Hot carrier and hot phonon coupling during ultrafast relaxation of photoexcited electrons in graphene

We study, by means of a Monte Carlo simulator, the hot phonon effect on the relaxation dynamics in photoexcited graphene and its quantitative impact as compared to considering an equilibrium phonon distribution. Our multi-particle approach indicates that neglecting the hot phonon effect significantly underestimates the relaxation times in photoexcited graphene. The hot phonon effect is more important for a higher energy of the excitation pulse and photocarrier densities between $1$ and $3\times 10^{12} \mathrm{~cm}^{-2}$. Acoustic intervalley phonons play a non-negligible role, and emitted phonons with wavelengths limited up by a maximum (determined by the carrier concentration) induce a slower carrier cooling rate. Intrinsic phonon heating is damped in graphene on a substrate due to additional cooling pathways, with the hot phonon effect showing a strong inverse dependence with the carrier density.Comment: 12 pages, 5 figure

Submillimetric spectroscopic observations of volatiles in comet C/2004 Q2 (Machholz)

We aim to determine the production rates of several parent and product volatiles and the 12C/13C isotopic carbon ratio in the long-period comet C/2004 Q2 (Machholz), which is likely to originate from the Oort Cloud. The line emission from several molecules in the coma was measured with high signal-to-noise ratio in January 2005 at heliocentric distance of 1.2 AU by means of high-resolution spectroscopic observations using the Submillimeter Telescope (SMT). We have obtained production rates of several volatiles (CH3OH, HCN, H13CN, HNC, H2CO, CO and CS) by comparing the observed and simulated line-integrated intensities. Furthermore, multiline observations of the CH3OH (7-6) series allow us to estimate the rotational temperature using the rotation diagram technique. We find that the CH3OH population distribution of the levels sampled by these lines can be described by a rotational temperature of 40 \pm 3 K. Derived mixing ratios relative to hydrogen cyanide are CO/CH3OH/H2CO/CS/HNC/H13CN/HCN = 30.9/24.6/4.8/0.57/0.031/0.013/1 assuming a pointing offset of 8" due to the uncertain ephemeris at the time of the observations and the telescope pointing error. The measured relative molecular abundances in C/2004 Q2 (Machholz) are between low- to typical values of those obtained in Oort Cloud comets, suggesting that it has visited the inner solar system previously and undergone thermal processing. The HNC/HCN abundance ratio of ~3.1% is comparable to that found in other comets, accounting for the dependence on the heliocentric distance, and could possibly be explained by ion-molecule chemical processes in the low-temperature atmosphere. From a tentative H13CN detection, the measured value of 97 \pm 30 for the H12CN/H13CN isotopologue pair is consistent with a telluric value.Comment: 14 pages with 11 figures, abridged abstrac

A PLS multigroup analysis of the role of businesswomen in the tourism sector in Andalusia

The objective of this study is to determine the factors that influ-ence “business performance” or the “role of entrepreneurs”, as well as to analyse whether gender functions as a moderating variable, based on a survey conducted on a sample of 127 com-panies. Most of the literature in the tourism sector only considers hotel accommodation; thus, it is still limited in the case of non-hotel accommodation. Our research fills this gap by focusing on both types of establishments. An explanatory and confirmatory model has been carried out based on a PLS-SEM approach, taking the factors that determine business performance into ac-count. Moreover, a MICOM and a multi-group analysis have been undertaken in order to check whether gender acts as a modera-tor. Our findings reveal that there are no significant differences between tourist accommodation companies run by women and men in Andalusia; hence, gender is not a moderating variable regarding business performance. Furthermore, as full measure-ment invariance has been established, a comparison between groups emphasises that the influence of the environment, and the resources and capabilities of the entrepreneur, are factors that affect women more than men, and the number of employ-ees, work experience, and the occupancy rate are more impor-tant for businesswomen, whereas the distance to the nearest airport, check-in, and the occupancy rate are more important for businessmen. This empirical study has practical implications for hospitality industry professionals and concerned authorities which are responsible for designing strategies and policies related to this sector in Andalusia

A model formative assessment strategy to promote student-centered self-regulated learning in higher education

Adult learners are already involved in the process of self-regulation; hence, higher education institutions should focus on strengthening students’ self-regulatory skills. Self-regulation can be facilitated through formative assessment. This paper proposes a model formative assessment strategy that would complement existing university teaching, and can be used in higher education to promote student-centered self-regulated learning with minimal effort and time input from teachers. Based on this model, a real-world teaching example on writing an essay as a challenge task has also been developed. This model strategy incorporates Nicol and Macfarlane-Dick’s seven principles of good feedback practice that promotes self-regulation.Jayakumar Bose, Zed Renge

A Deep Learning-Monte Carlo Combined Prediction of Side-Effect Impact Ionization in Highly Doped GaN Diodes

The existence of leakage current pathways leading to the appearance of impact ionization and the potential device breakdown in planar Gunn GaN diodes is analyzed by means of a combined Monte Carlo-deep learning approach. Front-view (lateral) Monte Carlo simulations of the devices show the appearance of a high-field hotspot at the anode corner of the etched region, just at the boundaries between the dielectric, the GaN-doped layer, and the buffer. Thus, if the isolation created by the etched trenches is not complete, a relevant hot carrier population within the buffer is observed at sufficiently high applied voltages, provoking the appearance of a very significant number of impact ionizations and the consequent avalanche process before the onset of Gunn oscillations. A neural network trained from Monte Carlo simulations allows predicting with extremely good precision the breakdown voltage of the diodes depending on the doping of the GaN active layer, the permittivity of the isolating dielectric, and the lattice temperature. Low doping, high temperature and high permittivity provide larger operational voltages, which implies a tradeoff with the conditions required to achieve THz Gunn oscillations at low voltages

A core of three amino acids at the carboxyl-terminal region of glutamine synthetase defines its regulation in cyanobacteria

© 2015 John Wiley & Sons Ltd. Glutamine synthetase (GS) type I is a key enzyme in nitrogen metabolism, and its activity is finely controlled by cellular carbon/nitrogen balance. In cyanobacteria, a reversible process that involves protein-protein interaction with two proteins, the inactivating factors IF7 and IF17, regulates GS. Previously, we showed that three arginine residues of IFs are critical for binding and inhibition of GS. In this work, taking advantage of the specificity of GS/IFs interaction in the model cyanobacteria Synechocystis sp. PCC 6803 and Anabaena sp. PCC 7120, we have constructed a different chimeric GSs from these two cyanobacteria. Analysis of these proteins, together with a site-directed mutagenesis approach, indicates that a core of three residues (E419, N456 and R459) is essential for the inactivation process. The three residues belong to the last 56 amino acids of the C-terminus of SynechocystisGS. A protein-protein docking modeling of SynechocystisGS in complex with IF7 supports the role of the identified core for GS/IF interaction.Peer Reviewe

Radiative transfer and inversion codes for characterizing planetary atmospheres: an overview

The study of planetary atmospheres is crucial for understanding the origin, evolution, and processes that shape celestial bodies like planets, moons and comets. The interpretation of planetary spectra requires a detailed understanding of radiative transfer (RT) and its application through computational codes. With the advancement of observations, atmospheric modelling, and inference techniques, diverse RT and retrieval codes in planetary science have been proliferated. However, the selection of the most suitable code for a given problem can be challenging. To address this issue, we present a comprehensive mini-overview of the different RT and retrieval codes currently developed or available in the field of planetary atmospheres. This study serves as a valuable resource for the planetary science community by providing a clear and accessible list of codes, and offers a useful reference for researchers and practitioners in their selection and application of RT and retrieval codes for planetary atmospheric studies