Nano- and Micromechanics of Crystalline Polymers

It is currently thought that crystalline polymers consists of lamellar crystals which are separated from each other by a layer of amorphous polymer and are held together by tie molecules through the amorphous phase [e.g. 1]. The lamellae are formed from mostly folded chains. The thickness of lamellae is determined by the parameters such as interfacial energies, glass transition temperature and melting temperature, undercooling, segmental diffusivity, etc. The thickness reported lies usually in a narrow range between 3 and 20 nm as obtained from observations in various types of microscopes or calculated from the degree of crystallinity and long period. It has been recognized that chain folding is not so regular as it was thought and molecular packing in lamellae is subject to considerable and irregularly distributed disorder depending on undercooling- regimes of crystallization. It has been demonstrated in various ways that the planar growth front will always break up into fibrous or cellular growth. Also crystallization of polymers leads to interface instability. More sophisticated treatment of the instabilities involve perturbation analyses of planar interfaces, correlating diffusion, temperature gradients along the interface, and interfacial energy with the size of the growing crystals

Towards a numerical simulation of direct manufacturing of thermoplastic parts by powder laser sintering COMPLAS XI

Direct manufacturing technology using Selective Laser Sintering (SLS) on thermoplastic powders allows obtaining final parts in a short time, with classical polymer density and a high flexibility of shape and evolution of parts. The physical base of this process is the coalescence of grains, which initiates the densification of powder during SLS. This study presents a 2D C-NEM simulation of the whole process. We firstly focus on the chosen method and its advantages. We present the simulation details and validate the modeling through a 2D infinite cylinders coalescence simulation. The mesh of the grain interface is continuously adapted to the local curvature to better capture the coalescence phenomenon. We are able to simulate the sintering of twelve particles laying on a support within some hours

I. Jet Formation and Evolution due to 3D Magnetic Reconnection

Using simulated data-driven three-dimensional resistive MHD simulations of the solar atmosphere, we show that magnetic reconnection can be responsible of the formation of jets with characteristic of Type II spicules. For this, we numerically model the photosphere-corona region using the C7 equilibrium atmosphere model. The initial magnetic configuration is a 3D potential magnetic field, extrapolated up to the solar corona region from a dynamic realistic simulation of solar photospheric magnetoconvection model which is mimicking quiet-Sun. In this case we consider a uniform and constant value of the magnetic resistivity of 12.56 Ω m. We have found that formation of the jets depends on the Lorentz force, which helps to accelerate the plasma upwards. Analyzing various properties of the jet dynamics, we found that the jet structure shows Doppler shift near to regions with high vorticity. The morphology, upward velocity, covering a range up to 100 km s−1, and life-time of the estructure, bigger than 100 s, are similar to those expected for Type II spicules

In situ generation of coronal Alfvén waves by jets

Within the framework of 3D resistive magnetohydrodynamic, we simulate the formation of a plasma jet with the morphology, upward velocity up to 130 km s−1, and time-scale formation between 60 and 90 s after beginning of simulation, similar to those expected for type II spicules. Initial results of this simulation were published in paper by, e.g. González-Avilés et al. (2018), and present paper is devoted to the analysis of transverse displacements and rotational-type motion of the jet. Our results suggest that 3D magnetic reconnection may be responsible for the formation of the jet in paper by González-Avilés et al. (2018). In this paper, by calculating times series of the velocity components vx and vy in different points near to the jet for various heights we find transverse oscillations in agreement with spicule observations. We also obtain a time-distance plot of the temperature in a cross-cut at the plane x = 0.1 Mm and find significant transverse displacements of the jet. By analysing temperature isosurfaces of 104 K with the distribution of vx, we find that if the line-of-sight (LOS) is approximately perpendicular to the jet axis then there is both motion towards and away from the observer across the width of the jet. This red–blue shift pattern of the jet is caused by rotational motion, initially clockwise and anti-clockwise afterwards, which could be interpreted as torsional motion and may generate torsional Alfvén waves in the corona region. From a nearly vertical perspective of the jet the LOS velocity component shows a central blue-shift region surrounded by red-shifted plasma

Electrosynthesis of Aryliminophosphoranes in Continuous Flow

A practical electrochemical method for synthesizing aryliminophosphoranes from widely available nitro(hetero)arenes in a continuous-flow system is presented. The utilization of flow technology offers several advantages to our approach, including the elimination of the need for a supporting electrolyte and enhanced scalability. Our method demonstrates good tolerance towards various functional groups, with electron-deficient nitroarenes being particularly suitable for this strategy. In addition, we have demonstrated the versatility of aryliminophosphoranes as intermediates in synthesizing anilines, amines, and amides. To further enhance the utility of our approach, we have developed a telescoped method that utilizes a tube-in-tube setup for the in-situ production of isocyanates

Adaptive partitioning of real-time tasks on multiple processors

This paper presents a new algorithm for scheduling real-time tasks on multiprocessor/multicore systems. This new algorithm is based on combining EDF scheduling with a migration strategy that moves tasks only when needed. It has been evaluated through an extensive set of simulations that showed good performance when compared with global or partitioned EDF: a worst-case utilisation bound similar to partitioned EDF for hard real-time tasks, and a tardiness bound similar to global EDF for soft real-time tasks. Therefore, the proposed scheduler is effective for dealing with both soft and hard real-time workloads

Dihydrotestosterone stimulates amino acid uptake and the expression of LAT2 in mouse skeletal muscle fibres through an ERK1/2-dependent mechanism

Dihydrotestosterone (DHT) has acute/non-genomic actions in adult mammalian skeletal muscles whose physiological functions are still poorly understood. Therefore, the primary aim of this study was to investigate the acute/non-genomic effects of DHT on amino acid uptake as well as the cellular signal transduction events underlying these actions in mouse fast- and slow-twitch skeletal muscle fibre bundles. 14C-Labelled amino acids were used to investigate the effects of DHT and testosterone (T) on amino acid uptake and pharmacological interventions were used to determine the cellular signal transduction events mediating these actions. While T had no effect on the uptake of isoleucine (Ile) and a-methylaminoisobutyric acid (MeAIB) in both fibre types, DHT increased their uptake in the fast-twitch fibre bundles. This effect was reversed by inhibitors of protein translation, the epidermal growth factor receptor (EGFR), system A, system L, mTOR and MEK. However, it was relatively insensitive to inhibitors of transcription, androgen receptors and PI3K/Akt. Additionally, DHT treatment increased the expression of LAT2 and the phosphorylation of the EGFR in the fast-twitch fibre bundles and that of ERK1/2, RSK1/2 and ATF2 in both fibre types. Also, it decreased the phosphorylation of eEF2 and increased the incorporation of Ile into proteins in both fibre types. Most of these effects were reversed by EGFR and MEK inhibitors. From these findings we suggest that another physiological function of the acute/non-genomic actions of DHT in isolated mammalian skeletal muscle fibres is to stimulate amino acid uptake. This effect is mediated through the EGFR and involves the activation of the MAPK pathway and an increase in LAT2 expression

Identifying frequency decorrelated dust residuals in B-mode maps by exploiting the spectral capability of bolometric interferometry

Astrophysical polarized foregrounds represent the most critical challenge in Cosmic Microwave Background (CMB) B-mode experiments. Multi-frequency observations can be used to constrain astrophysical foregrounds to isolate the CMB contribution. However, recent observations indicate that foreground emission may be more complex than anticipated. We investigate how the increased spectral resolution provided by band splitting in Bolometric Interferometry (BI) through a technique called spectral imaging can help control the foreground contamination in the case of unaccounted Galactic dust frequency decorrelation along the line-of-sight. We focus on the next generation ground-based CMB experiment CMB-S4, and compare its anticipated sensitivities, frequency and sky coverage with a hypothetical version of the same experiment based on BI. We perform a Monte-Carlo analysis based on parametric component separation methods (FGBuster and Commander) and compute the likelihood on the recovered tensor-to-scalar ratio. The main result of this analysis is that spectral imaging allows us to detect systematic uncertainties on r from frequency decorrelation when this effect is not accounted for in component separation. Conversely, an imager would detect a biased value of r and would be unable to spot the presence of a systematic effect. We find a similar result in the reconstruction of the dust spectral index, where we show that with BI we can measure more precisely the dust spectral index also when frequency decorrelation is present. The in-band frequency resolution provided by BI allows us to identify dust LOS frequency decorrelation residuals where an imager of similar performance would fail. This opens the prospect to exploit this potential in the context of future CMB polarization experiments that will be challenged by complex foregrounds in their quest for B-modes detection.Comment: 13 Pages, 15 figures, 4 tables. Submitted to A&