11,857 research outputs found

    Activity of alumina supported fe catalysts for N2O decomposition: Effects of the iron content and thermal treatment

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    Indexación: Scopus.The activity of Fe2O3/Al2O3 catalysts prepared by impregnation of Al2O3 with different amounts of Fe and calcination temperatures (650 and 900 °C) in the direct N2O decomposition reaction was studied. High calcination temperature was introduced to study the effect of "aging", which are the conditions prevailing in the process-gas option for N2O abatement. The catalysts were characterized by BET, XRD, UV-DRS, and H2-TPR. The incorporation of Fe promotes the alumina phase transition (g-Al2O3 to a-Al2O3) when the catalysts are calcined at 900 °C, which is accompanied by a decrease in the specifc area. The activity of the catalysts and the specifc surface area depend on Fe loading and calcination temperature. It was found that highly dispersed Fe species are more active than bulk type Fe2O3 particles. We conclude that Fe2O3/Al2O3 catalysts prepared by impregnation method are active in the decomposition of N2O, to be used at low or high reaction temperatures (tail-gas or process-gas treatments, respectively), as part of nitric acid production plant. © 2018 Sociedad Chilena de Quimica. All rights reserved.https://scielo.conicyt.cl/pdf/jcchems/v62n4/0717-9324-jcchems-62-04-3752.pd

    Modelling and performance analysis of four and eight element TCAS

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    This semi-annual report describes the work performed during the period September 1989 through March 1990. The first section presents a description of the effect of the engines of the Boeing 737-200 on the performance of a bottom mounted eight-element traffic alert and collision avoidance system (TCAS). The second section deals exclusively with a four element TCAS antenna. The model obtained to simulate the four element TCAS and new algorithms developed for studying its performance are described. The effect of location on its performance when mounted on top of a Boeing 737-200 operating at 1060 MHz is discussed. It was found that the four element TCAS generally does not perform as well as the eight element TCAS III
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