2,122 research outputs found
Core hole-electron correlation in coherently coupled molecules
We study the core hole-electron correlation in coherently coupled molecules
by energy dispersive near edge X-ray absorption fine-structure spectroscopy. In
a transient phase, which exists during the transition between two bulk
arrangements, 1,4,5,8-naphthalene-tetracarboxylicacid-dianhydride multilayer
films exhibit peculiar changes of the line shape and energy position of the
X-ray absorption signal at the C K-edge with respect to the bulk and gas phase
spectra. By a comparison to a theoretical model based on a coupling of
transition dipoles, which is established for optical absorption, we demonstrate
that the observed spectroscopic differences can be explained by an
intermolecular delocalized core hole-electron pair. By applying this model we
can furthermore quantify the coherence length of the delocalized core-exciton.Comment: 5 pages, 3 figures, Accepted Version, PRL, minor wording change
Structure and transport in multi-orbital Kondo systems
We consider Kondo impurity systems with multiple local orbitals, such as rare
earth ions in a metallic host or multi--level quantum dots coupled to metallic
leads. It is shown that the multiplet structure of the local orbitals leads to
multiple Kondo peaks above the Fermi energy , and to ``shadow'' peaks
below . We use a slave boson mean field theory, which recovers the strong
coupling Fermi liquid fixed point, to calculate the Kondo peak positions,
widths, and heights analytically at T=0, and NCA calculations to fit the
temperature dependence of high--resolution photoemission spectra of Ce
compounds. In addition, an approximate conductance quantization for transport
through multi--level quantum dots or single--atom transistors in the Kondo
regime due to a generalized Friedel sum rule is demonstrated.Comment: 4 pages, 3 figures. Invited article, 23rd International Conference on
Low Temperature Physics LT23, Hiroshima, Japan 200
Fall Armyworm (Lepidoptera: Noctuidae) Resistance in Texas Bluegrass, Kentucky Bluegrass, and Their Hybrids ( Poa spp.)
Resistance in Zoysiagrass ( Zoysia spp.) to the Fall Armyworm ( Spodoptera frugiperda ) (Lepidoptera: Noctuidae)
Paper Session I-A - Is It SEP Yet?
This paper is a presentation of the results of recent studies indicating that solar electric propulsion can be implemented in a Discovery-class scenario to permit an affordable exploration of comets and asteroids in the very near future. Gallium arsenide solar array technology, the availability of space-qualified ion and plasma thrusters, and appropriate power conditioning equipment are cited as enabling factors for an exciting class of missions that can permit exploration of a number of asteroids and short-period comets, using the Delta launch vehicle, before the turn of the century. Launch requirements are about 993 kg to C$ = 10 km^/s^ for an assumed 50 to 75 kg complement of science instruments. An advantageous feature of electric propulsion is that the high installed power level, unnecessary for propulsion during rendezvous, enables high science data rates from most potential targets
Adsorption geometry and electronic structure of iron phthalocyanine on Ag surfaces: A LEED and photoelectron momentum mapping study
We present a comprehensive study of the adsorption behavior of iron
phthalocyanine on the low-index crystal faces of silver. By combining
measurements of the reciprocal space by means of photoelectron momentum mapping
and low energy electron diffraction, the real space adsorption geometries are
reconstructed. At monolayer coverage ordered superstructures exist on all
studied surfaces containing one molecule in the unit cell in case of Ag(100)
and Ag(111), and two molecules per unit cell for Ag(110). The azimuthal tilt
angle of the molecules against the high symmetry directions of the substrate is
derived from the photoelectron momentum maps. A comparative analysis of the
momentum patterns on the substrates with different symmetry indicates that both
constituents of the twofold degenerate FePc lowest unoccupied molecular orbital
are occupied by charge transfer from the substrate at the interface
Complete determination of molecular orbitals by measurement of phase symmetry and electron density.
Several experimental methods allow measuring the spatial probability density of electrons in atoms, molecules and solids, that is, the absolute square of the respective single-particle wave function. But it is an intrinsic problem of the measurement process that the information about the phase is generally lost during the experiment. The symmetry of this phase, however, is a crucial parameter for the knowledge of the full orbital information in real space. Here, we report on a key experiment that demonstrates that the phase symmetry can be derived from a strictly experimental approach from the circular dichroism in the angular distribution of photoelectrons. In combination with the electron density derived from the same experiment, the full quantum mechanical wave function can thus be determined experimentally
Momentum-resolved evolution of the Kondo lattice into 'hidden-order' in URu2Si2
We study, using high-resolution angle-resolved photoemission spectroscopy,
the evolution of the electronic structure in URu2Si2 at the Gamma, Z and X
high-symmetry points from the high-temperature Kondo-screened regime to the
low-temperature `hidden-order' (HO) state. At all temperatures and symmetry
points, we find structures resulting from the interaction between heavy and
light bands, related to the Kondo lattice formation. At the X point, we
directly measure a hybridization gap of 11 meV already open at temperatures
above the ordered phase. Strikingly, we find that while the HO induces
pronounced changes at Gamma and Z, the hybridization gap at X does not change,
indicating that the hidden-order parameter is anisotropic. Furthermore, at the
Gamma and Z points, we observe the opening of a gap in momentum in the HO
state, and show that the associated electronic structure results from the
hybridization of a light electron band with the Kondo-lattice bands
characterizing the paramagnetic state.Comment: Updated published version. Mansucript + Supplemental Material (8
pages, 9 figures). Submitted 16 September 201
Temperature dependence of the Kondo resonance and its satellites in CeCu_2Si_2
We present high-resolution photoemission spectroscopy studies on the Kondo
resonance of the strongly-correlated Ce system CeCuSi. Exploiting the
thermal broadening of the Fermi edge we analyze position, spectral weight, and
temperature dependence of the low-energy 4f spectral features, whose major
weight lies above the Fermi level . We also present theoretical
predictions based on the single-impurity Anderson model using an extended
non-crossing approximation (NCA), including all spin-orbit and crystal field
splittings of the 4f states. The excellent agreement between theory and
experiment provides strong evidence that the spectral properties of
CeCuSi can be described by single-impurity Kondo physics down to K.Comment: 4 pages, 3 figure
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