Development of lanthanum nickelate as a cathode for use in intermediate temperature solid oxide fuel cells

The performance of lanthanum nickelate, La2NiO4+δ (LNO), as a cathode in IT-SOFCs with the electrolyte cerium gadolinium oxide, Ce0.9Gd0.1O2−δ (CGO), has been investigated by AC impedance spectroscopy of symmetrical cells. A significant reduction in the area specific resistance (ASR) has been achieved with a layered cathode structure consisting of a thin compact LNO layer between the dense electrolyte and porous electrode. This decrease in ASR is believed to be a result of contact at the electrolyte/cathode boundary enhancing the oxygen ion transfer to the electrolyte. An ASR of 1.0 Ω cm2 at 700 °C was measured in a symmetrical cell with this layered structure, compared to an ASR of 7.4 Ω cm2 in a cell without the compact layer. In addition, further improvements were observed by enhancing the cell current collection and it is anticipated that a symmetrical cell consisting of a layered structure with adequate current collection would lower these ASR values further

Investigation of Graded La2NiO4+ Cathodes to Improve SOFC Electrochemical Performance

Mixed ionic and electronic conducting MIEC oxides are promising materials for use as cathodes in solid oxide fuel cells SOFCs due to their enhanced electrocatalytic activity compared with electronic conducting oxides. In this paper, the MIEC oxide La2NiO4+ was prepared by the sol-gel route. Graded cathodes were deposited onto yttria-stabilized zirconia YSZ pellets by dip-coating, and electrochemical impedance spectroscopy studies were performed to characterize the symmetrical cell performance. By adapting the slurries, cathode layers with different porosities and thicknesses were obtained. A ceria gadolinium oxide CGO barrier layer was introduced, avoiding insulating La2Zr2O7 phase formation and thus reducing resistance polarization of the cathode. A systematic correlation between microstructure, composition, and electrochemical performance of these cathodes has been performed. An improvement of the electrochemical performance has been demonstrated, and a reduction in the area specific resistance ASR by a factor of 4.5 has been achieved with a compact interlayer of La2NiO4+ between the dense electrolyte and the porous La2NiO4+ cathode layer. The lowest observed ASR of 0.11 cm2 at 800°C was obtained from a symmetrical cell composed of a YSZ electrolyte, a CGO interlayer, an intermediate compact La2NiO4+ layer, a porous La2NiO4+ electrode layer, and a current collection layer of platinum paste

Modernisation de l'agriculture irriguée et durabilité des ressources en eau dans le périmètre du Tadla au Maroc

International audienceLes cultures irriguées de la plaine du Tadla dépendent principalement du grand périmètre irrigué de 100 000 ha géré par l'Office régional de mise en valeur agricole du Tadla (ORMVAT). Ce périmètre est alimenté par des ressources en eau de surface, et par des prélèvements individuels dans les nappes souterraines qui se sont multipliés depuis les années 1980 au rythme des sécheresses et des évolutions culturales. Les nouveaux besoins agricoles en eau, apparus après la libéralisation des assolements en 1996, et la réduction de l'offre en eau de surface ont favorisé la hausse rapide de ces prélèvements. Si le niveau global de la production agricole s'est jusqu'ici maintenu, la dégradation de la qualité de l'eau et la chute du niveau des nappes montrent aujourd'hui les limites de ce système et interrogent sur sa pérennité. Ce contexte de rareté de la ressource et d'accès conjoint aux ressources en eau superficielle et souterraine se rencontre dans de nombreux périmètres du Maghreb, mais aussi dans de nombreuses régions du monde. La Commission méditerranéenne du développement durable a proposé en premier lieu que le système soit fondé sur la gestion de la demande en eau et que soient mobilisés simultanément des instruments techniques, économiques et institutionnels. Deux scénarios techniques et économiques sont analysés. Ils correspondent à des améliorations des pratiques d'irrigation, par un planage des parcelles en irrigation gravitaire, ou par l'introduction de la micro-irrigation. Leurs effets sur la consommation d'eau sont étudiés, en s'appuyant sur la modélisation économique des exploitations agricoles de la zone (association polyculture-élevage, rˆole prédominant de l'élevage laitier) et leur mode d'accès à l'eau souterraine, le coût de l'eau consommée étant fonction de la source et de l'équipement. Les résultats montrent que ces innovations (introduction d'un planage régulier ou équipement en micro-irrigation) peuvent effectivement conduire à des diminutions substantielles des prélèvements de la nappe. Cependant, ces techniques ne sont pas couramment adoptées par les agriculteurs, des facteurs de freins ou de blocage restent à identifier. Des instruments économiques peuvent influencer ces évolutions (en particulier pour faire baisser la consommation d'eau souterraine) en les rendant plus attractives pour les producteurs, et assurer ainsi leur diffusion

Are Laparoscopic Staplers Effective for Ligation of Large Intraabdominal Arteries?

AbstractObjectives. To evaluate ligation of aortoiliac arteries with laparoscopic staplers in order to develop specifically designed staplers.Methods. Cadaveric study. Seven human cadaver aortas were stapled using EndoGIA60® staplers. Efficiency was evaluated macroscopically and on a hydrodynamic bench.Clinical study. Twelve patients had ligation of 14 large abdominal arteries (aorta: nine, iliac artery: four, hepatic artery: one) using a laparoscopic stapler. Stapling efficiency was judged on peroperative clinical and postoperative CT scan criteria.Results. Cadaveric study. Stapling was performed perfectly on four moderately calcified aortas, without leakage with a pulsatile pressure of >250 mmHg. For three aortas with severe calcification, stapling was not efficient and major leakage occurred.Clinical study. Stapling appeared clinically efficient on all arteries but one aorta: this severely calcified aorta was ligated conventionally. The staplers are not easy to use due to their shape and their lack of articulation. After a mean follow-up of 31.3 months, all the other stapled arteries were effectively ligated.Conclusion. The commercially available staplers can be used securely on moderately calcified arteries but stapling of severely calcified arteries should be avoided. These devices should be redesigned to facilitate their use in vascular surgery

Continuous macroscopic limit of a discrete stochastic model for interaction of living cells

In the development of multiscale biological models it is crucial to establish a connection between discrete microscopic or mesoscopic stochastic models and macroscopic continuous descriptions based on cellular density. In this paper a continuous limit of a two-dimensional Cellular Potts Model (CPM) with excluded volume is derived, describing cells moving in a medium and reacting to each other through both direct contact and long range chemotaxis. The continuous macroscopic model is obtained as a Fokker-Planck equation describing evolution of the cell probability density function. All coefficients of the general macroscopic model are derived from parameters of the CPM and a very good agreement is demonstrated between CPM Monte Carlo simulations and numerical solution of the macroscopic model. It is also shown that in the absence of contact cell-cell interactions, the obtained model reduces to the classical macroscopic Keller-Segel model. General multiscale approach is demonstrated by simulating spongy bone formation from loosely packed mesenchyme via the intramembranous route suggesting that self-organizing physical mechanisms can account for this developmental process.Comment: 4 pages, 3 figure

The Non-thermal Radio Jet Toward the NGC 2264 Star Formation Region

We report sensitive VLA 3.6 cm radio observations toward the head of the Cone nebula in NGC 2264, made in 2006. The purpose of these observations was to study a non-thermal radio jet recently discovered, that appears to emanate from the head of the Cone nebula. The jet is highly polarized, with well-defined knots, and one-sided. The comparison of our images with 1995 archive data indicates no evidence of proper motions nor polarization changes. We find reliable flux density variations in only one knot, which we tentatively identify as the core of a quasar or radio galaxy. An extragalactic location seems to be the best explanation for this jet.Comment: 12 pages, 5 figure

Preparation of Ni–YSZ thin and thick films on metallic interconnects as cell supports. Applications as anode for SOFC

In this work, we propose the preparation of a duplex anodic layer composed of both a thin (100 nm) and a thick film (10 lm) with Ni–YSZ material. The support of this anode is a metallic substrate, which is the interconnect of the SOFC unit cell. The metallic support limits the temperature of thermal treatment at 800 C to keep a good interconnect mechanical behaviour and to reduce corrosion. We have chosen to elaborate anodic coatings by sol–gel route coupled with dip-coating process, which are low cost techniques and allow working with moderate temperatures. Thin films are obtained by dipping interconnect substrate into a sol, and thick films into an optimized slurry. After thermal treatment at only 800 C, anodic coatings are adherent and homogeneous. Thin films have compact microstructures that confer ceramic protective barrier on metal surface. Further coatings of 10 lm thick are porous and constitute the active anodic material

OH main line masers in the M82 starburst

A study of the distribution of OH gas in the central region of the nearby active starburst galaxy M82 has confirmed two previously known bright masers and revealed several new main line masers. Three of these are seen only at 1665 MHz, one is detected only at 1667 MHz, while the rest are detected in both lines. Observations covering both the 1665 and 1667 MHz lines, conducted with both the Very Large Array (VLA) and the Multi-Element Radio Linked Interferometer Network (MERLIN), have been used to accurately measure the positions and velocities of these features. This has allowed a comparison with catalogued continuum features in the starburst such as HII regions and supernova remnants, as well as known water and satellite line OH masers. Most of the main line masers appear to be associated with known HII regions although the two detected only at 1665 MHz are seen along the same line of sight as known supernova remnants.Comment: MNRAS accepted. 16 pages, 13 figure

Exponential Distribution of Locomotion Activity in Cell Cultures

In vitro velocities of several cell types have been measured using computer controlled video microscopy, which allowed to record the cells' trajectories over several days. On the basis of our large data sets we show that the locomotion activity displays a universal exponential distribution. Thus, motion resulting from complex cellular processes can be well described by an unexpected, but very simple distribution function. A simple phenomenological model based on the interaction of various cellular processes and finite ATP production rate is proposed to explain these experimental results.Comment: 4 pages, 3 figure