Primer registro de reptiles marinos triásicos (notosaurios, sauropterigios) del Complejo Alpujárride (Zonas Internas de la Cordillera Bética, España)

This work reports the first record in the Internal Zones of the Betic Cordillera of a vertebrate fossil remain, more exactly a rib, corresponding to a marine reptile (Sauropterygia). The development of epicontinental platforms restricted to the Tethys Ocean during the fragmentation of Pangea since the late Lower Triassic favoured the radiation of Sauropterygia, diapsid marine reptiles including Placodontiformes, Pachypleurosauria, Nothosauroidea, and Pistosauroidea. The Triassic of the Alpujarride Complex, in the Internal Zones of the Betic Cordillera, SE Spain, comprises the carbonate deposits of these epicontinental platforms developed during the Middle-Late Triassic in the northern margin of the Mesomediterranean Massif. The studied stratigraphic interval is located at Sierra de Lújar (Granada Province) and consists of 17.5-m thick succession of alternating fossiliferous marls and limestones with local intense bioturbation and abundance of macroinvertebrates. The studied interval represents shallow facies of the inter- to subtidal environment as deduced by the record of Lofer cycles and the record of carbonated breccia at the top of the sequence likely related to storm events. Lofer cycles display lamination at their bases and intense bioturbation and abundant bivalves towards the top. A 15-cm long dorsal rib of a sauropterygian, likely a nothosaur, was recorded in this succession. It is well preserved, without evidence of original fragmentation, borings, or encrustations. This study shows for the first time fossil bones of marine reptiles in the Alpujarride Complex, which inhabited the shallow-water environments during the Triassic, equivalent to the marine reptiles recorded in other areas such as the Iberian Palaeomargin and other central Europe basins.Este trabajo documenta el primer registro de vertebrados fósiles, concretamente de un reptil marino (sauropterygia), en las Zonas Internas de la Cordillera Bética. El desarrollo de plataformas epicontinentales en el Tetis durante la fragmentación de Pangea a partir del Triásico Inferior tardío favoreció la radiación de los sauropterigios, grupo de reptiles diápsidos marinos que incluye a los clados Placodontiformes, Pachypleurosauria, Nothosauroidea y Pistosauroidea. Los materiales triásicos del Complejo Alpujárride de las Zonas Internas de la Cordillera Bética, SE de España, incluyen los depósitos carbonatados correspondientes a las plataformas epicontinentales desarrolladas durante el Triásico medio-superior en el margen norte del Macizo Messomediterraneo. El intervalo estratigráfico seleccionado se encuentra en la Sierra de Lújar (Granada) y es una sucesión de 17,5 m de potencia con una alternancia de margas y calizas fosilíferas con abundante bioturbación y restos de macroinvertebrados. Se han identificado ciclos loferíticos con laminación a la base que cambia a un sedimento intensamente bioturbado con abundantes bivalvos hacia el techo del ciclo. El intervalo de estudio representa facies someras en un ambiente inter- o submareal como indican los ciclos loferíticos y la presencia de brechas carbonatadas en el techo de la secuencia, presumiblemente relacionadas con tormentas. Una costilla dorsal de 15 cm de longitud de un sauropterigio, probablemente un notosaurio, ha sido descubierta en esta serie en buen estado de conservación y sin evidencias de fragmentación, perforaciones o encostrantes. Este estudio muestra por primera vez la presencia de restos fósiles de reptiles marinos en el Complejo Alpujárride, reptiles que vivieron en aguas someras durante el Triásico al igual que se ha documentado en el Paleomargen Ibérico y en algunas cuencas triásicas de Europa central.Juan de la Cierva Program Ministerio de Ciencia, Innovación y Universidade

Phreatomagmatic activity and associated hydrothermal processes in the lamproitic Volcano of Cancarix (Southeast Spain)

The study of the Cancarix volcano structure (Sierra de las Cabras, SE Spain) and the regional observations in similar lamproite volcanoes suggest that these magmas were emplaced during the Miocene in relation to transtensive structures at the North end of the Betic Cordillera. These structures were able to reactivate previous basement faults which facilitated the ascending circulation of enriched ultrapotassic magma. Two episodes are distinguished: 1) explosive volcanism due to the interaction between magma and groundwater from the karstic system of the host carbonate rocks, which generated a phreatomagmatic-effusive complex and 2) volcanic-building with crystal-rich magma. The phreatomagmatic breccia distribution is conditioned by the tectonic structure of the host rock, with maximum thickness over the marls basement, mechanically less competent, which is controlling the preferential magma movement towards the S-SE. Chemical, mineralogical and textural study of the host rocks and the volcanic products indicates that following the magmatic activity hydrothermal processes ocurred, with: (1) the genesis of new minerals (namely, saponitic smectite and serpentine minerals) in the host rock clasts from the phreatomagmatic breccia; and (2) the recrystallisation of dolomite and amorphous silica growing up to 20 m from the contact in porous carbonates. In contrast, marls and micritic carbonates show no recrystallisation, only a slight enrichment of Mg and some exotic elements, limited to the first few metres.El estudio de la estructura del Volcán de Cancarix (Sierra de las Cabras, SE España) y las observaciones regionales en volcanes lamproíticos similares sugieren que el emplazamiento de los magmas tuvo lugar durante el Mioceno en relación con estructuras transtensivas en el extremo Norte de la Cordillera Bética. Estas estructuras favorecieron la reactivación de fallas previas del basamento que facilitaron la circulación ascendente de magmas enriquecidos en Mg y K. Se han diferenciado dos episodios de emisión de material en el Volcán de Cancarix: 1) vulcanismo explosivo debido a la interacción del magma con el agua subterránea procedente del sistema kárstico de los carbonatos que componen la roca caja, que generó un complejo freatomagmático (brechas y lavas) y 2) una etapa de vulcanismo efusivo con un magma rico en cristales que dio lugar al domo lamproítico. La distribución de la brecha freatomagmática estuvo condicionada por la estructura tectónica de la roca caja, con un máximo espesor sobre las margas, mecánicamente menos competentes. En consequencia, la dirección preferente de avance del magma fue hacia el S-SE, donde las margas son predominantes. El estudio geoquímico, mineralógico y textural de la roca caja y del material volcánico indica que tras la actividad volcánica, hubo una actividad hidrotermal que produjo la alteración de los materiales con: (1) la génesis de nuevos minerales (esmectitas saponíticas y minerales del grupo de la serpentina) en los clastos de la roca caja incorporados a la brecha freatomagmática y (2) la recristalizacion de dolomita y sílice amorfa en las rocas carbonatadas más porosas desde el contacto hasta una distancia de aproximadamente 20 m. Sin embargo, las margas y los carbonatos micríticos no muestran recristalización, únicamente un ligero enriquecimiento en Mg y algunos elementos traza en los primeros metros cerca del contacto con la brecha freatomagmática y la lamproita

TAPHONOMY OF AMMONITE ASSEMBLAGES FROM THE MIDDLE-UPPER OXFORDIAN (TRANSVERSARIUM? - BIFURCATUS ZONES) IN THE INTERNAL PREBETIC (BETIC CORDILLERA, SOUTHERN SPAIN): TAPHONIC POPULATIONS AND TAPHOFACIES TO SUPPORT ECOSTRATIGRAPHIC INTERPRETATIONS

The taphonomic analysis conducted on ammonoid assemblages has proven useful for palaeobiological and palaeoenvironmental reconstructions in upper Middle-to-lower Upper Oxfordian epicontinental deposits of the Internal Prebetic (southern Spain). Taphonic populations close to type I indicate the proximity, even coincidence, of life areas for neritic ammonites (i.e. parautochthonous assemblages). The relationships among preservation mode, shell size, within-bed position, corrasion, fragmentation, and epibionts (encrustment included), with lumpy-oncolitic and condensed & bioclasts-rich lumpy-oncolitic limestones allows us to typify two taphofacies. Taphofacies I shows higher values of mean shell size, corrasion, epibionts and encrustments, as well as a high number of specimens in quasi-horizontal settlement. The opposite characteristics serve to identify Taphofacies II. Taphonomic features, taphofacies and lithofacies combine in coherence with progressing third-order transgressive-to-highstand system-tract conditions and the resulting ecostratigraphic trends, which are registered by fluctuations in ammonite assemblages

Foraminiferal morphogroups in dysoxic shelf deposits from the Jurassic of Spitsbergen

Analysis of benthic foraminiferal assemblages was performed in Bathonian to Kimmeridgian deposits through a section covering the lower half of the Agardhfjellet Formation in central Spitsbergen. The section consists mainly of organic-rich shales, which contain low-diversity agglutinated assemblages. In this foraminiferal succession five morphogroups were differentiated according to shell architecture (general shape, mode of coiling and number of chambers), integrated with the supposed microhabitat (epifaunal, shallow infaunal and deep infaunal) and feeding strategy (suspension-feeder, herbivore, bacterivore, etc.). The environmental evolution of the analysed section is interpreted by using the stratigraphic distribution of morphogroups, combined with species diversities and sedimentary data, in a sequence stratigraphic framework. The section comprises two depositional sequences, which demonstrate that species diversity and relative frequency of morphogroups are correlative with transgressive–regressive trends controlling depth and oxygenation of the water column. In both sequences, the maximum flooding interval is characterized by increased organic carbon content, dominance of the epifaunal morphogroups and reduced species diversity: features reflecting the increased degree of stagnation separating the transgressive phase from the regressive phase.The participation of J. Nagy in this research has been supported by the Statoil/Hydro VISTA programme. The contribution of M. Reolid and F.J. Rodríguez-Tovar has been supported by the projects CGL2005-06636-C0201 and CGL2005-0316/BTE, the EMMI group (RNM-178, Junta de Andalucía) and the Acción Integrada 30.AI.PO.1300 (University of Granada–University of Oslo). A grant of the Universidad de Jaén financed M. Reolid’s short stay at the University of Oslo

On the microstructure, growth pattern and original porosity of belemnite rostra: insights from calcitic Jurassic belemnites

Calcitic belemnite rostra are usually employed to perform paleoenvironmental studies based on geochemical data. However, several questions, such as their original porosity and microstructure, remain open, despite they are essential to make accurate interpretations based on geochemical analyses. This paper revisits and enlightens some of these questions. Petrographic data demonstrate that calcite crystals of the rostrum solidum of belemnites grow from spherulites that successively develop along the apical line, resulting in a “regular spherulithic prismatic” microstructure. Radially arranged calcite crystals emerge and diverge from the spherulites: towards the apex, crystals grow until a new spherulite is formed; towards the external walls of the rostrum, the crystals become progressively bigger and prismatic. Adjacent crystals slightly vary in their c-axis orientation, resulting in undulose extinction. Concentric growth layering develops at different scales and is superimposed and traversed by a radial pattern, which results in the micro-fibrous texture that is observed in the calcite crystals in the rostra. Petrographic data demonstrate that single calcite crystals in the rostra have a composite nature, which strongly suggests that the belemnite rostra were originally porous. Single crystals consistently comprise two distinct zones or sectors in optical continuity: 1) the inner zone is fluorescent, has relatively low optical relief under transmitted light (TL) microscopy, a dark-grey color under backscatter electron microscopy (BSEM), a commonly triangular shape, a “patchy” appearance and relatively high Mg and Na contents; 2) the outer sector is non-fluorescent, has relatively high optical relief under TL, a light-grey color under BSEM and low Mg and Na contents. The inner and fluorescent sectors are interpreted to have formed first as a product of biologically controlled mineralization during belemnite skeletal growth and the non-fluorescent outer sectors as overgrowths of the former, filling the intra- and inter-crystalline porosity. This question has important implications for making paleoenvironmental and/or paleoclimatic interpretations based on geochemical analyses of belemnite rostra. Finally, the petrographic features of composite calcite crystals in the rostra also suggest the non-classical crystallization of belemnite rostra, as previously suggested by other authors. © 2016, Universidad Complutense de Madrid. All rights reserved

The biotic crisis across the Oceanic Anoxic Event 2: Palaeoenvironmental inferences based on foraminifera and geochemical proxies from the South Iberian Paleomargin

Open marine sediments deposited during the CenomanianeTuronian transition are well exposed in the Spanish Ba~nos de la Hedionda section (Betic Cordillera, South Iberian Palaeomargin). Analysis of foraminiferal assemblages and geochemical proxies allow inferences on the impact of the Oceanic Anoxic Event 2 (OAE2) in this area of the western Tethys. Three main intervals have been identified corresponding to different lithological units and biozones. (1) The top of the Capas Blancas Member (Rotalipora cushmani Biozone) represents the pre-extinction phase with diverse foraminiferal assemblages and well developed water-column tiering, well-oxygenated, oligotrophic deep-waters and oxygenated to poorly oxygenated, mesotrophic surface-waters. Foraminiferal opportunist species point to a minor event with dysoxic conditions preceding the OAE2. (2) The black radiolaritic shales (Whiteinella archaeocretacea Biozone) consist of a foraminiferal-barren interval, except for the lowermost centimetres where planktic surface-dweller opportunists are common. Redox sensitive elements (Cr/Al, V/Al, U/Th, MoEF, Moaut, UEF and Uaut) and increased TOC values reflect oxygen depleted conditions related to the OAE2. The increase in P/Ti values at the base of this stratigraphic interval indicates an abrupt increase in productivity. High concentrations of radiolarians are congruent with high surface productivity probably related to changes in oceanic circulation and enhanced upwelling currents, as well as subsequent shallowing of the oxygenminimum zone. The increase in MoEF and Moaut towards the top of the black radiolaritic shales indicates temporal euxinic conditions. (3) A slow, bottom-up recovery of foraminiferal assemblages is inferred at the base of the Boqueron Member (Helvetoglobotruncana helvetica Biozone), with seafloor recolonization by benthic foraminifera being recorded previous to the water column colonization by planktic forms, mainly by intermediate-dwellers typical of mesotrophic waters. The subsequent proliferation of surfacedweller opportunists and deep-dweller opportunists adapted to mesotrophic to eutrophic conditions, and the decrease in planktic foraminiferal diversity, may indicate the persistence of poorly oxygenated conditions in the water column towards the lower-middle part of the H. helvetica Biozone

CALLOVIAN TO OXFORDIAN BENTHIC FORAMINIFERA FROM LER DOME, KUTCH BASIN (GUJARAT, INDIA): SYSTEMATIC, ECOSTRATIGRAPHY AND PALAEOENVIRONMENTAL RECONSTRUCTION

Analysis of the foraminiferal assemblages of the Chari Formation (Middle-Upper Jurassic transition) exposed at Ler Dome, Kutch Basin (India) allows one to interpret the incidence of different environmental parameters, especially the effect of sea-level changes in this group of microorganisms. The overall deposition of the Chari Formation took place in an open marine environment in the middle to outer shelf, having normal salinity and well-oxygenated bottom waters according to the lithofacies and the composition of the foraminiferal and macroinvertebrate assemblages. Changes in the diversity, abundance of foraminifera, and proportion of specialist forms were associated mainly with the availability of labile organic matter on the sea floor. The changes in trophic resources were associated with fluctuations in the type of sedimentation, which ranges from carbonates to siltstones and sandstones. During the regressive phase, a relatively high input of food resources, probably phytodetritus, was associated with siliciclastic sedimentation and commonly related with increased abundance and diversity of foraminifera, including specialist forms. During the transgressive phase, the influx of food resources from emerged areas and shallow environments decreased; sedimentation was more calcareous, with an accumulation of ammonoid shells that indicates hemipelagic conditions. The decrease in food resources for benthic foraminifera is reflected by a lesser diversity and abundance, and lower proportions of specialist foraminifera

SPECTRAL ANALYSIS OF TOARCIAN SEDIMENTS FROM THE VALDORBIA SECTION (UMBRIA-MARCHE APENNINES): THE ASTRONOMICAL INPUT IN THE FORAMINIFERAL RECORD

Toarcian sections studied mainly in Europe have revealed the incidence of Milankovitch forcing with a well-developed, highly stable, 405 ky component of eccentricity, a short-term eccentricity of ~100 kyr, the cycle of obliquity ~36 kyr, and the precession signal at ~21 kyr. Cyclostratigraphic analysis of the Toarcian succession at the Valdorbia section (Umbria-Marche Apennines) was conducted based on time-series of foraminiferal assemblages. Well-developed cyclic patterns were obtained, with several significant cycles corresponding to thicknesses of 3.8-4.1 m / 5.8-6.3 m / 8.2 m / 10.4 m. Comparison with previous studies at the Valdorbia section led us to interpret the cycle of ~4 m as directly related with the short-term eccentricity (95-105 kyr). The rest of the cycles could be assigned to a periodicity of ~140-160 kyr, ~200 kyr and ~250 kyr, and interpreted as indirect signals of the long-term eccentricity, obliquity and precession, whose record would be impeded by the incompleteness of the studied succession and the sampling interval. Studied components in the foraminiferal assemblage show variable cyclostratigraphic patterns, allowing for a differentiation of groups based on similar registered cycles. These groups reveal different responses by the foraminiferal assemblage, associated with particular requirements, to the palaeoenvironmental changes of Milankovitch origin

Lower/Middle Ordovician (Arenigian) shallow-marine trace fossils of the Pochico Formation, southern Spain: palaeoenvironmental and palaeogeographic implications at the Gondwanan and peri-Gondwanan realm

Nineteen ichnospecies belonging to thirteen ichnogenera (Archaeonassa, Catenichnus, Cochlichnus, Cruziana, Didymaulichnus, ?Diplichnites, Gordia, Lingulichnus, Lockeia, cf. Monocraterion, Planolites, Ptychoplasma, and Rusophycus) occur in the Pochico Formation (Arenigian) in the Aldeaquemada section, Sierra Morena, southern Spain, just above the Armorican Quartzite. They belong to the archetypal Cruziana ichnofacies, indicating a lower shoreface-upper offshore zone. The low degree of sediment reworking may be due to a high rate of sedimentation. The trace fossil assemblage, rich in large Cruziana, is typical of the Armorican Quartzite that developed on the margins of Gondwana and peri-Gondwanan microcontinents. The distribution of ichnofauna during the Early Ordovician was partly palaeogeographically controlled, although ichnological data from the literature point to paths of migration between Gondwana, Baltica and Laurentia. Differences between the ichnofauna of Gondwana and Baltica could be conditioned by facies (clastics in Gondwana and carbonates in Baltica) causing a taphonomic filter, because Cruziana requires diversified clastic deposits for preservation. The ichnofauna would also be influenced by trophic group amensalism between filter feeding and deposit feeding fauna, the former prevailing in Baltica and the latter in Gondwana.Se presenta el análisis sedimentológico/icnológico de los materiales de la Formación Pochico (Arenigian) de la sección de Aldeaquemada, Sierra Morena, Sur de España, provincia de Jaén, justo por encima la Cuarcita Armoricana. Se han reconocido diecinueve icnoespecies pertenecientes a trece icnogéneros (Archaeonassa, Catenichnus, Cochlichnus, Cruziana, Didymaulichnus, ?Diplichnites, Gordia, Lingulichnus, Lockeia, cf. Monocraterion, Planolites, Ptychoplasma, y Rusophycus). Las características icnológicas junto con los rasgos sedimentológicos permiten asignarlas a las icnofacies arquetípicas de Cruziana, comunes de las zonas de shoreface inferior a offshore superior. El grado de bioturbación relativamente bajo puede estar relacionado con una alta tasa de depósito. La asociación registrada, dominada por grandes Cruziana, es típica de la Cuarcita Armoricana desarrollada en los márgenes de Gondwana y peri-Gondwana. La distribucción de icnofósiles del Ordovícico temprano posee, en gran medida, un control paleogeográfico, aunque datos icnológicos procedentes de la literatura indican la existencia de migraciones entre Gondwana, Baltica y Laurentia. Las diferencias entre las asociaciones de Gondwana y Báltica pueden estar asociadas a las diferentes facies, con el dominio de materiales clásticos en Gondwana y de carbonatados en Báltica, causando un filtro tafonómico ya que el potencial de conservación de Cruziana es mucho mayor en las facies clásticas heterolíticas. A estos factores habría que añadir las estrategias de alimentación asociadas, diferenciando entre filtradores y aquellos que se alimentan de las partículas existentes en el sedimento, los primeros podrían verse favorecidos en Báltica y los segundos en Gondwana.Research by R.-T. was supported by Projects CGL2008-03007, and CGL2012-33281 (Secretaría de Estado de I+D+I, Spain), Project RNM-3715 and Research Group RNM-178 (Junta de Andalucía)

Evidence of phyllosilicate alteration processes and clay mineral neoformation promoted by hydrothermal fluids in the Padul Fault area (Betic Cordillera, SE Spain)

Acknowledgements We acknowledge the technical and human support provided by CICT of Universidad de Ja´en (UJA, MINECO, Junta de Andalucía, FEDER). Cecilia de la Prada is especially recognized for helping with the HRTEM work. The access to the HAADF Thermo Fisher Scientific TALOS F200X microscope was facilitated by the Centro de Instrumentaci´on Científica of the Universidad de Granada. The authors are indebted to responsible of the JUMA Quarry and El Mill´on Quarry. Thanks are extended to B. Dubacq and an anonymous reviewer for their critical reviews and helpful comments and suggestions.Supplementary data to this article can be found online at https://doi. org/10.1016/j.clay.2022.106669.Funding This research was supported by the project PGC2018-094573-B-I00 from the MCIU-AEIFEDER and the research groups RNM-325, RNM-200 and RNM-179 of the Junta de Andalucía.Geochemical changes and authigenic clays were detected in the fault rocks of the Padul Fault. An enrichment from the protolith to the ultracataclasites in Si, Al, Fe, Ca, Ti and also Zn but an impoverishment in Mg was detected. Although the protolith (dolostones) and fault rocks are mostly composed of carbonates, the fault rocks are also characterized by the presence of fine-grained clays in the matrix (mainly chlorite and Mg-rich biotite, but also smectite and punctually talc). Neither chlorite nor talc were detected in the protolith. The application of chlorite thermometry gives temperatures around 140–220 °C for chlorites lamellae located on the fault plane. These chlorites are compositionally homogeneous, whereas the chlorites detected in the cataclasites are more variable, although both of them are Mg-rich and have almost no Fe. As well, chlorites from the cataclasites usually include Zn in their composition and, as observed at nanoscale, they are genetically related to biotites, which come from the protolith. Talc grains (< 1 μm) are always found between dolomite and calcite. These observations point to clay mineral reactions in the fault rocks as the chlorite and talc precipitation promoted by circulation of fault-controlled hydrothermal fluids close to 200 °C. Other clays such as smectite are the result of the final step of the hydrothermal activity in the fault. The identification of authigenic clay minerals, which cause weakening mechanisms, is consistent with the geodetic characterization of the Padul Fault, which plays an important role in aseismic deformation.Project PGC2018-094573-B-I00 from the MCIU-AEIFEDERResearch groups RNM-325, RNM-200 and RNM-179 of the Junta de Andalucí