Condensation risk: comparison of steady-state and transient methods

Accurate assessment of both surface and interstitial condensation risk is important not only to reduce the damaging effect of moisture within the structure of buildings, but also to provide a healthy environment free from mould growth. The current British Standard (BS EN ISO 13788: 2002) contains an assessment procedure based on the assumption of a steady-state heat flow through the building envelope, neglecting the transient nature of the problem. This paper compares and evaluates numerical results of the condensation risk calculation under both steady-state and transient conditions using the existing numerical codes. Significant differences are apparent between the predictions of the simple (steady-state) and complex (transient) methods for all construction details modelled

Inner-sphere complexation of cations at the rutile-water interface: A concise surface structural interpretation with the CD and MUSIC model

Acid–base reactivity and ion-interaction between mineral surfaces and aqueous solutions is most frequently investigated at the macroscopic scale as a function of pH. Experimental data are then rationalized by a variety of surface complexation models. These models are thermodynamically based which in principle does not require a molecular picture. The models are typically calibrated to relatively simple solid-electrolyte solution pairs and may provide poor descriptions of complex multi-component mineral–aqueous solutions, including those found in natural environments. Surface complexation models may be improved by incorporating molecular-scale surface structural information to constrain the modeling efforts. Here, we apply a concise, molecularly-constrained surface complexation model to a diverse suite of surface titration data for rutile and thereby begin to address the complexity of multi-component systems. Primary surface charging curves in NaCl, KCl, and RbCl electrolyte media were fit simultaneously using a charge distribution (CD) and multisite complexation (MUSIC) model [Hiemstra T. and Van Riemsdijk W. H. (1996) A surface structural approach to ion adsorption: the charge distribution (CD) model. J. Colloid Interf. Sci. 179, 488–508], coupled with a Basic Stern layer description of the electric double layer. In addition, data for the specific interaction of Ca2+ and Sr2+ with rutile, in NaCl and RbCl media, were modeled. In recent developments, spectroscopy, quantum calculations, and molecular simulations have shown that electrolyte and divalent cations are principally adsorbed in various inner-sphere configurations on the rutile 1 1 0 surface [Zhang Z., Fenter P., Cheng L., Sturchio N. C., Bedzyk M. J., Predota M., Bandura A., Kubicki J., Lvov S. N., Cummings P. T., Chialvo A. A., Ridley M. K., Bénézeth P., Anovitz L., Palmer D. A., Machesky M. L. and Wesolowski D. J. (2004) Ion adsorption at the rutile–water interface: linking molecular and macroscopic properties. Langmuir 20, 4954–4969]. Our CD modeling results are consistent with these adsorbed configurations provided adsorbed cation charge is allowed to be distributed between the surface (0-plane) and Stern plane (1-plane). Additionally, a complete description of our titration data required inclusion of outer-sphere binding, principally for Cl- which was common to all solutions, but also for Rb+ and K+. These outer-sphere species were treated as point charges positioned at the Stern layer, and hence determined the Stern layer capacitance value. The modeling results demonstrate that a multi-component suite of experimental data can be successfully rationalized within a CD and MUSIC model using a Stern-based description of the EDL. Furthermore, the fitted CD values of the various inner-sphere complexes of the mono- and divalent ions can be linked to the microscopic structure of the surface complexes and other data found by spectroscopy as well as molecular dynamics (MD). For the Na+ ion, the fitted CD value points to the presence of bidenate inner-sphere complexation as suggested by a recent MD study. Moreover, its MD dominance quantitatively agrees with the CD model prediction. For Rb+, the presence of a tetradentate complex, as found by spectroscopy, agreed well with the fitted CD and its predicted presence was quantitatively in very good agreement with the amount found by spectroscopy

An initial evaluation of a biohygrothermal model for the purpose of assessing the risk mould growth in UK dwellings

Moulds are organisms that may be found in both the indoor and outdoor environment. Moulds play an important rolebreaking down and digesting organic material, but, if they are significantly present in the indoor environment they mayaffect the health of the occupants. A relative humidity of 80% at wall surfaces is frequently stated as the decisivecriterion for mould growth and methods used to assess the risk of mould growth are often based on steady stateconditions. However, considering the dynamic conditions typically found in the indoor environment, a betterunderstanding of the conditions required for mould to grow would seem desirable. This paper presents initialexploratory work to evaluate and assess ‘WUFI-bio’ - ‘biohygrothermal’ software that predicts the likelihood of mould growth under transient conditions. Model predictions are compared with large monitored data set from 1,388 UKdwellings before and after insulation and new heating systems are installed (‘Warm Front’), the suitability of thissoftware as a tool to predict mould growth will ultimately be assessed. This paper presents some initial, exploratorywork

Post occupancy evaluation of buildings in a zero carbon city

This paper presents a methodology to monitor the performance of buildings in a Zero Carbon City from the occupant perspective. Masdar City in Abu Dhabi is hailed as the World's pioneering Zero Carbon Zero Waste city. The initial phase of construction is complete and the first students have moved into the residential quarters of the Masdar Institute of Science and Technology (MIST) in September 2010. Although the study monitors both Carbon and Waste, this paper outlines a Post Occupancy Evaluation (POE) to assess the resident's satisfaction and building performance at MIST. The research focuses on the role that user behaviour and satisfaction plays on energy efficiency. It is hoped that such an approach will allow building performance to be normalized for user behaviour and to examine how best to commission, explain and handover complex low energy developments to new residents. It is hoped that the residents' reaction and adaptation to the first Zero Carbon Zero Waste city will provide valuable insights that can be applied to future low energy developments

Upper-surface blowing nacelle design study for a swept wing airplane at cruise conditions

A study was made to design two types of overwing nacelles for an existing wing-body at a design condition of Mach = 0.8 and C sub L = 0.2. Internal and external surface contours were developed for nacelles having either a D-shaped nozzle or a high-aspect-ratio nozzle for upper-surface blowing in the powered-lift mode of operation. The goal of the design was the development of external nacelle lines that would minimize high-speed aerodynamic interference effects. Each nacelle type was designed for both two- and four-engine airplanes using an iterative process of aerodynamic potential flow analysis. Incremental nacelle drag estimates were made for flow-through wind tunnel models of each configuration

An evaluation of the hygrothermal performance of 'standard' and 'as built' construction details using steadystate and transient modelling

Accurate assessment of both surface and interstitial condensation risk at the design stage of buildings is of great importance - not just to minimise the damaging effects moisture can cause to building envelopes, but also to contribute to the provision of adequate indoor air quality. Guidance certainly does exist with regards to limiting thermal bridging in order to prevent condensation occurring on new constructions. However, a recent study has provided clear evidence that the reality, both in translating the available guidance into a specific design and in construction on site is often rather different from the 'ideal'. This paper reports on that study and compares and evaluates the hygrothermal performance of construction details for different phases during the building life cycle. The results of both the surface and interstitial condensation risk simulations under both steady-state and transient conditions are presented and discussed. Significant differences in the hygrothermal performance of 'standard' and 'as built' construction details are observed