in northeastern Montana that represent the earliest dated occurrences of plesiadapiforms. We constrain the age of these earliest purgatoriids to magnetochron C29R and most likely to within 105–139 thousand years post- K/Pg boundary. Given the occurrence of at least two species, Purgatorius janisae and a new species, at the locality, we provide the strongest support to date that purgatoriids and, by extension, Pan-Primates, Euarchonta and Placentalia probably originated by the Late Cretaceous. Within 1 million years of their arrival in northeastern Montana, plesiadapiforms outstripped archaic ungulates in numerical abundance and dominated the arboreal omnivore–frugivore niche in mammalian local faunas