478 research outputs found

    Limiting process in shallow junction solar cells

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    In extending the violet and nonreflective cell technology to lower resistivities, several processes limiting output power were encountered. The most important was the dark diffusion current due to recombination at the front grid contacts. After removal of this problem by reduction of the silicon metal contact area (to 0.14 percent of the total area), the electric field enhanced junction recombination current J sub r was the main limitation. Alteration of the diffusion profile to reduce the junction field is shown to be an effective means of influencing J sub r. The remaining problems are the bulk recombination in the n+ layer and the surface recombination at the oxide-silicon interface; both of these problems are aggravated by band-narrowing resulting from heavy doping in the diffused layer. Experimental evidence for the main limitations is shown, where increased diffusion temperature is seen to reduce both the influence of the front grid contacts and the junction electric field by increasing the junction depth. The potential for further significant improvement in efficiency appears to be high

    Observation of non-classical rotational inertia in bulk solid 4He

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    In recent torsional oscillator experiments by Kim and Chan (KC), a decrease of rotational inertia has been observed in solid 4He in porous materials and in a bulk annular channel. This observation strongly suggests the existence of "non-classical rotational inertia" (NCRI), i.e. superflow, in solid 4He. In order to study such a possible "supersolid" phase, we perform torsional oscillator experiments for cylindrical solid 4He samples. We have observed decreases of rotational inertia below 200 mK for two solid samples (pressures P = 4.1 and 3.0 MPa). The observed NCRI fraction at 70 mK is 0.14 %, which is about 1/3 of the fraction observed in the annulus by KC. Our observation is the first experimental confirmation of the possible supersolid finding by KC.Comment: 6 pages, 3 firures, submitted to J. Low Temp. Phys. (Proceedings of QFS2006

    Zero-point vacancies in quantum solids

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    A Jastrow wave function (JWF) and a shadow wave function (SWF) describe a quantum solid with Bose--Einstein condensate; i.e. a supersolid. It is known that both JWF and SWF describe a quantum solid with also a finite equilibrium concentration of vacancies x_v. We outline a route for estimating x_v by exploiting the existing formal equivalence between the absolute square of the ground state wave function and the Boltzmann weight of a classical solid. We compute x_v for the quantum solids described by JWF and SWF employing very accurate numerical techniques. For JWF we find a very small value for the zero point vacancy concentration, x_v=(1.4\pm0.1) x 10^-6. For SWF, which presently gives the best variational description of solid 4He, we find the significantly larger value x_v=(1.4\pm0.1) x 10^-3 at a density close to melting. We also study two and three vacancies. We find that there is a strong short range attraction but the vacancies do not form a bound state.Comment: 19 pages, submitted to J. Low Temp. Phy

    Giant Coulomb broadening and Raman lasing on ionic transitions

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    CW generation of anti-Stokes Raman laser on a number of blue-green argon-ion lines (4p-4s, 4p-3d) has been demonstrated with optical pumping from metastable levels 3d'^2G, 3d^4F. It is found, that the population transfer rate is increased by a factor of 3-5 (and hence, the output power of such Raman laser) owing to Coulomb diffusion in the velocity space. Measured are the excitation and relaxation rates for the metastable level. The Bennett hole on the metastable level has been recorded using the probe field technique. It has been shown that the Coulomb diffusion changes shape of the contour to exponential cusp profile while its width becomes 100 times the Lorentzian one and reaches values close to the Doppler width. Such a giant broadening is also confirmed by the shape of the absorption saturation curve.Comment: RevTex 18 pages, 5 figure

    Search for supersolidity in 4He in low-frequency sound experiments

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    We present results of the search for supersolid 4He using low-frequency, low-level mechanical excitation of a solid sample grown and cooled at fixed volume. We have observed low frequency non-linear resonances that constitute anomalous features. These features, which appear below about 0.8 K, are absent in 3He. The frequency, the amplitude at which the nonlinearity sets in, and the upper temperature limit of existence of these resonances depend markedly on the sample history.Comment: Submitted to the Quantum Fluids and Solids Conf. Aug. 2006 Kyot

    A practical synthesis of diethyl 1-methylthio-2-oxo-2-phenylethylphosphonates from diethyl methylthiomethylphosphonate

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    An efficient synthesis of 2'- and 3'-substituted diethyl 1-methylthio-2-oxo-2-phenylethylphosphonates 3a-k from 2'- and 3'-substituted benzoyl chlorides 2a-k using diethyl methylthio-l-lithiomethylphosphonate is described.81248125

    Two-body correlations and the superfluid fraction for nonuniform systems

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    We extend the one-body phase function upper bound on the superfluid fraction in a periodic solid (a spatially ordered supersolid) to include two-body phase correlations. The one-body current density is no longer proportional to the gradient of the one-body phase times the one-body density, but rather it depends also on two-body correlation functions. The equations that simultaneously determine the one-body and two-body phase functions require a knowledge of one-, two-, and three-body correlation functions. The approach can also be extended to disordered solids. Fluids, with two-body densities and two-body phase functions that are translationally invariant, cannot take advantage of this additional degree of freedom to lower their energy.Comment: 13 page

    BCC vs. HCP - The Effect of Crystal Symmetry on the High Temperature Mobility of Solid 4^4He

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    We report results of torsional oscillator (TO) experiments on solid 4^4He at temperatures above 1K. We have previously found that single crystals, once disordered, show some mobility (decoupled mass) even at these rather high temperatures. The decoupled mass fraction with single crystals is typically 20- 30%. In the present work we performed similar measurements on polycrystalline solid samples. The decoupled mass with polycrystals is much smaller, ∼\sim 1%, similar to what is observed by other groups. In particular, we compared the properties of samples grown with the TO's rotation axis at different orientations with respect to gravity. We found that the decoupled mass fraction of bcc samples is independent of the angle between the rotation axis and gravity. In contrast, hcp samples showed a significant difference in the fraction of decoupled mass as the angle between the rotation axis and gravity was varied between zero and 85 degrees. Dislocation dynamics in the solid offers one possible explanation of this anisotropy.Comment: 10 pages, 5 figures, to appear in Journal of Low Temperature Physics - special issue on Supersolidit

    The glassy response of solid He-4 to torsional oscillations

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    We calculated the glassy response of solid He-4 to torsional oscillations assuming a phenomenological glass model. Making only a few assumptions about the distribution of glassy relaxation times in a small subsystem of otherwise rigid solid He-4, we can account for the magnitude of the observed period shift and concomitant dissipation peak in several torsion oscillator experiments. The implications of the glass model for solid He-4 are threefold: (1) The dynamics of solid He-4 is governed by glassy relaxation processes. (2) The distribution of relaxation times varies significantly between different torsion oscillator experiments. (3) The mechanical response of a torsion oscillator does not require a supersolid component to account for the observed anomaly at low temperatures, though we cannot rule out its existence.Comment: 9 pages, 4 figures, presented at QFS200
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